Patent classifications
C03B2211/22
Utilization of sulfate in the fining of submerged combustion melted glass
A method of producing and fining glass includes monitoring a temperature of a molten glass bath contained within a fining chamber of a fining vessel and, based on the monitored temperature, controlling an amount of a sulfate chemical fining agent added into a glass melt contained within an interior reaction chamber of an upstream submerged combustion melter that feeds the fining vessel. The temperature of the molten glass bath may be determined within a temperature indication zone that encompasses a subsurface portion of the molten glass bath that lies adjacent to a floor of a housing of the fining vessel. By monitoring the temperature of the molten glass bath and controlling the amount of the sulfate chemical fining agent added to the glass melt of the submerged combustion melter, the wasteful use of the sulfate chemical fining agent can be minimized and the fining process rendered more efficient.
Cooling panel for a melter
A cooling panel for a melter and method for fabricating the cooling panel are disclosed. In particular, the cooling panel can include first and second outer walls and a plurality of side walls coupled to the outer walls that define an interior space. A plurality of baffles is disposed in the interior space, where projections in the baffles fit into respective openings in the outer walls and can be connected from outside the cooling panel. The cooling panel can be formed by way of welding and/or additive manufacturing, as discussed herein.
SUBMERGED COMBUSTION MELTING EXHAUST SYSTEMS
A submerged combustion melting system includes a furnace including a tank with a floor, a roof, a perimeter wall, and an interior, and burners to melt glass feedstock into molten glass, a batch inlet, a molten glass outlet, and an exhaust outlet. An exhaust system is in fluid communication with the interior of the tank, and includes a flue in fluid communication with the exhaust outlet. A refractory-lined hood may be in fluid communication with the flue, which may be fluid-cooled including fluid-cooled perimeter panels and lower and upper baffles. The hood may include a protrusion that protrudes into a downstream horizontal exhaust path and has an excurvate upper surface to streamline flow of exhaust gas through the hood to prevent gas recirculation and formation of condensate piles in the hood.
SUBMERGED FEEDSTOCK CHARGING OF MELTING VESSELS
A melting furnace feedstock charger includes a charger conduit including an inlet to receive feedstock and an outlet at an outlet portion of the charger conduit to transmit feedstock, and an auger or other feedstock mover coupled to the charger conduit to convey feedstock in a direction from the inlet toward the outlet. A gate may be detachably coupled to the outlet portion of the charger conduit and configured to be coupled directly to a wall of a melting vessel. The auger may have a helical flight with an outer diameter of varying size. A stripper may be movably carried by the charger conduit and may include a stripping tool moved by an actuator with respect to the charger conduit to facilitate transmission of feedstock and/or to strip away clogged feedstock and/or molten material.
Burner for submerged combustion melting
Submerged combustion burners having a burner body and a burner tip body connected thereto. The burner body has an external conduit and a first internal conduit substantially concentric therewith. The external conduit and first internal conduit form an annulus for passing a cooling fluid there between. A second internal conduit substantially concentric with the external conduit forms a second annulus between the first and second internal conduits. A burner tip body is connected to the burner body at ends of the external and first internal conduits. The burner tip body includes a generally central flow passage for a combustible mixture, the flow passage defined by an inner wall of the burner tip body. The burner tip body further has an outer wall and a crown connecting the inner and outer walls. The crown includes at least one physical convolution sufficient to increase surface area and fatigue resistance of the crown.
PROCESS FOR THE PREPARATION OF A SILICA MELT
Fly ash and/or rice husk ash is molten in a submerged combustion melter, possibly together with fluxing agent and/or further vitrifiable material, and vitrified upon cooling.
Feed Material for Producing Flint Glass using Submerged Combustion Melting
A method of producing flint glass using submerged combustion melting involves introducing a vitrifiable feed material into a glass melt contained within a submerged combustion melter. The vitrifiable feed material is formulated to provide the glass melt with a glass chemical composition suitable for producing flint glass articles. To that end, the glass melt comprises a total iron content expressed as Fe.sub.2O.sub.3 in an amount ranging from 0.04 wt % to 0.06 wt % and also has a redox ratio that ranges from 0.1 to 0.4, and the vitrifiable feed material further includes between 0.008 wt % and 0.016 wt % of selenium or between 0.1 wt % and 0.2 wt % of manganese oxide in order to achieve an appropriate content of selenium or manganese oxide in the glass melt.
Glass Redox Control in Submerged Combustion Melting
A method of producing glass using submerged combustion melting is disclosed. The method includes introducing a vitrifiable feed material into a glass melt contained within a submerged combustion melter. The glass melt contained in the melter has a redox ratio defined as a ratio of Fe.sup.2+ to total iron in the glass melt. The method further includes combusting a combustible gas mixture supplied to each of the submerged burners to produce combustion products, and discharging the combustion products directly into the glass melt. Still further, the method includes adjusting the redox ratio of the glass melt by controlling one or more operating conditions of the submerged combustion melter selected from (1) an oxygen-to-fuel ratio of the combustible gas mixture supplied to each of the submerged burners, (2) a residence time of the glass melt, and (3) a gas flux through the glass melt.
Producing Flint Glass Using Submerged Combustion Melting
A method of producing flint glass using submerged combustion melting is disclosed. The method includes operating a submerged combustion melter such that combustion products are discharged from one or more submerged burners combusting a combustible gas mixture that comprises fuel and oxygen. An oxygen-to-fuel ratio of the combustible gas mixture ranges from stoichiometry to 30% excess oxygen relative to stoichiometry, a temperature of a glass melt in the submerged combustion melter is between 1200° C. and 1500° C., a residence time of the glass melt is maintained between 1 hour and 10 hours, and a specific throughput rate of molten glass discharged from the submerged combustion melter ranges from 2 tons per day per meter squared of cross-sectional area of the submerged combustion melter [tons/day/m.sup.2] to 25 tons/day/m.sup.2. A method of forming glass containers from the molten glass discharged from the melter is also disclosed.
Fining Glass Using High Temperature and Low Pressure
A glass fining system, glass fining device, and method are disclosed. The glass fining device in accordance with one aspect of the disclosure includes at least one heated orifice through which molten glass flows from a glass melter to produce at least one superheated glass stream; and a low-pressure chamber disposed downstream from the heated orifice, where the at least one superheated glass stream flows from the at least one heated orifice and into the low-pressure chamber, and where the low-pressure chamber surrounds the at least one superheated glass stream. In some embodiments, the low-pressure chamber may include at least one surface extender.