Patent classifications
C03B2211/22
Glass redox control in submerged combustion melting
A method of producing glass using submerged combustion melting includes supplying a combustible gas mixture to one or more submerged burners of a submerged combustion melter, combusting the combustible gas mixture supplied to the submerged burner(s) to produce combustion products, and discharging the combustion products from the submerged burner(s) directly into a glass melt contained within the submerged combustion melter to agitate and heat the glass melt. The glass melt is comprised of soda-lime-silica glass and has a redox ratio. Additionally, the disclosed method involves controlling one or more operating conditions of the submerged combustion melter selected from (1) an oxygen-to-fuel ratio of the combustible gas mixture supplied to each of the submerged burners, (2) a residence time of the glass melt, and (3) a gas flux through the glass melt.
Submerged combustion melters, wall structures or panels of same, and methods of using same
Submerged combustion burner panels, submerged combustion melters including one or more of the panels, and methods of using the same. The burner panel includes a panel body including a fluid-cooled portion and a protective non-fluid cooled portion. An exterior surface defined by the fluid-cooled portion, and an interior surface defined by the protective non-fluid cooled portion, exterior and interior referring to an SCM in which the panel is installed. The fluid-cooled portion has at least one burner support passage of diameter (d1) extending from the exterior surface to a seam where the fluid-cooled and protective non-fluid cooled portions meet supporting at least one fluid-cooled SC burner having a fluid-cooled burner tip attached to a burner body protruding away from the seam. The protective non-fluid-cooled portion has a combustion products flow passage of diameter (d2)<(d1). The burner panels promote burner life and melter campaign length.
Submerged combustion burners, submerged combustion glass melters including the burners, and methods of use
Submerged combustion burners having improved fuel and oxidant mixing characteristics. Submerged combustion melters including the burners. Methods of using submerged combustion melters to melt glass-forming materials and produce molten glass.
Stilling Vessel for Submerged Combustion Melter
A method of producing glass includes receiving unrefined molten glass in a stilling chamber of a stilling tank at a fluctuating flow rate. The unrefined molten glass merges with an intermediate pool of molten glass being held within the stilling chamber. The intermediate pool of molten glass is heated in the stilling chamber by one or more non-submerged burners. Molten glass flows from the intermediate pool of molten glass to a transfer pool of molten glass held in a spout chamber of a feeding spout that is appended to the stilling tank. Additionally, a molten glass feed is delivered out of the feeding spout from the transfer pool of molten glass at a controlled flow rate.
Processing organics and inorganics in a submerged combustion melter
Primary inorganic feedstock material is introduced into the melting region of an SCM melter. The material is heated with a burner to form a turbulent melt matrix. The burner exit is disposed below the top surface of the turbulent melt matrix. A mixture of secondary inorganic material and organic material is introduced into the melting region below the top surface of the turbulent melt mixture. The mixture is heated with the burner to incorporate the secondary inorganic material into the turbulent melt matrix and combust at least some of the organic material to produce heat.
Submerged combustion burners and melters, and methods of use
Submerged combustion burners having a burner body, a burner tip connected thereto, and a protective cap and/or cladding layer. Submerged combustion melters including the burners and methods of using them to produce molten glass. The burner body has an external conduit and first and second internal conduits substantially concentric therewith, forming first and second annuli for passing a cooling fluid therethrough. The burner tip body is connected to the burner body at ends of the external and second internal conduits. The burner tip and protective cap and/or cladding layer include a generally central flow passage for a combustible mixture, the flow passage defined by an inner wall of the burner tip and protective cap.
Submerged combustion burners
Submerged combustion burners having a burner body and a burner tip connected thereto. The burner body has an external conduit and first and second internal conduits substantially concentric therewith, forming first and second annuli for passing a cooling fluid therethrough. A burner tip body is connected to the burner body at ends of the external and second internal conduits. The burner tip includes a generally central flow passage for a combustible mixture, the flow passage defined by an inner wall of the burner tip. The burner tip further has an outer wall and a crown connecting the inner and outer walls. The inner and outer walls, and the crown are comprised of same or different materials having greater corrosion and/or fatigue resistance than at least the external burner conduit.
Submerged combustion melting processes for producing glass and similar materials, and systems for carrying out such processes
Processes of controlling submerged combustion melters, and systems for carrying out the methods. One process includes feeding vitrifiable material into a melter vessel, the melter vessel including a fluid-cooled refractory panel in its floor, ceiling, and/or sidewall, and heating the vitrifiable material with a burner directing combustion products into the melting zone under a level of the molten material in the zone. Burners impart turbulence to the molten material in the melting zone. The fluid-cooled refractory panel is cooled, forming a modified panel having a frozen or highly viscous material layer on a surface of the panel facing the molten material, and a sensor senses temperature of the modified panel using a protected thermocouple positioned in the modified panel shielded from direct contact with turbulent molten material. Processes include controlling the melter using the temperature of the modified panel. Other processes and systems are presented.
High Temperature and Low Pressure Fining of Submerged Combustion or Other Glass
A method of producing glass includes discharging an outflow (22, 1022) of fined molten glass from a fining tank (18, 1018) of a vacuum induction fining apparatus (10, 1010) and delivering the fined molten glass into a thermal conditioning tank (16, 1016) that is separated from the fining tank by an open space (26, 1026) occupied by an ambient environment (24, 1024). The fining tank includes a vertically-elongated housing (80, 1080) that defines an interior fining chamber (82, 1082) where a bath (76, 1076) of molten glass is collected and maintained. The interior fining chamber is maintained at subatmospheric pressure and the housing is surrounded by at least one induction coil (74, 1074) to introduce heat into the molten glass bath. The vacuum maintained in the interior fining chamber and the heating supplied by the induction coil(s) promote the ascension of gas bubbles upwards through the molten glass bath. A glass-producing system that includes the vacuum induction fining apparatus is also disclosed.
Systems and methods for making foamed glass using submerged combustion
Submerged combustion systems and methods of use to produce foamed glass. One system includes a submerged combustion melter having an outlet, the melter configured to produce an initial foamy molten glass having a density and comprising bubbles filled primarily with combustion product gases. The initial foamy molten glass is deposited directly onto or into a transport apparatus that transports the initial foamy molten glass to a downstream processing apparatus. An intermediate stage may be included between the melter and the transport apparatus. One intermediate stage is a channel that includes gas injectors. Another intermediate stage is a channel that produces an upper flow of a less dense glass and a relatively more dense glass lower flow. The upper flow may be processed into foamed glass products, while the more dense flow may be processed into dense glass products.