C03C3/076

Continuous sol-gel process for producing silicate-containing glasses or glass ceramics

A continuous sol-gel process for producing silicate-containing glasses and glass ceramics is proposed, comprising the following steps: (a) continuously feeding a silicon tetraalkoxide, a silicon alkoxide with at least one non-alcoholic functional group and an alcohol into a first reactor (R1), and at least partially hydrolyzing by the addition of a mineral acid to obtain a first product stream (A); (b) continuously providing a second product stream (B) in a second reactor (R2) by feeding a metal alkoxide component or continuously mixing an alcohol and a metal alkoxide component; (c) continuously mixing product streams (A) and (B) in a third reactor (R3) for producing a presol to obtain a third product stream (C); (d) continuously adding water or a diluted acid to the product stream (C) to obtain a sol (gelation); (e) continuously filling the emerging sol into molds to obtain an aquagel; (f) drying the aquagels to obtain xerogels; (g) sintering the xerogels to obtain silicate-containing glasses and glass ceramics.

Continuous sol-gel process for producing silicate-containing glasses or glass ceramics

A continuous sol-gel process for producing silicate-containing glasses and glass ceramics is proposed, comprising the following steps: (a) continuously feeding a silicon tetraalkoxide, a silicon alkoxide with at least one non-alcoholic functional group and an alcohol into a first reactor (R1), and at least partially hydrolyzing by the addition of a mineral acid to obtain a first product stream (A); (b) continuously providing a second product stream (B) in a second reactor (R2) by feeding a metal alkoxide component or continuously mixing an alcohol and a metal alkoxide component; (c) continuously mixing product streams (A) and (B) in a third reactor (R3) for producing a presol to obtain a third product stream (C); (d) continuously adding water or a diluted acid to the product stream (C) to obtain a sol (gelation); (e) continuously filling the emerging sol into molds to obtain an aquagel; (f) drying the aquagels to obtain xerogels; (g) sintering the xerogels to obtain silicate-containing glasses and glass ceramics.

Bioactive glass/polymer composite filament, and methods of making
11433598 · 2022-09-06 · ·

Bioactive glass compositions, composites of the bioactive glass compositions with polymers, and 3D printable filaments made from the same, along with methods of making and using the same, are described. In some embodiments, the compositions, composites, and filaments have antibacterial activity.

Glass for autonomous car

The invention concerns an automotive glazing comprising (i) at least one glass sheet having an absorption coefficient lower than 5 m.sup.−1 in the wavelength range from 1051 nm to 1650 nm and having an external face and an internal face, and (ii) an infrared filter. According to the present invention, an infrared-based remote sensing device in the wavelength range from 1051 nm to 1650 nm, is placed on the internal face of the glass sheet in a zone free of the infrared filter layer.

Glass for autonomous car

The invention concerns an automotive glazing comprising (i) at least one glass sheet having an absorption coefficient lower than 5 m.sup.−1 in the wavelength range from 1051 nm to 1650 nm and having an external face and an internal face, and (ii) an infrared filter. According to the present invention, an infrared-based remote sensing device in the wavelength range from 1051 nm to 1650 nm, is placed on the internal face of the glass sheet in a zone free of the infrared filter layer.

METHODS FOR REDUCING CHROMIUM OXIDATION STATE DURING PROCESSING OF GLASS COMPOSITIONS
20220081346 · 2022-03-17 ·

Glass manufacturing methods disclosed herein include delivering a molten glass to a melting vessel, and melting the batch materials to produce a molten glass comprising less than about 20 ppm CrO.sub.3. Glass articles produced by these methods are also disclosed herein.

METHODS FOR REDUCING CHROMIUM OXIDATION STATE DURING PROCESSING OF GLASS COMPOSITIONS
20220081346 · 2022-03-17 ·

Glass manufacturing methods disclosed herein include delivering a molten glass to a melting vessel, and melting the batch materials to produce a molten glass comprising less than about 20 ppm CrO.sub.3. Glass articles produced by these methods are also disclosed herein.

Lithium Containing Glass with High Oxidized Iron Content and Method of Making Same

A low infrared absorbing lithium glass includes FeO in the range of 0.0005-0.015 wt %, more preferably 0.001-0.010 wt %, and a redox ratio in the range of 0.005-0.15, more preferably in the range of 0.005-010. The glass can be chemically tempered and used to provide a ballistic viewing cover for night vision goggles or scope. A method is provided to change a glass making process from making a high infrared absorbing lithium glass having FeO in the range of 0.02 to 0.04 wt % and a redox ratio in the range of 0.2 to 0.4 to the low infrared absorbing lithium glass by adding additional oxidizers to the batch materials. A second method is provided to change a glass making process from making a low infrared absorbing lithium glass to the high infrared absorbing lithium glass by adding additional reducers to the batch material. In one embodiment of the invention the oxidizer is CeO.sub.2. An embodiment of the invention covers a glass made according to the method.

CRYSTALLIZED GLASS OF THREE-DIMENSIONAL SHAPE, CHEMICALLY STRENGTHENED GLASS OF THREE-DIMENSIONAL SHAPE, AND METHOD FOR PRODUCING CRYSTALLIZED GLASS OF THREE-DIMENSIONAL SHAPE AND CHEMICALLY STRENGTHENED GLASS OF THREE-DIMENSIONAL SHAPE
20220064054 · 2022-03-03 · ·

The present invention provides crystallized glass of three-dimensional shape for easily producing chemically strengthened glass of three-dimensional shape that resists damage and has exceptional transparency. This crystallized glass of three-dimensional shape:

contains crystals; has light transmittance in terms of a thickness of 0.8 mm of 80% or higher; and contains 45-74% SiO.sub.2, 1-30% Al.sub.2O.sub.3, 1-25% Li.sub.2O, 0-10% Na.sub.2O, 0-5% K.sub.2O, a total of 0-15% of SnO.sub.2 and/or ZrO.sub.2, and 0-12% P.sub.2O.sub.5, these amounts expressing the oxide-based mass percentage.

GLASS ELEMENT COMPRISING ENAMEL COATING AND USE THEREOF, COATING AGENT FOR MAKING SAME, AND METHOD FOR PRODUCING THE COATING AGENT

Glass elements are provided that include a coating and a sheet-like glass substrate. The sheet-like glass substrate has a first surface and a second surface opposite the first surface. The coating is disposed in at least some areas of at least one of the first and second surfaces. The coating is an inorganic glass-based coating that includes at least one glassy component; at least one pigment comprising pigment particles; and a filler. The filler is inorganic and includes filler particles with a d.sub.50 value, based on an equivalent diameter, of at least 0.1 μm and less than 10 μm.