According to various embodiments described herein, an article comprises a glass or glass-ceramic substrate having a first major surface and a second major surface opposite the first major surface, and a via extending through the substrate from the first major surface to the second major surface over an axial length in an axial direction. The article further comprises a helium hermetic adhesion layer disposed on the interior surface; and a metal connector disposed within the via, wherein the metal connector is adhered to the helium hermetic adhesion layer. The metal connector coats the interior surface of the via along the axial length of the via to define a first cavity from the first major surface to a first cavity length, the metal connector comprising a coating thickness of less than 12 μm at the first major surface. Additionally, the metal connector coats the interior surface of the via along the axial length of the via to define a second cavity from the second major surface to a second cavity length, the metal connector comprising a coating thickness of less than 12 μm at the second major surface and fully fills the via between the first cavity and the second cavity.

A tempered glass of the present invention includes as a glass composition, in terms of mass %, 40% to 60% of SiO.sub.2, 15% to 25% of Al.sub.2O.sub.3, 0% to 13.5% of B.sub.2O.sub.3, 12% to 24% of Na.sub.2O, and 0% to less than 3% of MgO.

The invention relates to a method for treating a silicate-type glass comprising alkali and alkaline-earth metal oxides or d.sup.10 or IIIA metal oxides, said method comprising at least the following steps: (a) incorporation of nitrogen into the surface of the glass; and (b) thermal poling treatment of the material obtained in (a), under a chemically inert controlled atmosphere. The invention also relates to the material produced by said method.

Glare-free glass articles and methods for producing are provided. The glass article includes a surface with an area having a roughness RMS from 10 nm to 1000 nm, a distinctness of image DOI from 30 to 70, a gloss value of less than 40 at a viewing angle of 60°, and a haze value, determined in transmission, of less than 3%. The area also has a ratio of mean height of peaks above core surface (Spk) to mean depth of valleys below core surface (Svk) that is equal to 1±0.1 within a measured surface area of more than 0.1 mm.sup.2 and less than 3 mm.sup.2.

Glare-free glass articles and methods for producing are provided. The glass article includes a surface with an area having a roughness RMS from 10 nm to 1000 nm, a distinctness of image DOI from 30 to 70, a gloss value of less than 40 at a viewing angle of 60°, and a haze value, determined in transmission, of less than 3%. The area also has a ratio of mean height of peaks above core surface (Spk) to mean depth of valleys below core surface (Svk) that is equal to 1±0.1 within a measured surface area of more than 0.1 mm.sup.2 and less than 3 mm.sup.2.

The present invention relates to a blank for dental purposes which has a first and a second layer which, independently of each other, are based on glass, glass-ceramic or ceramic, wherein the first layer and the second layer differ in colour and form a boundary surface, wherein the boundary surface runs obliquely.

A glass has a maximum crystallization rate (KG.sub.max) of at most 0.20 μm/min in a temperature range of 700° C. to 1250° C. and a hydrolytic stability according to a hydrolytic class 1 HGA1 according to ISO 720:1985. In the case of a sample thickness of 2 mm of the glass, a ratio of a minimum transmittance in a wavelength range of 850 nm to 950 nm to a maximum transmittance in a wavelength range of 250 nm to 700 nm is in a range of 1.9:1 to 15:1.

A glass includes cations of the following components in the indicated amounts (molar proportion in cat.-%): 30-80 cat.-% silicon; 0-20 cat.-% boron; 0-2 cat.-% aluminum; 5-35 cat.-% sodium; 2-25 cat.-% potassium; 0-0.5 cat.-% nickel; 0-0.5 cat.-% chromium; and 0.03-0.5 cat.-% cobalt. A sum of the molar proportions of cations of sodium and potassium is in a range of from 15 to 50 cat.-%, a sum of the molar proportions of cations of nickel and chromium is in a range of from 0.1 to 0.5 cat.-%, and a ratio of the sum of the molar proportions of cations of sodium and potassium to the sum of the molar proportions of cations of nickel and chromium is in a range of from 70:1 to 200:1.

Annealing treatments for modified titania-silica glasses and the glasses produced by the annealing treatments. The annealing treatments include an isothermal hold that facilitates equalization of non-uniformities in fictive temperature caused by non-uniformities in modifier concentration in the glasses. The annealing treatments may also include heating the glass to a higher temperature following the isothermal hold and holding the glass at that temperature for several hours. Glasses produced by the annealing treatments exhibit high spatial uniformity of CTE, CTE slope, and fictive temperature, including in the presence of a spatially non-uniform concentration of modifier.

Annealing treatments for modified titania-silica glasses and the glasses produced by the annealing treatments. The annealing treatments include an isothermal hold that facilitates equalization of non-uniformities in fictive temperature caused by non-uniformities in modifier concentration in the glasses. The annealing treatments may also include heating the glass to a higher temperature following the isothermal hold and holding the glass at that temperature for several hours. Glasses produced by the annealing treatments exhibit high spatial uniformity of CTE, CTE slope, and fictive temperature, including in the presence of a spatially non-uniform concentration of modifier.