A method including digital printing a heat curable aqueous composition onto a substrate, wherein the composition includes: (a) at least one water soluble synthetic alkali metal silicate; and (b)(i) at least one pigment or (b)(ii) at least one additive selected from aluminum oxide, ceramic microspheres, recycled ground glass, or calcium carbonate; wherein the composition is substantially free of any organic solvent; and heating the composition bearing substrate thereby curing the composition, and wherein the substrate includes a material selected from glass, ceramic, textile, polymeric, metal, wood, or a combination thereof.

A method including digital printing a heat curable aqueous composition onto a substrate, wherein the composition includes: (a) at least one water soluble synthetic alkali metal silicate; and (b)(i) at least one pigment or (b)(ii) at least one additive selected from aluminum oxide, ceramic microspheres, recycled ground glass, or calcium carbonate; wherein the composition is substantially free of any organic solvent; and heating the composition bearing substrate thereby curing the composition, and wherein the substrate includes a material selected from glass, ceramic, textile, polymeric, metal, wood, or a combination thereof.

The present disclosure provides a method for coating a composite structure, comprising forming a first slurry by combining a first pre-slurry composition comprising a first phosphate glass composition, with a primary flow modifier and a first carrier fluid, wherein the primary flow modifier comprises at least one of cellulose or calcium silicate; applying the first slurry on a surface of the composite structure to form a base layer; and heating the composite structure to a temperature sufficient to adhere the base layer to the composite structure.

The present disclosure provides a method for coating a composite structure, comprising forming a first slurry by combining a first pre-slurry composition comprising a first phosphate glass composition, with a primary flow modifier and a first carrier fluid, wherein the primary flow modifier comprises at least one of cellulose or calcium silicate; applying the first slurry on a surface of the composite structure to form a base layer; and heating the composite structure to a temperature sufficient to adhere the base layer to the composite structure.

A substrate for flexible device. The substrate has a nickel-plated metal sheet having a nickel-plating layer formed on at least one surface of a metal sheet or a nickel-based sheet, and a glass layer of an electrically-insulating layered bismuth-based glass on a surface of the nickel-plating layer or the nickel-based sheet. An oxide layer having a roughened surface is formed on the surface of the nickel-plating layer or the surface of the nickel-based sheet, and the bismuth-based glass contains 70 to 84% by weight of Bi.sub.2O.sub.3, 10 to 12% by weight of ZnO, and 6 to 12% by weight of B.sub.2O.sub.3. Also disclosed is a method for producing the substrate for flexible device, a substrate for an organic EL device, a sheet used as a substrate for flexible device, a method for producing the sheet and a bismuth-based lead-free glass composition.

A substrate for flexible device. The substrate has a nickel-plated metal sheet having a nickel-plating layer formed on at least one surface of a metal sheet or a nickel-based sheet, and a glass layer of an electrically-insulating layered bismuth-based glass on a surface of the nickel-plating layer or the nickel-based sheet. An oxide layer having a roughened surface is formed on the surface of the nickel-plating layer or the surface of the nickel-based sheet, and the bismuth-based glass contains 70 to 84% by weight of Bi.sub.2O.sub.3, 10 to 12% by weight of ZnO, and 6 to 12% by weight of B.sub.2O.sub.3. Also disclosed is a method for producing the substrate for flexible device, a substrate for an organic EL device, a sheet used as a substrate for flexible device, a method for producing the sheet and a bismuth-based lead-free glass composition.

A particle mixture for forming an enamel comprising particles of a first glass frit and particles of a second glass frit; wherein the first glass frit comprises greater than 5 wt % silicon oxide (SiO.sub.2) and less than 5 wt % boron oxide (B.sub.2O.sub.3); wherein the second glass frit comprises boron oxide (B.sub.2O.sub.3) and less than 5 wt % of silicon oxide (SiO.sub.2); and wherein both the particles of the first glass frit and the particles of the second glass frit have a D90 particle size of less than 5 microns. Also described is an ink comprising the particle mixture, methods of preparing the ink, an article formed using the ink, and a kit comprising particles of the first and second glass frit.

A particle mixture for forming an enamel comprising particles of a first glass frit and particles of a second glass frit; wherein the first glass frit comprises greater than 5 wt % silicon oxide (SiO.sub.2) and less than 5 wt % boron oxide (B.sub.2O.sub.3); wherein the second glass frit comprises boron oxide (B.sub.2O.sub.3) and less than 5 wt % of silicon oxide (SiO.sub.2); and wherein both the particles of the first glass frit and the particles of the second glass frit have a D90 particle size of less than 5 microns. Also described is an ink comprising the particle mixture, methods of preparing the ink, an article formed using the ink, and a kit comprising particles of the first and second glass frit.

An enamel paste composition includes glass frit; a pigment; and an organic carrier medium; wherein the glass frit includes at least two glass frits including a first glass frit and a second glass frit, and wherein the first glass frit has a larger particle size and a higher glass transition temperature than the second glass frit. Also described is a method of forming an enamel coating by depositing the enamel paste composition on a substrate; and firing the enamel paste to form an enamel coating on the substrate, the enamel coating having a heterogeneous frit microstructure with particles of the first frit embedded in a matrix of second frit.

An enamel paste composition includes glass frit; a pigment; and an organic carrier medium; wherein the glass frit includes at least two glass frits including a first glass frit and a second glass frit, and wherein the first glass frit has a larger particle size and a higher glass transition temperature than the second glass frit. Also described is a method of forming an enamel coating by depositing the enamel paste composition on a substrate; and firing the enamel paste to form an enamel coating on the substrate, the enamel coating having a heterogeneous frit microstructure with particles of the first frit embedded in a matrix of second frit.