The present disclosure relates to a low temperature-calcined lead-free glass frit and paste, and a vacuum glass assembly using the same. The glass frit according to the present disclosure has a novel component system comprising V.sub.2O.sub.5, TeO.sub.2, CuO, BaO, one or more of Ag.sub.2O and Bi.sub.2O.sub.3, ZnO, and one or more of SnO and MoO.sub.3 at a characteristic composition ratio according to the disclosure, whereby the glass frit can replace a lead-based glass composition of the related art, can be calcined at a low temperature of 350° C. or lower and can ensure excellent chemical durability.

The present disclosure discloses a ceramic glass powder and a solar cell metallization paste containing the ceramic glass powder, and belongs to the technical field of solar cells. The present disclosure provides a novel formula mode of a glass powder including a crystallization nucleus component and a glass network component, that is, a formula of a ceramic glass powder that has a special crystallization behavior, a low crystallinity before sintering and a high crystallinity after the sintering, and a conductive metallization paste containing the ceramic glass powder is further obtained. The present disclosure solves the technical problem that by using metallization pastes in the prior art, a balance between corrosion of a silicon wafer and an ohmic contact is difficult to achieve. The efficiency of a solar cell is improved.

The present disclosure discloses a ceramic glass powder and a solar cell metallization paste containing the ceramic glass powder, and belongs to the technical field of solar cells. The present disclosure provides a novel formula mode of a glass powder including a crystallization nucleus component and a glass network component, that is, a formula of a ceramic glass powder that has a special crystallization behavior, a low crystallinity before sintering and a high crystallinity after the sintering, and a conductive metallization paste containing the ceramic glass powder is further obtained. The present disclosure solves the technical problem that by using metallization pastes in the prior art, a balance between corrosion of a silicon wafer and an ohmic contact is difficult to achieve. The efficiency of a solar cell is improved.

A ceramic printing ink is provided that is suitable for application using an inkjet printing process to produce a coating on glass ceramics. The ink includes a glassy material of glass particles and pigment particles. The glass particles are present in a ratio of total weight to the pigment particles of at least 1.5 and less than 19. The glass particles have an equivalent diameter d.sub.90 ranging from at least 0.5 μm to at most 5 μm. The ink has an effective coefficient of linear thermal expansion, α.sub.20-300,eff, in a range from 6.5*10.sup.−6/K to 11*10.sup.−6/K.

Coated glass panes having a glass pane and a coating in at least one region of at least one side of the glass pane. The glass pane is composed of glass with SiO.sub.2 and B.sub.2O.sub.3. The coating includes first coating applied in at least one region of the at least one side. The first coating has a binder with SiO.sub.2 and a pigment. The glass pane, in the at least one region, has a flexural strength between at least 5 and at most 170 MPa.

Strengthened glass substrates with glass fits and methods for forming the same are disclosed. According to one embodiment, the present invention provides a glass frit with a coefficient of thermal expansion less than or equal to the coefficient of thermal expansion of the glass substrate where it is going to be painted. The glass frit of the present invention has similar ion exchange properties to the glass substrate that is going to be used to paint with the glass frit allowing the glass substrate to be ion-exchanged. The glass frit of the present invention is mixed with an organic carrier.

A silver powder containing: silver particles; and an adherent that is attached to surfaces of the silver particles and contains a metal oxide that has a melting point lower than a melting point of silver.

A silver powder containing: silver particles; and an adherent that is attached to surfaces of the silver particles and contains a metal oxide that has a melting point lower than a melting point of silver.

An inkjet ink for a glass substrate can enable formation of an aesthetic image with high concealability on the surface of the glass substrate. The inkjet ink disclosed here can include: an inorganic solid including an inorganic pigment that develops a color except for black and a glass frit; a monomer component having a photocuring property; and a photoinitiator. In the inkjet ink, a volume ratio of the inorganic solid in a case where an ink total volume is 100 volume % can be 35 volume % or less, a volume ratio of the inorganic pigment in the case where a total volume of the inorganic solid is 100 volume % can be 15 volume % or more and less than 90 volume %, and a volume ratio of the inorganic pigment to the photoinitiator can be 11 times or less.

An inkjet ink for a glass substrate can enable formation of an aesthetic image with high concealability on the surface of the glass substrate. The inkjet ink disclosed here can include: an inorganic solid including an inorganic pigment that develops a color except for black and a glass frit; a monomer component having a photocuring property; and a photoinitiator. In the inkjet ink, a volume ratio of the inorganic solid in a case where an ink total volume is 100 volume % can be 35 volume % or less, a volume ratio of the inorganic pigment in the case where a total volume of the inorganic solid is 100 volume % can be 15 volume % or more and less than 90 volume %, and a volume ratio of the inorganic pigment to the photoinitiator can be 11 times or less.