The purpose of the present invention is to provide a lead-free glass composition in which crystallization is suppressed and which has a low softening point. This lead-free glass composition is characterized by containing silver oxide, tellurium oxide and vanadium oxide, and further containing at least one compound selected from among yttrium oxide, lanthanum oxide, cerium oxide, erbium oxide, ytterbium oxide, aluminum oxide, gallium oxide, indium oxide, iron oxide, tungsten oxide and molybdenum oxide as an additional component, and in that the content values (mol %) of silver oxide, tellurium oxide and vanadium oxide satisfy the relationships Ag.sub.2O>TeO.sub.2V.sub.2O.sub.5 and Ag.sub.5O2V.sub.2O.sub.5 when calculated in terms of the oxides, and in that the content of TeO.sub.2 is 25-37 mol. %.

The purpose of the present invention is to provide a lead-free glass composition in which crystallization is suppressed and which has a low softening point. This lead-free glass composition is characterized by containing silver oxide, tellurium oxide and vanadium oxide, and further containing at least one compound selected from among yttrium oxide, lanthanum oxide, cerium oxide, erbium oxide, ytterbium oxide, aluminum oxide, gallium oxide, indium oxide, iron oxide, tungsten oxide and molybdenum oxide as an additional component, and in that the content values (mol %) of silver oxide, tellurium oxide and vanadium oxide satisfy the relationships Ag.sub.2O>TeO.sub.2V.sub.2O.sub.5 and Ag.sub.5O2V.sub.2O.sub.5 when calculated in terms of the oxides, and in that the content of TeO.sub.2 is 25-37 mol. %.

An apparatus for manufacturing vacuum insulation glass is provided. The apparatus for manufacturing the vacuum insulation glass includes a cap frit disposed on an exhaust hole, and an exhaust finishing frit provided on a bottom surface of the cap frit and including a frit formed of a glass material. The exhaust finishing frit is dispensed, in the paste form, to the cap frit such that the exhaust finishing frit is easily aligned with the cap frit.

An apparatus for manufacturing vacuum insulation glass is provided. The apparatus for manufacturing the vacuum insulation glass includes a cap frit disposed on an exhaust hole, and an exhaust finishing frit provided on a bottom surface of the cap frit and including a frit formed of a glass material. The exhaust finishing frit is dispensed, in the paste form, to the cap frit such that the exhaust finishing frit is easily aligned with the cap frit.

An overglaze decoration material is provided that can be used to apply to a ceramic product a luster overglaze in which a luster pigment does not dissolve in glass and can thus maintain its luster properties to provide a metallic texture and high surface gloss. The overglaze decoration material in accordance with the present invention contains a frit that has a composition thereof including 40 wt % to 60 wt % of silicon dioxide, 15 wt % to 35 wt % of boron oxide, and 18 wt % or less of one or more alkali metal oxides selected from the group consisting of lithium oxide, sodium oxide and potassium oxide, and a luster pigment for providing a metallic look.

An overglaze decoration material is provided that can be used to apply to a ceramic product a luster overglaze in which a luster pigment does not dissolve in glass and can thus maintain its luster properties to provide a metallic texture and high surface gloss. The overglaze decoration material in accordance with the present invention contains a frit that has a composition thereof including 40 wt % to 60 wt % of silicon dioxide, 15 wt % to 35 wt % of boron oxide, and 18 wt % or less of one or more alkali metal oxides selected from the group consisting of lithium oxide, sodium oxide and potassium oxide, and a luster pigment for providing a metallic look.

A coating composition, coating glass and a method for preparation thereof, and a cooking appliance including the coating class are described. The coating composition includes a coating material and a heat conductive oxide nano powder that is 5 to 10 wt % with respect to a weight of the coating material. The coating composition provides an excellent infrared reflective function, a high transmittance, and an excellent cleaning performance.

A method of protecting a carbon-containing composite material part against oxidation, includes applying a first coating composition in the form of an aqueous suspension on an outside surface of the part, the first coating composition including a metallic phosphate; a powder of an ingredient comprising titanium; and a powder of B.sub.4C; subjecting the applied first coating composition to heat treatment in order to obtain a first coating on the outside surface of the part; applying a second coating composition on the first coating composition, the second coating composition including an aqueous suspension of colloidal silica; a powder of borosilicate glass; and a powder of TiB.sub.2; and subjecting the applied second coating composition to second heat treatment in order to obtain a second coating on the first coating.

A method of protecting a carbon-containing composite material part against oxidation, includes applying a first coating composition in the form of an aqueous suspension on an outside surface of the part, the first coating composition including a metallic phosphate; a powder of an ingredient comprising titanium; and a powder of B.sub.4C; subjecting the applied first coating composition to heat treatment in order to obtain a first coating on the outside surface of the part; applying a second coating composition on the first coating composition, the second coating composition including an aqueous suspension of colloidal silica; a powder of borosilicate glass; and a powder of TiB.sub.2; and subjecting the applied second coating composition to second heat treatment in order to obtain a second coating on the first coating.

Disclosed herein are floor tiles comprising, for instance, a substrate and a surface coating, wherein the surface coating comprises (i) a base formula comprising a glaze and (ii) particles comprising alumina trihydrate.