The present invention relates to a glass including, in terms of mole percentage based on oxides: 50.0 to 75.0% of SiO.sub.2; 7.5 to 25.0% of Al.sub.2O.sub.3; 0 to 25.0% of B.sub.2O.sub.3; 6.5 to 20.0% of Li.sub.2O; 1.5 to 10.0% of Na.sub.2O; 0 to 4.0% of K.sub.2O; 1.0 to 20.0% of MgO; one or more components selected from MgO, CaO, SrO, and BaO in a total amount of 1.0 to 20.0%; and 0 to 5.0% of TiO.sub.2, in which a value of Y calculated based on the following formula is 19.5 or less, Y=1.2×([MgO]+[CaO]+[SrO]+[BaO])+1.6×([Li.sub.2O]+[Na.sub.2O]+[K.sub.2O]), provided that [MgO], [CaO], [SrO], [BaO], [Li.sub.2O], [Na.sub.2O], and [K.sub.2O] are contents, in terms of mole percentage based on oxides, of components of MgO, CaO, SrO, BaO, Li.sub.2O, Na.sub.2O, and K.sub.2O respectively.

A method for producing a glass ceramic includes: providing a batch of raw materials; heating the batch of raw materials until a melt is obtained, the batch of raw materials being heated at least in a plurality of sections to a temperature above T3 which corresponds to a viscosity of a molten glass of 10.sup.3 dPa*s; refining the melt, the melt being heated at least in a plurality of sections to a temperature above T2.5 which corresponds to a viscosity of the molten glass of 10.sup.2.5 dPa*s; obtaining a refined glass which is configured for being ceramized to form a glass ceramic material; and ceramizing a glass which is configured for being ceramized to form the glass ceramic material, at least one of the step of heating until the melt is obtained and the step of refining being performed with heating by way of H.sub.2 and O.sub.2 combustion.

A glass-based article with a textured surface exhibiting low haze is provided. The glass-based articles are produced by utilizing a combination of abrasion and etching, where hydrofluoric acid is not utilized. The process for producing the glass-based articles also includes an ion exchange process.

According to one embodiment, a glass-ceramic composition may include from about 60 mol. % to about 75 mol. % SiO.sub.2; from about 5 mol. % to about 10 mol. % Al.sub.2O.sub.3; from about 2 mol. % to about 20 mol. % alkali oxide R.sub.2O, the alkali oxide R.sub.2O including Li.sub.2O and Na.sub.2O; and from 0 mol. % to about 5 mol. % alkaline earth oxide RO, the alkaline earth oxide RO including MgO. A ratio of Al.sub.2O.sub.3 (mol. %) to the sum of (R.sub.2O (mol. %)+RO (mol. %)) may be less than 1 in the glass-ceramic composition. A major crystalline phase of the glass-ceramic composition may be Li.sub.2Si.sub.2O.sub.5. A liquidus viscosity of the glass-ceramic composition may be greater than 35 kP. The glass-ceramic composition may be used to form the glass clad layer(s) of a laminated glass article.

In embodiments, a precursor glass composition comprises from about 55 wt. % to about 80 wt. % SiO.sub.2; from about 2 wt. % to about 20 wt. % Al.sub.2O.sub.3; from about 5 wt. % to about 20 wt. % Li.sub.2O; greater than 0 wt % to about 3 wt. % Na.sub.2O; a non-zero amount of P.sub.2O.sub.5 less than or equal to 4 wt. %; and from about 0.2 wt. % to about 15 wt. % ZrO.sub.2. In embodiments, ZrO.sub.2 (wt. %)+P.sub.2O.sub.5 (wt. %) is greater than 3. When the precursor glass composition is converted to a glass-ceramic article, the glass-ceramic article may include grains having a longest dimension of less than 100 nm.

Ion-exchanged glass ceramic articles described herein have a stress that decreases with increasing distance according to a substantially linear function from a depth of about 0.07t to a depth of about 0.26t from the outer surface of the ion-exchanged glass ceramic article from a compressive stress to a tensile stress. The stress transitions from the compressive stress to the tensile stress at a depth of from about 0.18t to about 0.25t from the outer surface of the ion-exchanged glass ceramic article. An absolute value of a maximum compressive stress at the outer surface of the ion-exchanged glass article is from 1.8 to 2.2 times an absolute value of a maximum central tension (CT) of the ion-exchanged glass article, and the glass ceramic article has a fracture toughness of 1 MPa√m or more as measured according to the double cantilever beam method.

A ceramic printing ink is provided that is suitable for application using an inkjet printing process to produce a coating on glass ceramics. The ink includes a glassy material of glass particles and pigment particles. The glass particles are present in a ratio of total weight to the pigment particles of at least 1.5 and less than 19. The glass particles have an equivalent diameter d.sub.90 ranging from at least 0.5 μm to at most 5 μm. The ink has an effective coefficient of linear thermal expansion, α.sub.20-300,eff, in a range from 6.5*10.sup.−6/K to 11*10.sup.−6/K.

The present invention relates to a chemically strengthened glass article including: a first surface; a second surface facing the first surface; and an end portion in contact with the first surface and the second surface, in which the first surface has a compressive stress value of 400 MPa to 1000 MPa, in which, when a compressive stress value of an inside of the glass is expressed with a depth from the first surface as a variable, a depth m [μm] at which the compressive stress value is maximum is larger than 0 μm, and a value of CS.sub.m−CS.sub.0 [MPa] is 30 MPa or more, and in which a depth DOL at which the compressive stress value is 0 is 50 μm to 150 μm.

Optically transparent glass ceramic materials comprising a glass phase containing and a crystalline tungsten bronze phase comprising nanoparticles and having the formula M.sub.xWO.sub.3, where M includes at least one H, Li, Na, K, Rb, Cs, Ca, Sr, Ba, Zn, Cu, Ag, Sn, Cd, In, Tl, Pb, Bi, Th, La, Pr, Nd, Sm, Eu, Gd, Dy, Ho, Er, Tm, Yb, Lu, and U, and where 0<x<1. Aluminosilicate and zinc-bismuth-borate glasses comprising at least one of Sm.sub.2O.sub.3, Pr.sub.2O.sub.3, and Er.sub.2O.sub.3 are also provided.

A composition includes 30 mol % to 60 mol % SiO.sub.2; 15 mol % to 40 mol % Al.sub.2O.sub.3; 5 mol % to 25 mol % Y.sub.2O.sub.3; 5 mol % to 15 mol % TiO.sub.2; and 0.1 mol % to 15 mol % RO, such that RO is a sum of MgO, CaO, SrO, and BaO.