Modified copper chromite spinel pigments exhibit lower coefficients of thermal expansion than unmodified structures. Three methods exist to modify the pigments: (1) the incorporation of secondary modifiers into the pigment core composition, (2) control of the pigment firing profile, including both the temperature and the soak time, and (3) control of the pigment core composition.

A method includes depositing a glass frit on sidewalls of a plurality of cavities of a shaped article formed from a glass material, a glass ceramic material, or a combination thereof. The glass frit is heated to a firing temperature above a glass transition temperature of the glass frit to sinter the glass frit into a glaze disposed on the sidewalls of the plurality of cavities.

A method includes depositing a glass frit on sidewalls of a plurality of cavities of a shaped article formed from a glass material, a glass ceramic material, or a combination thereof. The glass frit is heated to a firing temperature above a glass transition temperature of the glass frit to sinter the glass frit into a glaze disposed on the sidewalls of the plurality of cavities.

An enamel composition, a method for preparing an enamel composition, and a cooking appliance are provided. The enamel composition may include phosphorus pentoxide (P.sub.2O.sub.5) at 15 to 50 wt %; silicon dioxide (SiO.sub.2) at 10 to 20 wt %; boron oxide (B.sub.2O.sub.3) at 1 to 15 wt %; one or more of lithium oxide (Li.sub.2O), sodium oxide (Na.sub.2O), or potassium oxide (K.sub.2O) at 5 to 20 wt %; one or more of sodium fluoride (NaF), calcium fluoride (CaF.sub.2), or aluminum fluoride (AlF.sub.3) at 1 to 5 wt %; one or more of magnesium oxide (MgO), barium oxide (BaO), or calcium oxide (CaO) at 1 to 35 wt %; and one or more of titanium dioxide (TiO.sub.2), cerium dioxide (CeO.sub.2), molybdenum trioxide (MoO.sub.3), bismuth oxide (Bi.sub.2O.sub.3), or copper oxide (CuO) at 10 to 25 wt %, such that a heating time required for cleaning may be shortened and oil contaminants may be completely removed.

Glass elements are provided that include a coating and a sheet-like glass substrate. The sheet-like glass substrate has a first surface and a second surface opposite the first surface. The coating is disposed in at least some areas of at least one of the first and second surfaces. The coating is an inorganic glass-based coating that includes at least one glassy component; at least one pigment comprising pigment particles; and a filler. The filler is inorganic and includes filler particles with a d.sub.50 value, based on an equivalent diameter, of at least 0.1 μm and less than 10 μm.

Glass elements are provided that include a coating and a sheet-like glass substrate. The sheet-like glass substrate has a first surface and a second surface opposite the first surface. The coating is disposed in at least some areas of at least one of the first and second surfaces. The coating is an inorganic glass-based coating that includes at least one glassy component; at least one pigment comprising pigment particles; and a filler. The filler is inorganic and includes filler particles with a d.sub.50 value, based on an equivalent diameter, of at least 0.1 μm and less than 10 μm.

An antenna unit for glass according to the present invention is installed on the indoor side of a glass sheet, and transmits and receives electromagnetic waves at the indoor side through the glass sheet.

Fluorescent rare earth glass frits are suitable for laser marking. A marking composition including fluorescent glass frits is disclosed that is capable of emitting fluorescence under irradiation of ultraviolet rays. A method of forming marks or indicia on a substrate using the fluorescent rare earth glass frits is also disclosed.

Fluorescent rare earth glass frits are suitable for laser marking. A marking composition including fluorescent glass frits is disclosed that is capable of emitting fluorescence under irradiation of ultraviolet rays. A method of forming marks or indicia on a substrate using the fluorescent rare earth glass frits is also disclosed.

An enamel composition, a method for preparing an enamel composition, and a cooking appliance are provided. The enamel composition may include 15 to 50 wt % of phosphorus pentoxide (P.sub.2O.sub.5); 5 to 20 wt % of one or more of lithium oxide (Li.sub.2O), sodium oxide (Na.sub.2O), or potassium oxide (K.sub.2O); 1 to 5 wt % of one or more of sodium fluoride (NaF), calcium fluoride (CaF.sub.2), or aluminum fluoride (AlF.sub.3); 1 to 35 wt % of one or more of magnesium oxide (MgO), barium oxide (BaO), or calcium oxide (CaO); and 5 to 30 wt % of one or more of manganese dioxide (MnO.sub.2), molybdenum trioxide (MoO.sub.3), bismuth oxide (Bi.sub.2O.sub.3), or nickel oxide (NiO). The enamel composition may be cleaned without being putting it into water.