A superstrate can include a body having a surface; a buffer layer overlying the surface; and a protective layer overlying the buffer layer, wherein the protective layer has a surface roughness that is equal to or less than a surface roughness of the surface of the body. The protective layer can include a material that can be selectively removed with respect to the buffer layer, and the buffer layer can include a material that can be selectively removed with respect to the body of the superstrate. The superstrate can be used for more planarization or other processing sequences before the body needs to be replaced, as any defects that may form extend into the protective layer or buffer layer and not reach the body. The layers can be removed and replaced by corresponding new layers without significantly adversely affecting the body.

A glass article includes at least one glass substrate on which a stack of layers is deposited. The stack includes at least one layer consisting of a layer of silicon nitride of formulation SiN.sub.x, in which x is less than 1.25. The physical thickness of the SiN.sub.x layer is between 5 and 50 nm. The light reflection of the glass article, measured on the side of the substrate on which the stack is deposited, is greater than 20%.

A glass-based substrate having a Young's modulus, a first surface, and a second surface. A coating, on at least one of the first and second surfaces, having a Young's modulus equal to or greater than the substrate Young's modulus. A compressive region having a compressive stress CS of from 750 MPa to 1200 MPa at a surface and extending to a depth of compression (DOC). The compressive region having a first portion and a second portion, the first portion extending from the first surface up to a first depth, the second portion extending from the first depth to the DOC, points in the first portion comprise a tangent having a slope that is less than −15 MPa/micrometers and greater than −60 MPa/micrometers, and points in the second portion comprise a tangent having a slope that is less than or equal to −1 MPa/micrometers and greater than −12 MPa/micrometers.

Antireflective nanoparticle coatings and methods of forming the coatings on substrates are disclosed. One method for forming an antireflective coating includes depositing a nanoparticle coating layer on a substrate, wherein the nanoparticle coating layer includes a colloidal solution of nanoparticles and a solidifying material. The solidifying material includes a silica precursor. The method further includes curing the solidifying material to form silica inter-particle connections between adjacent nanoparticles and between at least some of the nanoparticles and the substrate to bind the nanoparticles to each other and to the substrate to form the antireflective coating.

Glass stack configurations including a carrier plate, setter plates, and glass sheets for thermal treatment of the glass sheets to form glass ceramic articles are provided. The glass stacking configurations and components described herein are selected to improve thermal uniformity throughout a glass stack during ceramming processes while maintaining or even reducing the stresses in the resultant glass ceramic article. Accordingly, the glass ceramic articles made according to the various embodiments described herein exhibit improved optical qualities and less warp than glass ceramic articles made according to conventional processes. Various embodiments of carrier plates, setter plates, parting agent compositions, and methods of stacking glass sheets are described.

Disclosed are a coating for glass molding, a preparation method and application thereof and a mold having the coating. The coating includes a nitride layer and nano precious metal particles which are dispersed in the nitride layer. A surface roughness of the coating is 2-12 nm. The preparation method of the coating includes: cleaning a substrate and targets under an inert gas; and under a mixed atmosphere of nitrogen and the inert gas, depositing, with a high-purity W target, a high-purity Cr target and a precious metal inserted Cr target, a Cr intermediate layer, a nitride layer and nano precious metal particles on a surface of the substrate. The coating has good oxidation resistance and excellent anti-adhesion property. Moreover, the coating effectively inhibits the adhesion between the glass body and the mold.

Making a glass-based article having a coating and a target shape which comprises a planar central portion and a perimeter portion which borders at least part of the planar central portion and extends out of the plane of the planar central portion, the perimeter portion having a perimeter edge and a target edge-to-opposite edge dimension. The method includes forming a glass-based part to provide an initial formed part having an initial three-dimensional shape that is different from the target shape for at least the target edge-to-opposite edge dimension. Applying a coating to the initial formed part to form the glass-based article having a coating, the coating imparting a stress to the initial molded part that causes a calculated, warp-induced change to the initial shape.

A method to provide compressive stress to substrates includes depositing a film on a ceramic substrate at a deposition temperature (Td) to form an article, the film having a difference relative to the ceramic substrate at Td in a coefficient thermal expansion (CTE) of at least 1.010.sup.6/K and a difference in a refractive index >0.10. At least a portion of the thickness the film is converted in at least one of composition, phase and microstructure by lowering or raising the temperature from Td to reach a changed temperature (Tc) that is at least 100 C. different from Td. The film converting conditions result in the converted film portion providing a difference in refractive index at the Tc between the converted film and the ceramic substrate of |0.10|. The temperature of the article is then lowered to room temperature.

A coated glass article and of a system and method for forming a coated glass article are provided. The process includes applying a first coating precursor material to the first surface of the glass article and supporting the glass article via a gas bearing. The process includes heating the glass article and the coating precursor material to above a glass transition temperature of the glass article while the glass article is supported by the gas bearing such that during heating, a property of the first coating precursor material changes forming a coating layer on the first surface of the glass article from the first precursor material. The high temperature and/or non-contact coating formation may form a coating layer with one or more new physical properties, such as a deep diffusion layer within the glass, and may form highly consistent coatings on multiple sides of the glass.

A method for creating gradient optical properties within a substrate is disclosed herein. More specifically, the present invention teaches a method whereby a material disposed on a substrate is patterned in three dimensions such that the thickness and diffusivity properties of the material can be used to regulate the diffusion of ions into the substrate. An example is given in which ions, injected into a substrate through an ion exchange process, alter the refractive index within the substrate in a pre-selected fashion to form a gradient refractive index lens.