Asymmetrically strengthened glass articles, methods for producing the same, and use of the articles in portable electronic device is disclosed. Using a budgeted amount of compressive stress and tensile stress, asymmetric chemical strengthening is optimized for the utility of a glass article. In some aspects, the strengthened glass article can be designed for reduced damage, or damage propagation, when dropped.

The invention relates to a coated glass substrate or glass ceramic substrate with resistant, multi-functional surface properties, including a combination of anti-microbial, anti-reflective and anti-fingerprint properties, or a combination of anti-microbial, anti-reflective and anti-fingerprint properties where the substrate is chemically pre-stressed, or a combination of anti-microbial and anti-reflective properties where the substrate is chemically pre-stressed. The coated glass substrate or glass ceramic substrate exhibits a unique combination of functions which are permanently present and do not exert a negative effect on each other.

Described herein are various antimicrobial glass articles that have improved strength and resistance to discoloration. The improved antimicrobial glass articles described herein generally include a glass substrate with a compressive stress layer and an antimicrobial silver-containing region that each extend inward from a surface of the glass substrate to a specific depth. In some embodiments, the compressive stress layer has a compressive stress at the surface of about 500 MPa or greater and the compressive stress decreases monotonically from the surface into the depth of the glass substrate. Methods of making and using the glass articles are also described and include forming a compressive stress layer and forming an antimicrobial silver-containing region by preferentially exchanging a plurality of silver cations in a silver-containing medium for a specific plurality of first cations ions in the glass substrate.

Embodiments disclosed therein generally pertain to selectively strengthening glass. More particularly, techniques are described for selectively strengthening cover glass, which tends to be thin, for electronic devices, namely, portable electronic devices.

Asymmetrically strengthened glass articles, methods for producing the same, and use of the articles in portable electronic device is disclosed. Using a budgeted amount of compressive stress and tensile stress, asymmetric chemical strengthening is optimized for the utility of a glass article. In some aspects, the strengthened glass article can be designed for reduced damage, or damage propagation, when dropped.

An antimicrobial chemically strengthened glass and a method for manufacturing the chemically strengthened antimicrobial glass. The antimicrobial chemically strengthened glass includes an antimicrobial surface layer having at least 0.1 at % of silver ions and at least 0.1 at % of copper ions, wherein the chemically strengthened antimicrobial glass has a CIE color channel b* of less than 1.

A glass-ceramic article comprises: a center-volume composition comprising (on an oxide basis): 55-75 mol % SiO.sub.2; 0.2-10 mol % Al.sub.2O.sub.3; 0-5 mol % B.sub.2O.sub.3; 15-30 mol % Li.sub.2O; 0-2 mol % Na.sub.2O; 0-2 mol % K.sub.2O; 0-5 mol % MgO; 0-2 mol % ZnO; 0.2-3.0 mol % P.sub.2O.sub.5; 0.1-10 mol % ZrO.sub.2; 0-4 mol % TiO.sub.2; and 0-1.0 mol % SnO.sub.2. Lithium disilicate and either β-spodumene or β-quartz are the two predominant crystalline phases (by weight) of the glass-ceramic article. The glass-ceramic article further comprises tetragonal ZrO.sub.2 as a crystalline phase. The composition of the glass-ceramic article from a primary surface into a thickness of the glass-ceramic article can comprise over 10 mol % Na.sub.2O (on an oxide basis), with the mole percentage of Na.sub.2O decreasing from the primary surface towards the center-volume. The glass-ceramic article exhibits a ring-on-ring load-to-failure of at least 120 kgf, when the thickness of the glass-ceramic article is 0.3 mm to 2.0 mm.

Multicolored glass-based articles and methods of manufacture are disclosed. The method includes forming a glass-based part and exposing a first region to radiation and a second region to radiation such that the first and second regions have different sized metallic nanoparticles, resulting in a multicolored glass article.

Described is a method of processing an antimicrobial glass substrate. More particularly, described is a method of removing one or more of silver nitrate or silver oxide on the surface of an antimicrobial glass substrate. Also described is a method of manufacturing a glass substrate that is substantially free of yellow discoloration.

The efficiency of ion exchange processes is increased by increasing the concentration of nitrite salts in the molten salt bath. The increase in nitrite salt concentration may be achieved by adding a nitrite salt to a molten nitrate salt bath, aging a molten nitrate salt bath, or a combination thereof. The glass-based articles produced using the modified baths exhibit reduced haze and increased flexural strength.