An article having a nanostructured surface and a method of making the same are described. The article can include a substrate and a nanostructured layer bonded to the substrate. The nanostructured layer can include a plurality of spaced apart nanostructured features comprising a contiguous, protrusive material and the nanostructured features can be sufficiently small that the nanostructured layer is optically transparent. A surface of the nanostructured features can be coated with a continuous hydrophobic coating. The method can include providing a substrate; depositing a film on the substrate; decomposing the film to form a decomposed film; and etching the decomposed film to form the nanostructured layer.

The invention relates to a process for obtaining a material comprising a substrate coated on at least one part of at least one of its faces with at least one functional layer, said process comprising: a step of depositing the or each functional layer, then a step of depositing a sacrificial layer on said at least one functional layer, then a step of heat treatment by means of radiation chosen from laser radiation or radiation from at least one flash lamp, said radiation having at least one treatment wavelength between 200 and 2500 nm, said sacrificial layer being in contact with the air during this heat treatment step, then a step of removing the sacrificial layer using a solvent,

said sacrificial layer being a monolayer and being such that, before heat treatment, it absorbs at least one part of said radiation at said at least one treatment wavelength and that, after heat treatment, it is capable of being removed by dissolution and/or dispersion in said solvent.

Defined nanoparticle cluster arrays (NCAs) with dimensions up to 25.4 m square are fabricated on a 10 nm gold film using template guided self-assembly. Structural parameters are precisely controlled, allowing systematic variation of the number of nanoparticles in the clusters (n) and edge to edge separation () between 1<n<20 and 50 nm1000 nm, respectively. Rayleigh scattering spectra and surface enhanced Raman scattering (SERS) signal intensities as functions of n and reveal direct near-field coupling between the particles within individual clusters, whose strength increases with cluster size (n) until it saturates at around n=4. Strong near-field interactions between clusters significantly affects the SERS signal enhancement for edge-to-edge separations <200 nm. The NCAs support multiscale signal enhancement from simultaneous inter- and intra-cluster coupling and |E|-field enhancement. Applications include SERS-based spectral identification of bacteria.

The disclosure relates to glass articles having a decorative inorganic layer that is compatible with ion exchange processes and suitable for automotive glass. The inorganic layer comprises a plurality of pores in which polymerizable filler components have been deposited and cross-linked. The porous inorganic layer has a glass transition temperature of greater than 450? C. and a glass softening temperature of less than 650? C. The disclosure also provides glass articles containing the filled porous inorganic layer and methods for preparing the same.

Articles having poly(vinyl alcohol)-containing (PVA-containing) and silica nanoparticle multilayer coatings are provided. More specifically, articles include a substrate and a multilayer coating attached to the substrate. The multilayer coating includes a first silica layer and a first PVA-containing layer. The first silica layer is a primer layer of the multilayer coating, and the silica layer comprises a plurality of acid-sintered interconnected silica nanoparticles arranged to form a continuous three-dimensional porous network. The PVA-containing and silica nanoparticle multilayer coatings can be used on a large variety of substrates and tend to be resistant to wet and dry abrasions, scratches, and impacts.

A method for developing a coating having a high light transmission and/or a low light reflection is provided. The method relates to a process for developing a coating with a high light transmission and/or a low light reflection, where the coating is deposited on a substrate. The coating is deposited as a mixed coating comprising a material A and a material B, where the coating is developed to have a coating thickness profile in which the lowest proportion of the material B is on the substrate surface and the highest proportion of coating material is on the coating surface. The material B is at least partially removed from the coating after deposition of the coating on the substrate.

The coated glass sheet of the present invention includes: a glass sheet; and a coating film provided on at least one principal surface of the glass sheet and having a smooth surface. The coating film includes: isolated closed pores present within the coating film; and a matrix. The coating film is substantially free of open pores open at the surface of the coating film. For the coated glass sheet of the present invention, a transmittance gain is 2.5% or more, the transmittance gain being calculated by subtracting an average transmittance of the glass sheet as determined by applying light having wavelengths of 380 to 1100 nm to the glass sheet in the absence of the coating film on the surface of the glass sheet from an average transmittance of the coated glass sheet as determined by applying light having the wavelengths to the coated glass sheet from a side on which the coating film lies.

An optical member includes a substrate and a thin film that is disposed on the substrate and contains inorganic particles and a resin. The resin has a volume occupancy of less than 5% in a region up to at least 60 nm in depth from a surface of at least a part of the thin film, the surface being opposite from a substrate-end surface of the thin film.

The present disclosure provides a member having a porous layer containing particles and having a low refractive index and high film strength and a coating liquid for forming a porous layer containing particles, wherein the porous layer contains a plurality of silicon oxide particles bound by an inorganic binder and at least one acid.

An article having a nanostructured surface and a method of making the same are described. The article can include a substrate and a nanostructured layer bonded to the substrate. The nanostructured layer can include a plurality of spaced apart nanostructured features comprising a contiguous, protrusive material and the nanostructured features can be sufficiently small that the nanostructured layer is optically transparent. A continuous layer can be adhered to a plurality of surfaces of the nanostructured features to render the plurality of surfaces of the nanostructured features both hydrophobic and oleophobic with respect to fingerprint oil comprising eccrine secretions and sebaceous secretions, thereby providing an anti-fingerprinting characteristic to the article.