One or more aspects of the disclosure pertain to an article including a film disposed on a glass substrate, which may be strengthened, where the interface between the film and the glass substrate is modified, such that the article has an improved average flexural strength, and the film retains key functional properties for its application. Some key functional properties of the film include optical, electrical and/or mechanical properties. The bridging of a crack from one of the film or the glass substrate into the other of the film or the glass substrate can be suppressed by inserting a nanoporous crack mitigating layer between the glass substrate and the film.

A rational design and fabrication of ZnO/Al.sub.2O.sub.3 core-shell nanowire architectures with tunable geometries (length, spacing, branching) and surface chemistry is provided. The fabricated nanowires significantly delay or even prevent marine biofouling. In some embodiments, hydrophilic nanowires can reduce the fouling coverage by up to approximately 60% after 20 days compared to planar control surfaces. The mechanism of the fouling reduction is mainly due to two geometric effects: reduced effective settlement area and mechanical cell penetration. Further, superhydrophobic nanowires can completely prevent marine algal fouling for up to 22 days. Additionally, the developed nanowire surfaces are transparent across the visible spectrum, making them applicable to windows and oceanographic sensors.

Disclosed herein are embodiments of a porous aluminum oxide thin film having a surface RMS roughness value of less than 1 nm. The thin film may also comprise phosphorus. The disclosed thin films may have a refractive index of from 1 to 2, such as from 1 to 1.5. Also disclosed are embodiments of as method for making the disclosed thin films, comprising forming an aqueous solution of the alumina precursor, a surfactant and optionally a phosphorus-containing precursor, and depositing the solution on a substrate.

The invention provides substrates coated with a hydrocarbon or fluorocarbon layer. The coated substrate has superior properties such as improved hydrophobicity and/or oleophobicity. Also disclosed are methods of making coatings on substrates using atomic layer deposition (ALD) and/or molecular layer deposition (MLD).

The present invention relates to: a method of manufacturing glass with hollow nanopillars, which includes a silicon oxide layer forming step in which a silicon oxide layer made of silicon oxide is formed on one side of a glass substrate, a first etching step in which the silicon oxide layer is etched and a plurality of silicon oxide clusters are formed on the glass substrate, and a second etching step in which the glass substrate, on which the silicon oxide clusters are formed, is etched and hollow nanopillars are formed; and glass with hollow nanopillars manufactured thereby.

An antimicrobial article having a substrate, and a coating on a surface of the substrate. The coating includes a silver-containing alkali silicate. The antimicrobial article has an antimicrobial efficacy of greater than or equal to about 90.0% according to EPA Test Method for Efficacy of Copper Alloy Surfaces as a Sanitizer. The coating may further include at least one of a boron-containing compound and an aluminum-containing compound. A method for forming antimicrobial articles includes coating a substrate with a mixture comprising an alkali silicate; curing the coating at a temperature from greater than or equal to about 300° C. to less than or equal to about 620° C. for a duration of greater than or equal to about 15 minutes to less than or equal to about 120 minutes; and contacting the coating with an antimicrobial medium comprising silver nitrate and an alkali nitrate.

Antireflective nanoparticle coatings and methods of forming the coatings on substrates are disclosed. One method for forming an antireflective coating includes depositing a nanoparticle coating layer on a substrate, wherein the nanoparticle coating layer includes a colloidal solution of nanoparticles and a solidifying material. The solidifying material includes a silica precursor. The method further includes curing the solidifying material to form silica inter-particle connections between adjacent nanoparticles and between at least some of the nanoparticles and the substrate to bind the nanoparticles to each other and to the substrate to form the antireflective coating.

An optical fiber curing component includes a first tube comprising a first body defining a first interior surface and a first exterior surface, the first tube defining a first aperture and a second aperture on opposite ends of a first cavity, wherein the first tube defines a central axis extending through the first cavity; light sources coupled to the first body of the first tube and configured to emit light toward the central axis of the first tube, wherein each of the light sources intersect a common plane defined perpendicular to the central axis of the first tube; a silica glass article, having an anti-reflective coating, disposed between each of the plurality of light sources and the central axis of the first tube; and a reflective coating positioned on the interior surface of the first body and configured to reflect the light toward the central axis of the first tube.

One or more aspects of the disclosure pertain to an article including a film disposed on a glass substrate, which may be strengthened, where the interface between the film and the glass substrate is modified, such that the article retains its average flexural strength, and the film retains key functional properties for its application. Some key functional properties of the film include optical, electrical and/or mechanical properties. The bridging of a crack from one of the film or the glass substrate into the other of the film or the glass substrate can be prevented by inserting a crack mitigating layer between the glass substrate and the film.

Embodiments of the present disclosure describe monolithic interleaving materials and related methods. An interleaving material may include an interleaving particle or bead enrobed or impinged with stain-inhibiting organic acids or salts thereof. An interleaving material may include an interleaving particle or bead, wherein the interleaving particle or bead comprises an cation exchange resin, wherein the cation exchange resin is configured to sequester cations leached from glass. An interleaving material may include a functionalized porous media comprising functional groups that scavenge or react with ions leached from glass. A method of applying interleaving materials may include disposing a plurality of interleaving materials onto a surface of a glass article.