Disclosed herein are coated articles which may include a substrate and an optical coating that includes one or more layers of deposited material. At least a portion of the optical coating may include a residual compressive stress of more than 100 MPa. The coated article may include a strain-to-failure of 0.4% or more as measured by a Ring-on-Ring Tensile Testing Procedure. The optical coating may include a maximum hardness of 8 GPa or more and an average photopic transmission of 50% or greater.

A glass substrate with a silica film according to the present invention includes a glass substrate and a silica film formed using a silica film-forming composition, in which the composition includes at least one kind selected from the group consisting of a hydrolyzable compound, a hydrolyzate thereof, and a hydrolysis condensation compound thereof, and at least one kind selected from the group consisting of a silica particle and a zirconia particle, the hydrolyzable compound consisting of a tetraalkoxysilane, a compound (compound I) represented by formula I: (R.sub.3-p(L).sub.pSi-Q-Si(L).sub.pR.sub.3-p), optionally a fluoroalkylsilane having a hydrolysable group, and optionally a zirconium compound having a hydrolyzable group, and the contents of the tetraalkoxysilane, the compound I, and the at least one kind selected from the group consisting of a silica particle and a zirconia particle in terms of SiO.sub.2/ZrO.sub.2 fall within specified ranges, respectively.

In one or more embodiments disclosed herein, an electronic device may include a display device operable to project an image, a front cover substrate positioned over the display device and including a transparent material, and a protective coating disposed on at least a portion of the non-display area of the front cover substrate. The front cover substrate may include a display area over the display device and a non-display area around at least the perimeter of the front cover substrate. The protective coating may include an inorganic material. The protective coating may not be positioned over the display area.

There are provided: a composition for forming a water repellent film that can form a water repellent film not only excellent in water repellency but also excellent in abrasion resistance, particularly in abrasion resistance evaluated under close-to-actual-use conditions where a light resistance test is combined; a water repellent film formed by using the composition for forming a water repellent film; a substrate with a water repellent film including the water repellent film provided on at least part of a substrate; and an article including the substrate with a water repellent film. The composition for forming a water repellent film contains, at a predetermined quantitative ratio of a hydrolyzable silane compound (1) having a perfluoroalkyl group and having no ether bond; and a compound (21) that has a poly(oxyfluoroalkylene) group and a plurality of hydrolyzable silyl groups with a specific structure and that has a number average molecular weight of 3000 or more.

The present disclosure relates to an ultrathin glass comprising a coating layer, wherein the coating layer comprises a top surface coating layer formed on the top surface of the ultrathin glass and a side surface coating layer that is connected to the top surface coating layer and covers the side surface of the ultrathin glass, and a method for preparing the same.

A material includes a transparent substrate coated with a stack of thin layers acting on infrared radiation including at least one functional layer. The stack includes a carbon-based upper protective layer within which the carbon atoms are essentially in an sp.sup.2 hybridization state and the upper protective layer is deposited above at least a part of the functional layer and exhibits a thickness of less than 1 nm.

A window has an ion exchange substrate with a top surface. To improve robustness, the top surface has a polycrystalline aluminum oxide film formed from a plurality of crystals. At least 95% of the plurality of crystals in the aluminum oxide film has a largest dimension of no greater than about 10 nanometers. In addition, both the ion exchange substrate and aluminum oxide film are transparent or translucent.

Provided are methods of forming stacks comprising a substrate and one or more sol-gel layers disposed on the substrate. Also provided are stacks formed by these methods. The sol-gel layers in these stacks, especially outer layers, may have a porosity of less than 1% or even less than 0.5%. In some embodiments, these layers may have a surface roughness (R.sub.a) of less than 1 nanometers. The sol-gel layers may be formed using radiative curing and/or thermal curing at temperatures of between 400° C. and 700° C. or higher. These temperatures allow application of sol-gel layers on new types of substrates. A sol-gel solution, used to form these layers, may have colloidal nanoparticles with a size of less than 20 Angstroms on average. This small size and narrow size distribution is believed to control the porosity of the resulting sol-gel layers.

A material includes a transparent substrate coated with a stack of thin layers acting on infrared radiation including at least one functional layer. The stack includes a protective coating deposited above at least a part of the functional layer. The protective coating includes at least one lower protective layer based on titanium and zirconium, these two metals being in the metal, oxidized or nitrided form, and at least one upper protective layer of carbon, within which layer the carbon atoms are essentially in an sp.sup.2 hybridization state, located above the layer based on titanium and zirconium.

A method of making a heat treated (HT) substantially transparent coated article to be used in shower door applications, window applications, tabletop applications, or any other suitable applications. For example, certain embodiments relate to a method of making a coated article including a step of heat treating a glass substrate coated with at least layer of or including carbon (e.g., diamond-like carbon (DLC)) and an overlying protective film thereon. The protective film may be of or include both (a) an oxygen blocking or barrier layer, and (b) a release layer, with the release layer being located between at least the carbon based layer and the oxygen blocking layer. The release layer is of or includes zinc oxynitride (e.g., ZnO.sub.xN.sub.z). Following and/or during heat treatment (e.g., thermal tempering, or the like) the protective film may be entirely or partially removed. Other embodiments of this invention relate to the pre-HT coated article, or the post-HT coated article.