A system to calcine crushed carbonate, discharge alkaline oxide, and deliver an enhancing fluid having CO2, comprising: a pressurized insulated calciner having descendingly, a crushed alkaline carbonate feeder, a calciner fluid outlet manifold, a heated sideflow calciner fluid intake manifold, a preheated sideflow calciner fluid outtake manifold, a fluid inlet manifold to recirculate calciner fluid from the outlet manifold, and an alkaline oxide discharger; a pressurizer to repressurize sideflow calciner fluid, connected to intake and outtake manifolds; pressurizers to recirculate calciner outlet fluid to the inlet manifold, pressurize the calciner and deliver enhancing fluid comprising CO2; delivery and combustion systems to form a combustion fluid; a recuperating or regenerating refractory heat exchanger to heat sideflow calciner fluid with combustion fluid connected to the sideflow pressurizer, and fluid outtake and intake manifolds; and a controller operable to control combustion, heat exchange, calciner fluid formation and delivery, carbonate feed and oxide discharge.

A process and apparatus for manufacture of oxide products for use as biocide, chemical detoxifying, and catalytic support products, from caustic calcined carbonate powder, preferably from magnesite, dolomite, or hydromagnesite, is described. These oxide particles are characterized by high surface area, high porosity and a high degree of calcination, and the method of manufacture of utilizes an indirectly heated counterflow reactor. The oxides may be used as a powder, granules, or formulated into a slurry and used as a spray, emulsion, foam or fog, or the powder product may be directly applied. Also described is the formation of particles with microstructures defined by at least one nano-crystalline structure positioned on the outer surface of the particles.

Various embodiments of a process and device for the decarbonation of limestone, dolomite or other carbonated materials are disclosed. The process and device may involve heating particles of carbonated materials (6) in a reactor (8) of a first circuit (2) to obtain decarbonated particles (16) comprising CaO and/or MgO; transferring the decarbonated particles (16) to one or more cooling sections (22, 22) in which the conveyed decarbonated particles (16) release a portion of their thermal energy to second (14) and/or third gases (14); and providing substantially pure oxygen to the reactor (8) at an oxygen entrance point which is preferably located below one or more fuel entrance points. Waste heat and/or vented gas may be recovered and re-used within the process by virtue of unique configurations of the device and provision of novel apparatus to the device.