Patent classifications
C04B7/13
Hydraulic cement composition, process and use
- Gabriela Gon?alves Dias Ponzi ,
- FELIPE DALLA VECCHIA ,
- SANDRA MARA DE OLIVEIRA EINLOFT ,
- Marta Kerber Sch?tz ,
- VICTOR HUGO JACKS MENDES DOS SANTOS ,
- DARLAN PONTIN ,
- RENAN BORDULIS MARTEL ,
- Amanda Sofia De Guimar?es E Stepanha ,
- DELLYO RICARDO DOS SANTOS ALVARES ,
- Sonia Maria Cabral De Menezes ,
- ANA PAULA SANTANA MUSSE
The present invention describes a hydraulic cement composition, process and use thereof, wherein the composition comprises a hydraulic cement composition with increased resistance against carbon dioxide (CO.sub.2) for application in reservoirs such as oil and gas and carbon capture and storage (CCS) wells; with improved performance of cement paste formulations as a material for application in primary, secondary cementing, recovery and/or plugging operations, of reservoirs/wells that operate with high CO.sub.2 content; as a technological alternative to guarantee the integrity of wells in CO.sub.2-rich environments for long periods of time, without any additional intervention to the already current operational procedures for cementing wells, and with cost reduction in relation to class G cement (currently, the main raw material); and sufficient chemical resistance to carry out enhanced oil (EOR) and gas (EGR) recovery by injecting high levels of CO.sub.2, increasing reservoir pressure throughout the extraction period of hydrocarbon reservoirs.
Hydraulic cement composition, process and use
- Gabriela Gon?alves Dias Ponzi ,
- FELIPE DALLA VECCHIA ,
- SANDRA MARA DE OLIVEIRA EINLOFT ,
- Marta Kerber Sch?tz ,
- VICTOR HUGO JACKS MENDES DOS SANTOS ,
- DARLAN PONTIN ,
- RENAN BORDULIS MARTEL ,
- Amanda Sofia De Guimar?es E Stepanha ,
- DELLYO RICARDO DOS SANTOS ALVARES ,
- Sonia Maria Cabral De Menezes ,
- ANA PAULA SANTANA MUSSE
The present invention describes a hydraulic cement composition, process and use thereof, wherein the composition comprises a hydraulic cement composition with increased resistance against carbon dioxide (CO.sub.2) for application in reservoirs such as oil and gas and carbon capture and storage (CCS) wells; with improved performance of cement paste formulations as a material for application in primary, secondary cementing, recovery and/or plugging operations, of reservoirs/wells that operate with high CO.sub.2 content; as a technological alternative to guarantee the integrity of wells in CO.sub.2-rich environments for long periods of time, without any additional intervention to the already current operational procedures for cementing wells, and with cost reduction in relation to class G cement (currently, the main raw material); and sufficient chemical resistance to carry out enhanced oil (EOR) and gas (EGR) recovery by injecting high levels of CO.sub.2, increasing reservoir pressure throughout the extraction period of hydrocarbon reservoirs.
Rapid-setting hydraulic binder composition
The present invention relates to a rapid-setting hydraulic binder composition and, more specifically, to a hydraulic binder composition, which contains tricalcium aluminate (C3A) and dodecacalcium heptaaluminate (C12A7), and thus is rapidly set, has an easily adjustable setting time, and is bio-friendly.
Rapid-setting hydraulic binder composition
The present invention relates to a rapid-setting hydraulic binder composition and, more specifically, to a hydraulic binder composition, which contains tricalcium aluminate (C3A) and dodecacalcium heptaaluminate (C12A7), and thus is rapidly set, has an easily adjustable setting time, and is bio-friendly.
PERFORMANCE-ENHANCING PARTICULATE PREMIX COMPRISED OF MINERAL FINES TREATED WITH ONE OR MORE ADDITIVES
Performance-enhancing particulate premixes contain mineral fines treated with one or more performance-enhancing additives. Also disclosed are methods of manufacturing performance-enhancing particulate premixes and cementitious compositions that incorporate such performance-enhancing particulate premixes, a hydraulic cement binder, and optionally one or more supplementary cementitious materials (SCMs). The cementitious compositions can be dry cementitious compositions, fresh cementitious compositions (e.g., mixed with water to form a shapable mix), and hardened cementitious compositions (e.g., that contained hydrated cement). The performance-enhancing particulate premix can be formulated and manufactured to offset an increase in water demand and increase flow when used to replace a portion of Portland cement in concrete. For example, mineral fines are treated to yield performance-enhancing particulate premixes comprising one or more types of mineral fines and one or more types of water reducers.
PERFORMANCE-ENHANCING PARTICULATE PREMIX COMPRISED OF MINERAL FINES TREATED WITH ONE OR MORE ADDITIVES
Performance-enhancing particulate premixes contain mineral fines treated with one or more performance-enhancing additives. Also disclosed are methods of manufacturing performance-enhancing particulate premixes and cementitious compositions that incorporate such performance-enhancing particulate premixes, a hydraulic cement binder, and optionally one or more supplementary cementitious materials (SCMs). The cementitious compositions can be dry cementitious compositions, fresh cementitious compositions (e.g., mixed with water to form a shapable mix), and hardened cementitious compositions (e.g., that contained hydrated cement). The performance-enhancing particulate premix can be formulated and manufactured to offset an increase in water demand and increase flow when used to replace a portion of Portland cement in concrete. For example, mineral fines are treated to yield performance-enhancing particulate premixes comprising one or more types of mineral fines and one or more types of water reducers.
SUPPLEMENTARY CEMENTITIOUS MATERIAL MADE OF ALUMINIUM SILICATE AND DOLOMITE
This invention relates to a method for producing a supplementary cementitious material comprising the steps: providing a starting material containing dolomite and aluminium silicate, converting the starting material to the supplementary cementitious material by burning under reducing conditions in the temperature range of >700 to 1100 C. or by burning in the temperature range of 625 to 950 C. in the presence of a mineraliser, and cooling the supplementary cementitious material. The invention further relates to a binder comprising cement and to the ground supplementary cementitious material.
Activitation of natural pozzolans
An activated pozzolan composition includes a fine interground particulate blend of an initially unactivated natural pozzolan and a supplementary cementitious material (SCM) different than the initially unactivated natural pozzolan. The initially unactivated natural pozzolan may include volcanic ash or other natural pozzolanic deposit having a moisture content of at least 3%, and the activated pozzolan composition can have a moisture content less than 0.5% The initially unactivated natural pozzolan may have a particle size less than 1 mm before intergrinding with the SCM. The SCM used to activate the initially unactivated natural pozzolan can be initially coarse or granular with a size greater than 1-3 m and may include granulated blast furnace slag, steel slag, other metallurgical slag, pumice, limestone, fine aggregate, shale, tuff, trass, geologic material, waste glass, glass shards, basalt, sinters, ceramics, recycled bricks, recycled concrete, refractory materials, other waste industrial products, sand, or natural mineral.
Activitation of natural pozzolans
An activated pozzolan composition includes a fine interground particulate blend of an initially unactivated natural pozzolan and a supplementary cementitious material (SCM) different than the initially unactivated natural pozzolan. The initially unactivated natural pozzolan may include volcanic ash or other natural pozzolanic deposit having a moisture content of at least 3%, and the activated pozzolan composition can have a moisture content less than 0.5% The initially unactivated natural pozzolan may have a particle size less than 1 mm before intergrinding with the SCM. The SCM used to activate the initially unactivated natural pozzolan can be initially coarse or granular with a size greater than 1-3 m and may include granulated blast furnace slag, steel slag, other metallurgical slag, pumice, limestone, fine aggregate, shale, tuff, trass, geologic material, waste glass, glass shards, basalt, sinters, ceramics, recycled bricks, recycled concrete, refractory materials, other waste industrial products, sand, or natural mineral.
PROCESS FOR CO2 MINERALIZATION WITH NATURAL MINERAL PHASES AND USE OF THE PRODUCTS OBTAINED
There is a process of CO.sub.2 mineralization with natural mineral phases with prevalent alkaline-earth metals silicate content producing a mixture of magnesium carbonate, amorphous silica and other possibly non-reacted or non-mineralizable phases. The material thus obtained, after being washed with water, develops pozzolanic properties and can be used for formulating cements.