A plant may include an offgas-producing treatment apparatus for mechanical and/or thermal treatment of an inorganic material, an oxidation catalyst downstream of the offgas-producing treatment apparatus in a flow direction of the offgas, a reduction catalyst downstream of the oxidation catalyst in the flow direction of the offgas, and a temperature-affecting apparatus for affecting the temperature of the offgas upstream of the oxidation catalyst and/or between the oxidation catalyst and the reduction catalyst. In some examples, the the temperature-affecting apparatus is controllable and may comprise at least one of an auxiliary preheater, a mixing-in device for a fluid, or a heat exchanger.

The invention relates to a process plant (20) for converting a solid input material into a solid process product. The process plant (20) includes a calciner which is connected to a heat exchanger (26) and to which the input material can be continuously supplied for heating in order to transform the input material into an intermediate product. In the process plant (20) there is a kiln for converting the intermediate product into the process product by means of thermal treatment, raw gas being produced in doing so. The process plant (20) has a raw gas line system (50) comprising a raw gas line (50.1) which extends from the kiln to the calciner and through which the raw gas can flow from the kiln into the calciner for transferring raw gas heat to the input material, and includes a cooling device for cooling the process product after the thermal treatment in the kiln by transferring heat from the process product to a cooling gas containing oxygen, as a result of which a hot gas containing oxygen is generated. According to the invention, in the process plant (20) there is a waste air purification device for oxidizing raw gas, which is connected to the calciner via a raw gas line system (50), wherein a hot gas line system which is used for supplying hot gas generated from the cooling device is attached to the raw gas line system (50). The invention also relates to a method for converting a solid input material into a solid process product and to a method for purifying raw gas produced during the manufacture of cement.

The invention relates to a process plant (20) for converting a solid input material into a solid process product. The process plant (20) includes a calciner which is connected to a heat exchanger (26) and to which the input material can be continuously supplied for heating in order to transform the input material into an intermediate product. In the process plant (20) there is a kiln for converting the intermediate product into the process product by means of thermal treatment, raw gas being produced in doing so. The process plant (20) has a raw gas line system (50) comprising a raw gas line (50.1) which extends from the kiln to the calciner and through which the raw gas can flow from the kiln into the calciner for transferring raw gas heat to the input material, and includes a cooling device for cooling the process product after the thermal treatment in the kiln by transferring heat from the process product to a cooling gas containing oxygen, as a result of which a hot gas containing oxygen is generated. According to the invention, in the process plant (20) there is a waste air purification device for oxidizing raw gas, which is connected to the calciner via a raw gas line system (50), wherein a hot gas line system which is used for supplying hot gas generated from the cooling device is attached to the raw gas line system (50). The invention also relates to a method for converting a solid input material into a solid process product and to a method for purifying raw gas produced during the manufacture of cement.

An offgas treatment apparatus having a reduction catalyst and an oxidation catalyst downstream of the reduction catalyst may also include a temperature-affecting apparatus for the offgas positioned between the reduction catalyst and the oxidation catalyst. In some examples, the apparatus may include a second temperature-affecting apparatus for the offgas positioned upstream of the reduction catalyst. At least one of the first or second temperature affecting apparatuses may comprise a heat exchanger, a preheating apparatus, an auxiliary heater, or a mixing-in device for a fluid, for instance. In some examples, the apparatus may involve a dust filter positioned upstream of the reduction catalyst.

Methods and apparatus for reducing the content of controlled acidic pollutants in clinker kiln emissions are disclosed. The methods and apparatus include introducing bypass dust produced during production of clinker into one or more locations between the preheater exhaust and the inlet to a dust filter including into a gas conditioning tower. Total bypass dust separated from the kiln exhaust gas may be used. The bypass dust can be separated into a fine and coarse portions. Fine or total bypass dust can be mixed with water to form a bypass dust slurry that can be introduced into the gas conditioning tower. Bypass dust can be used to reduce the content of acidic pollutants such as hydrogen chloride HCl and sulfur oxides SO.sub.x from clinker kiln emissions.

An apparatus for producing cement clinker, comprising a kiln for calcining raw materials to form cement clinker, comprising a preheating stage for preheating the raw materials in a counter-flow to kiln off-gases, comprising a clinker cooler for cooling the cement clinker, comprising a denoxing stage for denoxing kiln off-gases, comprising a heat exchanger for heating the kiln off-gases upstream of the denoxing stage by heat exchange with a heat exchange medium, comprising at least one further heat exchanger for heating the heat exchange medium by heat exchange with kiln off-gases or exhaust air of the clinker cooler, wherein the heat exchanger is connected to the further heat exchanger via a line for the heat exchange medium, wherein a hot gas filter is arranged in the flow direction upstream of the further heat exchanger.

Methods and apparatus for reducing the content of controlled acidic pollutants in clinker kiln emissions are disclosed. The methods and apparatus include introducing bypass dust produced during production of clinker into one or more locations between the preheater exhaust and the inlet to a dust filter including into a gas conditioning tower. Total bypass dust separated from the kiln exhaust gas may be used. The bypass dust can be separated into a fine and coarse portions. Fine or total bypass dust can be mixed with water to form a bypass dust slurry that can be introduced into the gas conditioning tower. Bypass dust can be used to reduce the content of acidic pollutants such as hydrogen chloride HCl and sulfur oxides SO.sub.x from clinker kiln emissions.

A method for reducing pollution in a cement kiln environment and a system for treating cement kiln exhaust gas are provided. The method includes the steps of: treating a cement kiln exhaust gas stream with a treating fluid, such as a water soluble alkaline-earth metal sulfide. In one application, the treating fluid is injected by spraying droplets into the cement kiln exhaust gas stream. A system for treating cement kiln exhaust gas includes a reagent containing a water soluble alkaline-earth metal sulfide in water, and a nozzle to spray the reagent into the cement kiln exhaust gas stream.

A combustion gas bleeding probe includes a gas pipe for bleeding a part of a combustion gas from a kiln, and a plurality of discharge ports each of which is provided penetrating through the gas pipe and each of which discharges a low-temperature gas in a direction that is perpendicular to a direction of flow of a bleed gas bled by the gas pipe and that is directed toward a center of the flow of the bleed gas. The discharge ports discharge the low-temperature gas such that a ratio of a momentum of the low-temperature gas per discharge port to a momentum of the bleed gas satisfies 1.2 to 4.0, and a value (m1) obtained by dividing a ratio of a wind speed of the low-temperature gas to a wind speed of the bleed gas by an inner diameter of the gas pipe satisfies 1.5 to 3.5.

A method for denitrification of flue gases and a system, wherein flue gases generated in a rotary kiln are conveyed to a calcining zone for the deacidification of raw cement meal. Aqueous ammonia solution, ammonia, or ammonia-releasing substances for denitrifying the flue gases injected into the calcining zone according to the method of selective non-catalytic reduction (SNCR), and the flue gas stream, together with an ammonia slip generated during the denitrification, is passed through a heat exchanger and through at least one dedusting device. The flue gas is guided through a exhaust gas line via a catalyst for the decomposition of excess ammonia with residues of nitrogen oxide in accordance with a method of selective catalytic reduction (SCR), wherein the catalyst is arranged in a reactor provided in the exhaust line, and is no larger than is required for a sufficient decomposition of the ammonia.