The invention relates to a mineral binder suitable for use in binding aggregate in a mineral mortar or concrete mixture, said binder comprising the following components:

a) at least 40 wt % of calcined kaolinitic clay and ultrafine crushed CDW,
wherein the ratio between calcined clay and ultrafine crushed CDW is between 3:7 and 1:1 (w/w),
b) optionally 2-50 wt. % of a chemical activator; and
wherein the calcined kaolinitic clay, the ultrafine crushed CDW and the optionally present chemical activator are present in a combined amount of at least 90 wt. %, based on the total weight of the binder. The invention further relates to mineral mortar or concrete mixtures based on this mineral binder, as well as building units made from these mixtures.

A method of preparing a carbonated supplementary cementitious materials, includes carbonating the carbonatable mixture to obtain a first carbonated cementitious material, milling the first carbonated cementitious material, and carbonating the milled mixture to obtain the carbonated supplementary cementitious material.

A composition is provided. The composition consists essentially of (a) 1 to 30 wt. % of a hydrogen phosphate selected from the group consisting of mono and dihydrogen phosphates of sodium, potassium, ammonium, magnesium, calcium, aluminium, zinc, iron, cobalt, and copper; (b) 1 to 40 wt. % of a compound selected from the group consisting of oxides, hydroxides, and oxide hydrates of magnesium, calcium, iron, zinc, and copper; (c) 40 to 95 wt. % of a particulate filler selected from the group consisting of glass; mono-, oligo- and poly-phosphates of magnesium, calcium, barium and aluminum; calcium sulfate; barium sulfate; simple and complex silicates; simple and complex aluminates; simple and complex titanates; simple and complex zirconates; zirconium dioxide; titanium dioxide; aluminum oxide; silicon dioxide; silicon carbide; aluminum nitride; boron nitride and silicon nitride; and (d) 0 to 25 wt. % of a constituent that differs from constituents (a) to (c).

Method for the production of granulate materials designed to be used for manufacturing articles in slab or block form from a mixture. The method comprises the steps of a) melting a mixture of selected minerals having a specific chemical composition for obtaining a casting of molten material, c) cooling the cast material until a predetermined temperature is reached and d) crushing and/or grinding the material to obtain granules having a selected grain size and suitable for use respectively as aggregates or fillers in the mixture for manufacture of the articles. Moreover, the method comprises, downstream of the melting and casting step a), a step b) of keeping the molten and cooled material at a temperature of between 1030-1170° C. for a predetermined time period of at least 15 minutes. The granulate materials thus obtained have a content of silicon dioxide in crystalline form of less than 1%. The invention also relates to a plant for the production of granulate materials suitable for use as aggregates or fillers for the manufacture of articles in slab or block form.

The invention provides a high temperature resistant Portland cement slurry and a production method thereof. The high temperature resistant Portland cement slurry comprises the following components by weight: 100 parts of an oil well Portland cement, 60-85 parts of a high temperature reinforcing material, 68-80 parts of fresh water, 1-200 parts of a density adjuster, 0.1-1.5 parts of a suspension stabilizer, 0.8-1.5 parts of a dispersant, 3-4 parts of a fluid loss agent, 0-3 parts of a retarder and 0.2-0.8 part of a defoamer. The high temperature resistant Portland cement slurry has a good sedimentation stability at normal temperature, and develops strength rapidly at a low temperature. The compressive strength is up to 40 MPa or more at a high temperature of 350° C., and the long-term high-temperature compressive strength develops stably without degradation. Therefore, it can meet the requirements for field application in heavy oil thermal recovery wells, reaching the level of Grade G Portland cement for cementing oil and gas wells.

The invention provides a high temperature resistant Portland cement slurry and a production method thereof. The high temperature resistant Portland cement slurry comprises the following components by weight: 100 parts of an oil well Portland cement, 60-85 parts of a high temperature reinforcing material, 68-80 parts of fresh water, 1-200 parts of a density adjuster, 0.1-1.5 parts of a suspension stabilizer, 0.8-1.5 parts of a dispersant, 3-4 parts of a fluid loss agent, 0-3 parts of a retarder and 0.2-0.8 part of a defoamer. The high temperature resistant Portland cement slurry has a good sedimentation stability at normal temperature, and develops strength rapidly at a low temperature. The compressive strength is up to 40 MPa or more at a high temperature of 350° C., and the long-term high-temperature compressive strength develops stably without degradation. Therefore, it can meet the requirements for field application in heavy oil thermal recovery wells, reaching the level of Grade G Portland cement for cementing oil and gas wells.

The invention provides a high temperature resistant Portland cement slurry and a production method thereof. The high temperature resistant Portland cement slurry comprises the following components by weight: 100 parts of an oil well Portland cement, 60-85 parts of a high temperature reinforcing material, 68-80 parts of fresh water, 1-200 parts of a density adjuster, 0.1-1.5 parts of a suspension stabilizer, 0.8-1.5 parts of a dispersant, 3-4 parts of a fluid loss agent, 0-3 parts of a retarder and 0.2-0.8 part of a defoamer. The high temperature resistant Portland cement slurry has a good sedimentation stability at normal temperature, and develops strength rapidly at a low temperature. The compressive strength is up to 40 MPa or more at a high temperature of 350° C., and the long-term high-temperature compressive strength develops stably without degradation. Therefore, it can meet the requirements for field application in heavy oil thermal recovery wells, reaching the level of Grade G Portland cement for cementing oil and gas wells.

A method for making a carbonated precast concrete product includes: obtaining a mixture including at least one binder material, an aggregate, and water; molding the mixture into a molded intermediate; demolding the molded intermediate to obtain a demolded intermediate, the demolded intermediate having a first water-to-binder ratio; conditioning the demolded intermediate to provide a conditioned article having a second water-to-binder ratio less than the first water-to-binder ratio of the demolded intermediate; moisturizing at least one surface of the conditioned article with an aqueous medium, thereby causing a weight gain of the conditioned article and providing a moisturized product, a first portion of the moisturized product having a third water-to-binder ratio greater than a fourth water-to-binder ratio of a remainder of the moisturized product; and curing the moisturized product with carbon dioxide to obtain the carbonated precast concrete product.

A method for making a carbonated precast concrete product includes: obtaining a mixture including at least one binder material, an aggregate, and water; molding the mixture into a molded intermediate; demolding the molded intermediate to obtain a demolded intermediate, the demolded intermediate having a first water-to-binder ratio; conditioning the demolded intermediate to provide a conditioned article having a second water-to-binder ratio less than the first water-to-binder ratio of the demolded intermediate; moisturizing at least one surface of the conditioned article with an aqueous medium, thereby causing a weight gain of the conditioned article and providing a moisturized product, a first portion of the moisturized product having a third water-to-binder ratio greater than a fourth water-to-binder ratio of a remainder of the moisturized product; and curing the moisturized product with carbon dioxide to obtain the carbonated precast concrete product.

A radiation shield unit, which shields against neutron rays, X-rays, and γ-rays, contains 10 vol % or more and 90 vol % or less of gadolinium.