The invention relates to a system for asbestos neutralization, that comprises a neutralization unit comprising, in an atmospheric containment: a module for sorting of asbestos waste, an asbestos waste grinder, which reduces the size of the asbestos waste to a dimension ranging from one-tenth of a millimeter to one millimeter, a concentrated sulfuric acid tank, a vat containing a hot diluted acid solution, for which temperature is between 70 C. and 100 C., in which grinded asbestos waste containing asbestos is dipped, said solution neutralizing asbestos contained in the grinded asbestos waste, a filtration unit to separate, at the end of the neutralization reaction, a solid inert waste from a liquid phase of the diluted acid solution, a regeneration unit for the diluted acid solution, which adjusts the hydrogen potential of the extracted liquid phase by adding concentrated sulfuric acid from the tank, and means for transferring the regenerated solution into the vat.

Provided herein are methods and compositions utilizing one or more cementitious replacement materials, one or more alkaline activating materials, and, optionally one or more bonding materials and/or one or more setting time enhancer materials. The one or more cement precursors comprises one or more of non-radioactive nuclear waste; swarf, insoluble hydroxide of carbonate salts, radioactive wastes, petroleum coke, spent solvent wastes, electroporating and other metal finishing wastes, dioxin-bearing wastes, chlorinated aliphatic hydrocarbons production, wood preserving wastes, petroleum refinery wastewater treatment sludges, multisource leachate, organic chemicals manufacturing waste, pesticide manufacturing waste, petroleum refining waste, human pharmaceuticals manufacturing waste; veterinary pharmaceuticals manufacturing waste; inorganic pigment manufacturing waste; inorganic chemicals manufacturing waste; explosives manufacturing waste; iron and/or steel production waste; primary aluminum production waste; secondary lead processing waste; ink formulation waste; coking waste; or a combination thereof. The one or more alkaline activating agents comprises potassium silicate, potassium hydroxide, sodium hydroxide, sodium silicate, calcium hydroxide, magnesium hydroxide, reactive magnesium oxide, calcium chloride, sodium carbonate, silicone dioxide, sodium aluminate, calcium sulfate, sodium sulfate, or dolomite, or a combination thereof. The system comprises a vertical impact mill.

Provided herein are methods and compositions utilizing one or more cementitious replacement materials, one or more alkaline activating materials, and, optionally one or more bonding materials and/or one or more setting time enhancer materials. The one or more cement precursors comprises one or more of non-radioactive nuclear waste; swarf, insoluble hydroxide of carbonate salts, radioactive wastes, petroleum coke, spent solvent wastes, electroporating and other metal finishing wastes, dioxin-bearing wastes, chlorinated aliphatic hydrocarbons production, wood preserving wastes, petroleum refinery wastewater treatment sludges, multisource leachate, organic chemicals manufacturing waste, pesticide manufacturing waste, petroleum refining waste, human pharmaceuticals manufacturing waste; veterinary pharmaceuticals manufacturing waste; inorganic pigment manufacturing waste; inorganic chemicals manufacturing waste; explosives manufacturing waste; iron and/or steel production waste; primary aluminum production waste; secondary lead processing waste; ink formulation waste; coking waste; or a combination thereof. The one or more alkaline activating agents comprises potassium silicate, potassium hydroxide, sodium hydroxide, sodium silicate, calcium hydroxide, magnesium hydroxide, reactive magnesium oxide, calcium chloride, sodium carbonate, silicone dioxide, sodium aluminate, calcium sulfate, sodium sulfate, or dolomite, or a combination thereof. The system comprises a vertical impact mill.

The invention relates to a system for neutralizing asbestos, said system comprising a mobile neutralization unit (200) comprising: an asbestos waste sorting module (225), an asbestos grinder (255) and a hot acid bath (250) for rendering asbestos inert. Preferably, the asbestos waste sorting module comprises: a window with glove boxes; and a conveyor for transporting the asbestos waste in front of the window. In embodiments, the system comprises a means for containing the atmosphere within the mobile neutralization unit and/or the hot acid bath (250) of the mobile neutralization unit (200) comprises sulfuric acid.

This invention relates to a solidifying agent for solidifying radioactive waste, and more particularly to a solidifying-agent composition for solidifying radioactive waste, including alumina cement and a gypsum powder. The solidifying-agent composition including alumina cement and a gypsum powder is capable of effectively minimizing an increase in the volume of a solidified radioactive waste product to a level satisfying physical and chemical safety regulations upon the solidification of radioactive waste.

This invention relates to a solidifying agent for solidifying radioactive waste, and more particularly to a solidifying-agent composition for solidifying radioactive waste, including alumina cement and a gypsum powder. The solidifying-agent composition including alumina cement and a gypsum powder is capable of effectively minimizing an increase in the volume of a solidified radioactive waste product to a level satisfying physical and chemical safety regulations upon the solidification of radioactive waste.

The asbestos waste neutralization device (10) comprises: an acid tank (23), a vat (16) containing a diluted acid solution, in which waste containing asbestos is dipped, with this solution neutralizing the asbestos waste, a filtration unit (21) to separate, at the end of the neutralization reaction, the solid inert waste from the liquid phase of the acid solution, a regeneration unit (22) for the attacking acid solution, which adjusts the hydrogen potential of the extracted liquid phase by adding concentrated acid contained in the acid reservoir, and means for transferring the regenerated solution into the vat.

This invention relates to a solidifying agent for solidifying radioactive waste, and more particularly to a solidifying-agent composition for solidifying radioactive waste, including alumina cement and a gypsum powder. The solidifying-agent composition including alumina cement and a gypsum powder is capable of effectively minimizing an increase in the volume of a solidified radioactive waste product to a level satisfying physical and chemical safety regulations upon the solidification of radioactive waste.

This invention relates to a solidifying agent for solidifying radioactive waste, and more particularly to a solidifying-agent composition for solidifying radioactive waste, including alumina cement and a gypsum powder. The solidifying-agent composition including alumina cement and a gypsum powder is capable of effectively minimizing an increase in the volume of a solidified radioactive waste product to a level satisfying physical and chemical safety regulations upon the solidification of radioactive waste.

Treatment of a radioactive waste stream is provided by adding sodium hydroxide (NaOH) and/or potassium hydroxide (KOH) together with a rapidly dissolving form of silica, e.g., fumed silica or fly ash. Alternatively, the fumed silica can be first dissolved in a NaOH/KOH solution, which is then combined with the waste solution. Adding a binder that can be a mixture of metakaolin (Al.sub.2O.sub.3.2SiO.sub.2), ground blast furnace slag, fly ash, or other additives. Adding an enhancer that can be composed of a group of additives that are used to further enhance the immobilization of heavy metals and key radionuclides such as .sup.99Tc and .sup.129I. An additional step can involve simple mixing of the binder with the activator and enhancer, which can occur in the final waste form container, or in a mixing vessel prior to pumping into the final waste form container, depending on the particular application.