A method of pumping a fluid and reactive solid into a mineral formation includes the fluid reacting with the mineral formation to produce a nucleation product. The method may be used in shale formations to seal fissures and prevent leakage. The fluid used in this method may comprise CO.sub.2 and the nucleation products may be the products of carbonation reactions. A cement formed by reacting CO.sub.2 with a reactive solid under deep geological formation conditions is also disclosed.

Roofing granules comprising agglomerated inorganic material, and building materials, such as shingles, that include such roofing granules. By fabricating roofing granules from agglomerating inorganic material it is possible to tailor the particle size distribution so as to provide optimal shingle surface coverage, thus reducing shingle weight and usage of raw materials. Additionally, the use of agglomeration permits the utilization of by-products from conventional granule production processes.

A method may include providing a cement composition comprising ground vitrified clay, hydrated lime, and water; and introducing the cement composition into a subterranean formation.

A method for processing incinerator bottom ash (IBA) comprises the steps of carbonating IBA aggregate material by CO.sub.2 sequestration and providing a stabilizing additive for mixing with the carbonated IBA aggregate material, wherein the additive comprises one or more components from group (b1) and one or more components from group (b2), wherein group (b1) consists of aluminium chloride and at least one other metal chloride, and wherein group (b2) consists of silica, zeolite and apatite. When the carbonated IBA and additive is mixed a stabilized IBA composition is formed, the stabilized IBA composition being suitable for use as a substitute for traditional aggregates in the manufacture of concrete and concrete products.

A method for processing incinerator bottom ash (IBA) comprises the steps of carbonating IBA aggregate material by CO.sub.2 sequestration and providing a stabilizing additive for mixing with the carbonated IBA aggregate material, wherein the additive comprises one or more components from group (b1) and one or more components from group (b2), wherein group (b1) consists of aluminium chloride and at least one other metal chloride, and wherein group (b2) consists of silica, zeolite and apatite. When the carbonated IBA and additive is mixed a stabilized IBA composition is formed, the stabilized IBA composition being suitable for use as a substitute for traditional aggregates in the manufacture of concrete and concrete products.

A method for processing incinerator bottom ash (IBA) comprises the steps of carbonating IBA aggregate material by CO.sub.2 sequestration and providing a stabilizing additive for mixing with the carbonated IBA aggregate material, wherein the additive comprises one or more components from group (b1) and one or more components from group (b2), wherein group (b1) consists of aluminium chloride and at least one other metal chloride, and wherein group (b2) consists of silica, zeolite and apatite. When the carbonated IBA and additive is mixed a stabilized IBA composition is formed, the stabilized IBA composition being suitable for use as a substitute for traditional aggregates in the manufacture of concrete and concrete products.

A method and composition are provided for backfilling the annular gap created as a tunnel boring machine advances through the ground. The fill material is comprised of two components that are combined and mixed together just prior to entering the annular gap. The first component is non-cement slurry consisting of a fluidized bed combustion ash such as coal ash. The second component consists of an alkali silicate such as sodium silicate. Additionally, ordinary Portland cement and/or metakaolin can be added to the grout composition.

A method and composition are provided for backfilling the annular gap created as a tunnel boring machine advances through the ground. The fill material is comprised of two components that are combined and mixed together just prior to entering the annular gap. The first component is non-cement slurry consisting of a fluidized bed combustion ash such as coal ash. The second component consists of an alkali silicate such as sodium silicate. Additionally, ordinary Portland cement and/or metakaolin can be added to the grout composition.

A method and composition are provided for backfilling the annular gap created as a tunnel boring machine advances through the ground. The fill material is comprised of two components that are combined and mixed together just prior to entering the annular gap. The first component is non-cement slurry consisting of a fluidized bed combustion ash such as coal ash. The second component consists of an alkali silicate such as sodium silicate. Additionally, ordinary Portland cement and/or metakaolin can be added to the grout composition.

Sorbent components containing halogen, calcium, alumina, and silica are used in combination during coal combustion to produce environmental benefits. Sorbents such as calcium bromide are added to the coal ahead of combustion and other components are added into the flame or downstream of the flame, preferably at minimum temperatures to assure complete formation of the refractory structures that result in various advantages of the methods. When used together, the components reduce emissions of elemental and oxidized mercury; increase the level of Hg, As, Pb, and/or Cl in the coal ash; decrease the levels of leachable heavy metals (such as Hg) in the ash, preferably to levels below the detectable limits; and make a highly cementitious ash product.