A geopolymer cement and a method of producing the same are provided. A geopolymer cement binder may be provided including a geopolymer precursor and magnesium oxide as an alkali activator. The geopolymer cement binder may be mixed with water using high shear mixing.

Adding a small amount of lightweight course aggregate to a normal weight concrete mix to produce a clean, rough top surface so that manual or mechanical roughing of the top surface is not necessary. The lightweight course aggregate will float to the surface, and make a rough surface so that the bond and shear resistance of the interface (cold joint) between previously placed and newly placed concrete will be as strong as a manually roughened joint.

Adding a small amount of lightweight course aggregate to a normal weight concrete mix to produce a clean, rough top surface so that manual or mechanical roughing of the top surface is not necessary. The lightweight course aggregate will float to the surface, and make a rough surface so that the bond and shear resistance of the interface (cold joint) between previously placed and newly placed concrete will be as strong as a manually roughened joint.

Some embodiments of the present invention comprise a method of cementing comprising: placing a settable composition into a well bore, the settable composition comprising remediated coal ash, hydraulic cement, and water; and allowing the settable composition to set. Other embodiments comprise a method of cementing comprising: placing a settable composition into a well bore, the settable composition comprising remediated coal ash, calcium hydroxide (lime), and water; and allowing the settable composition to set. Other embodiments comprise a settable composition comprising: remediated coal ash, hydraulic cement, calcium hydroxide, natural pozzolan and water; and allowing the composition to set. Other embodiments comprise a settable composition comprising remediated coal ash and any combination of hydraulic cement, calcium hydroxide, slag, fly ash, and natural or other pozzolan.

Some embodiments of the present invention comprise a method of cementing comprising: placing a settable composition into a well bore, the settable composition comprising remediated coal ash, hydraulic cement, and water; and allowing the settable composition to set. Other embodiments comprise a method of cementing comprising: placing a settable composition into a well bore, the settable composition comprising remediated coal ash, calcium hydroxide (lime), and water; and allowing the settable composition to set. Other embodiments comprise a settable composition comprising: remediated coal ash, hydraulic cement, calcium hydroxide, natural pozzolan and water; and allowing the composition to set. Other embodiments comprise a settable composition comprising remediated coal ash and any combination of hydraulic cement, calcium hydroxide, slag, fly ash, and natural or other pozzolan.

This invention relates to an adaptable Geopolymer cement composition for application in oil and gas wells having a wide range of downhole temperatures. The base Geopolymer cement composition has an acceptable rheology of below 200 cP and can be tailored by the inclusion of various chemicals to control properties such as thickening time over a wide range of temperatures and densities. The disclosed Geopolymer cement composition is pumpable, mixable and stable. The composition can also be adapted to have expandable and swellable properties.

This invention relates to an adaptable Geopolymer cement composition for application in oil and gas wells having a wide range of downhole temperatures. The base Geopolymer cement composition has an acceptable rheology of below 200 cP and can be tailored by the inclusion of various chemicals to control properties such as thickening time over a wide range of temperatures and densities. The disclosed Geopolymer cement composition is pumpable, mixable and stable. The composition can also be adapted to have expandable and swellable properties.

An ink formulation for additive manufacturing of low density syntactic foams is described. The ink formulation can include a thermoset resin, a curing agent suitable for use with the thermoset resin, a plurality of hollow spheres, such as glass microballoons, one or more solvents, and one or more non-hollow, viscosity modifying filler. Also described are a method of preparing the ink formulation, a method of preparing three-dimensional objects comprising low density syntactic foams, and the three-dimensional objects prepared thereby.

An ink formulation for additive manufacturing of low density syntactic foams is described. The ink formulation can include a thermoset resin, a curing agent suitable for use with the thermoset resin, a plurality of hollow spheres, such as glass microballoons, one or more solvents, and one or more non-hollow, viscosity modifying filler. Also described are a method of preparing the ink formulation, a method of preparing three-dimensional objects comprising low density syntactic foams, and the three-dimensional objects prepared thereby.

Provided are a textile reinforced cement composite for suppressing occurrence of slipping and a crack and a manufacturing method thereof. The textile reinforced cement composite for suppressing occurrence of slipping and a crack can suppress slipping between a textile grid reinforcement and a cement composite by using an angulated filling material mixed therewith when a textile reinforced cement composite having a textile grid reinforcement embedded in a cement composite is manufactured, suppress occurrence of a crack of the cement composite, suppress occurrence of a crack of the cement composite due to a fiber bridging reaction by using organic fiber mixed therewith, induce distribution of fine cracks, suppress degradation of fluidity of the cement composite caused by mixing of the angulated filling material by using a spherical binder and a chemical admixture added thereto, and suppress slipping between the textile grid reinforcement and the cement composite by using a fine powder binder having a predetermined particle size and mixed therewith.