A hardener composition can be used for a reactive resin system containing a reactive resin based on radically curable, ethylenically unsaturated compounds. The hardener composition contains a hardener for the reactive resin and a filler mixture. The filler mixture is composed of a first filler having a first average particle size d.sub.50,1 and a second filler having a second average particle size d.sub.50,2. The first average particle size d.sub.50,1 of the first filler is greater than the second average particle size d.sub.50,2 of the second filler (d.sub.50,1>d.sub.50,2). The ratio d.sub.50,1 to d.sub.50,2 (d.sub.50,1:d.sub.50,2) is in the range of 8:1 to 100:1. The filler mixture is useful, and a reaction resin system can contain the hardener composition.

A hardener composition can be used for a reactive resin system containing a reactive resin based on radically curable, ethylenically unsaturated compounds. The hardener composition contains a hardener for the reactive resin and a filler mixture. The filler mixture is composed of a first filler having a first average particle size d.sub.50,1 and a second filler having a second average particle size d.sub.50,2. The first average particle size d.sub.50,1 of the first filler is greater than the second average particle size d.sub.50,2 of the second filler (d.sub.50,1>d.sub.50,2). The ratio d.sub.50,1 to d.sub.50,2 (d.sub.50,1:d.sub.50,2) is in the range of 8:1 to 100:1. The filler mixture is useful, and a reaction resin system can contain the hardener composition.

A method of making a cement composite can include contacting an aqueous solution comprising calcium ions with a carbon dioxide source producing a carbonated aqueous solution. Fine particles can be submerged in the carbonated aqueous solution to produce microaggregate particles comprising the fine particles coated with calcium carbonate. The microaggregate particles can be combined with cement particles to produce the cement composite. The cement composite can be used in cementing applications for hydrocarbon wells including for casing liners and well plugs.

A method of making a cement composite can include contacting an aqueous solution comprising calcium ions with a carbon dioxide source producing a carbonated aqueous solution. Fine particles can be submerged in the carbonated aqueous solution to produce microaggregate particles comprising the fine particles coated with calcium carbonate. The microaggregate particles can be combined with cement particles to produce the cement composite. The cement composite can be used in cementing applications for hydrocarbon wells including for casing liners and well plugs.

The present invention relates to a material system for 3D printing, to a 3D printing process using a lignin-containing component or derivatives thereof or modified lignins, to soluble moldings that are produced by a powder-based additive layer manufacturing process and to the use of the moldings.

The present invention relates to a material system for 3D printing, to a 3D printing process using a lignin-containing component or derivatives thereof or modified lignins, to soluble moldings that are produced by a powder-based additive layer manufacturing process and to the use of the moldings.

Expansive cement compositions for use in subterranean wellbores that include a monophase amorphous hydraulic binder material (MAHBM). The MAHBM may include a plurality of particles having a silica core and an amorphous coating substantially surrounding the silica core. The coating may comprise, for example, a plurality of amorphous α-dicalcium silicate hydrate nanoparticles or microparticles. The MAHBM may be used as an expansion agent in a cement composition or used as an expansive cement by itself.

Expansive cement compositions for use in subterranean wellbores that include a monophase amorphous hydraulic binder material (MAHBM). The MAHBM may include a plurality of particles having a silica core and an amorphous coating substantially surrounding the silica core. The coating may comprise, for example, a plurality of amorphous α-dicalcium silicate hydrate nanoparticles or microparticles. The MAHBM may be used as an expansion agent in a cement composition or used as an expansive cement by itself.

Disclosed are: damage-resistant ECMCs that need to work and remain elastic between minus 120° C. and positive 300° C.; ECMCs that need to be able to contain a flame of 1900° C. for more than 90 minutes; and composite structures, especially highly stressed structures. One of the characteristic problems of ceramic matrices is their fragility. Indeed, when a fracture starts, it propagates easily in the matrix. Disclosed are elastic ceramic matrix composites (ECMCs), for which: the ceramic matrix is split into solid “ceramic microdomains” (CMDs); the CMDs are connected to one another by a dense network of “elastic microelements” (EMEs); and the bonds between the EMEs and the CMDs are strong chemical bonds, preferably covalent.

Disclosed are: damage-resistant ECMCs that need to work and remain elastic between minus 120° C. and positive 300° C.; ECMCs that need to be able to contain a flame of 1900° C. for more than 90 minutes; and composite structures, especially highly stressed structures. One of the characteristic problems of ceramic matrices is their fragility. Indeed, when a fracture starts, it propagates easily in the matrix. Disclosed are elastic ceramic matrix composites (ECMCs), for which: the ceramic matrix is split into solid “ceramic microdomains” (CMDs); the CMDs are connected to one another by a dense network of “elastic microelements” (EMEs); and the bonds between the EMEs and the CMDs are strong chemical bonds, preferably covalent.