An aqueous dispersion of graphene oxide is prepared in an additive process by subjecting graphitic carbon, such as biochar, in water or an aqueous solution to a high-shear environment in the presence of a dispersing agent to exfoliate graphene oxide. An intercalating agent may be added to facilitate exfoliation, and optionally neutralized. The graphitic carbon may be pre-processed by wet milling prior to exfoliation. The aqueous dispersion of graphene oxide may be used as a concrete admixture in a concrete composition.

An aqueous dispersion of graphene oxide is prepared in an additive process by subjecting graphitic carbon, such as biochar, in water or an aqueous solution to a high-shear environment in the presence of a dispersing agent to exfoliate graphene oxide. An intercalating agent may be added to facilitate exfoliation, and optionally neutralized. The graphitic carbon may be pre-processed by wet milling prior to exfoliation. The aqueous dispersion of graphene oxide may be used as a concrete admixture in a concrete composition.

Methods of making carbonate aggregates are provided. Aspects of the methods include: preparing a carbonate slurry, subjecting the carbonate slurry to rotational action, e.g., by introducing the carbonate slurry (optionally with an aggregate substrate) into a revolving drum under conditions sufficient to produce a carbonate aggregate, e.g., made up of a spherical coating on a substrate and/or agglomeration particles. Also provided are aggregate compositions produced by the methods, as well as compositions that includes the carbonate coated aggregates, e.g., concretes, and uses thereof.

Methods of making carbonate aggregates are provided. Aspects of the methods include: preparing a carbonate slurry, subjecting the carbonate slurry to rotational action, e.g., by introducing the carbonate slurry (optionally with an aggregate substrate) into a revolving drum under conditions sufficient to produce a carbonate aggregate, e.g., made up of a spherical coating on a substrate and/or agglomeration particles. Also provided are aggregate compositions produced by the methods, as well as compositions that includes the carbonate coated aggregates, e.g., concretes, and uses thereof.

A method for manufacturing a binder of a hydratable material includes providing a starting material from one or more raw materials convertible by tempering at 600 to 1200° C. into the hydratable material and tempering the starting material to provide the hydratable material containing not more than 10% by weight monocalcium silicate and at least 15% by weight hydratable phases in the form of lime and dicalcium silicate. The residence time and the tempering temperature are adapted to obtain the hydratable material by converting not more than 80% by weight of the starting material, and the hydratable material is then cooled to provide the binder comprising the hydratable material. The binder can be mixed with water and optionally one or more of aggregate, additives, admixtures to obtain a binder paste that is placed, hydrated and carbonated to produce a building product.

A method for manufacturing a binder of a hydratable material includes providing a starting material from one or more raw materials convertible by tempering at 600 to 1200° C. into the hydratable material and tempering the starting material to provide the hydratable material containing not more than 10% by weight monocalcium silicate and at least 15% by weight hydratable phases in the form of lime and dicalcium silicate. The residence time and the tempering temperature are adapted to obtain the hydratable material by converting not more than 80% by weight of the starting material, and the hydratable material is then cooled to provide the binder comprising the hydratable material. The binder can be mixed with water and optionally one or more of aggregate, additives, admixtures to obtain a binder paste that is placed, hydrated and carbonated to produce a building product.

The present invention provides a method for manufacturing a composite carbonate in a semi-dry manner by using combustion ash and, more specifically, provides a method for manufacturing a composite carbonate in a semi-dry manner by using combustion ash, the method comprising a step of adding a small amount of water to combustion ash containing calcium ions in an atmosphere of carbon dioxide. According to the present invention, carbon mineralization is carried out in a semi-dry manner by the manufacturing method, so that the composite carbonate can be efficiently produced. In addition, the composite carbonate can be utilized as a component for a concrete composition.

The present invention provides a method for manufacturing a composite carbonate in a semi-dry manner by using combustion ash and, more specifically, provides a method for manufacturing a composite carbonate in a semi-dry manner by using combustion ash, the method comprising a step of adding a small amount of water to combustion ash containing calcium ions in an atmosphere of carbon dioxide. According to the present invention, carbon mineralization is carried out in a semi-dry manner by the manufacturing method, so that the composite carbonate can be efficiently produced. In addition, the composite carbonate can be utilized as a component for a concrete composition.

A method for forming a treated reclaimed bottom ash sand and a treated reclaimed bottom ash sand. The method includes providing reclaimed bottom ash sand. The reclaimed bottom ash sand is contacted with an aqueous composition having 0.5 to 3.0 M NaOH for a time greater than about 4 hours. The NaOH contacted reclaimed bottom ash sand is rinsed and decanted and iron is removed to form a treated reclaimed bottom ash sand having reduced hydrogen formation in concrete compared to the hydrogen formation of concrete utilizing reclaimed bottom ash sand. The treated reclaimed bottom ash sand includes reactive aluminum of less than 50% by weight of the reactive aluminum in the reclaimed bottom ash sand and the treated reclaimed bottom ash sand includes less than 2 wt % iron. A concrete formed from the treated reclaimed bottom ash sand is also disclosed.

A method for forming a treated reclaimed bottom ash sand and a treated reclaimed bottom ash sand. The method includes providing reclaimed bottom ash sand. The reclaimed bottom ash sand is contacted with an aqueous composition having 0.5 to 3.0 M NaOH for a time greater than about 4 hours. The NaOH contacted reclaimed bottom ash sand is rinsed and decanted and iron is removed to form a treated reclaimed bottom ash sand having reduced hydrogen formation in concrete compared to the hydrogen formation of concrete utilizing reclaimed bottom ash sand. The treated reclaimed bottom ash sand includes reactive aluminum of less than 50% by weight of the reactive aluminum in the reclaimed bottom ash sand and the treated reclaimed bottom ash sand includes less than 2 wt % iron. A concrete formed from the treated reclaimed bottom ash sand is also disclosed.