A method for forming a super-insulating material for a vacuum insulated structure for an appliance includes disposing hollow glass spheres within a rotating drum, wherein a plurality of interstitial spaces are defined between the hollow glass spheres. An anchor material is disposed within the rotating drum. The hollow glass spheres and the anchor material are rotated within the rotating drum, wherein the anchor material is mixed with the hollow glass spheres to partially occupy the interstitial spaces. A silica-based material is disposed within the rotating drum. The silica-based material is mixed with the anchor material and the hollow glass spheres to define a super-insulating material, wherein the silica-based material attaches to the anchor material and is entrapped within the interstitial spaces. The silica-based material and the anchor material occupy substantially all of an interstitial volume defined by the interstitial spaces.

A composite material, compositions, processes and methods of using coal and coal by-products composite ceramics is provided for use as a safe, non-toxic material for construction, building and architecture components. The composite material disclosed herein is formed from resin/coal aggregates that contain and prevent the release of harmful impurities that naturally occur in both coal and coal by-products while the advantages of coal-based composites are made available to the building industry. The strength, density and porosity of the composites can be tailored within a wide range to fit the final application by controlling the materials, form factor and processing parameters during fabrication.

A composite material, compositions, processes and methods of using coal and coal by-products composite ceramics is provided for use as a safe, non-toxic material for construction, building and architecture components. The composite material disclosed herein is formed from resin/coal aggregates that contain and prevent the release of harmful impurities that naturally occur in both coal and coal by-products while the advantages of coal-based composites are made available to the building industry. The strength, density and porosity of the composites can be tailored within a wide range to fit the final application by controlling the materials, form factor and processing parameters during fabrication.

A method for preparing a vacuum insulated panel includes forming an internal cavity between a liner and a wrapper and preparing a filler material to be disposed in the internal cavity. The filler material includes a first part and a second part and is prepared by treating a surface of the first part. A coating is applied to the surface of the first part with a chemical having a first charge. The coating forms a first surface charge on the surface of the first part. The method further includes mixing the first part with the second part forming the filler material. The second part includes a material having a second surface charge opposite the first surface charge.

A method for preparing a vacuum insulated panel includes forming an internal cavity between a liner and a wrapper and preparing a filler material to be disposed in the internal cavity. The filler material includes a first part and a second part and is prepared by treating a surface of the first part. A coating is applied to the surface of the first part with a chemical having a first charge. The coating forms a first surface charge on the surface of the first part. The method further includes mixing the first part with the second part forming the filler material. The second part includes a material having a second surface charge opposite the first surface charge.

A composition comprising at least one binder coated with at least one metallate additive according to formula 1: (RO).sub.m—M—(O.sub.a—X.sub.bR′.sub.c—Y.sub.d).sub.n (formula 1), wherein M is one of titanium and zirconium. The composition is particularly useful in producing treated binders and construction materials, wherein the resulting treated binders and construction materials have advantageous properties, such as increased strength. Also disclosed are methods of preparing the inventive composition, treated binders and construction materials.

Granular and/or shaped hydrophobic silica useful for thermal insulation materials are prepared by mixing hydrophilic silica with a hydrophobicizing agent at low temperature so the hydrophobicizing agent does not appreciably react, followed by deaeration and compaction.

Granular and/or shaped hydrophobic silica useful for thermal insulation materials are prepared by mixing hydrophilic silica with a hydrophobicizing agent at low temperature so the hydrophobicizing agent does not appreciably react, followed by deaeration and compaction.

Provided are: a coated sand having improved fluidity and being capable of improving a filling rate of a casting mold to be obtained; and a coated sand for advantageously manufacturing a casting mold having excellent strength, which coated sand provides a casting mold with good mold-releasability and collapsibility, gives cast products a favorable casting surface, and effectively improves sand adhesion on cast products. The coated sand is formed as a dry granular material having fluidity at room temperature, in which the surface of a refractory aggregate is coated with a solid layer of a water-soluble inorganic binder, and spherical particles of silicone resin having binder-repellency exist on the surface of the binder layer, or form a layer on the surface of the binder layer, a part of the spherical particles being not covered with the water-soluble inorganic binder and being exposed.

Provided are: a coated sand having improved fluidity and being capable of improving a filling rate of a casting mold to be obtained; and a coated sand for advantageously manufacturing a casting mold having excellent strength, which coated sand provides a casting mold with good mold-releasability and collapsibility, gives cast products a favorable casting surface, and effectively improves sand adhesion on cast products. The coated sand is formed as a dry granular material having fluidity at room temperature, in which the surface of a refractory aggregate is coated with a solid layer of a water-soluble inorganic binder, and spherical particles of silicone resin having binder-repellency exist on the surface of the binder layer, or form a layer on the surface of the binder layer, a part of the spherical particles being not covered with the water-soluble inorganic binder and being exposed.