The invention relates to a process for the wet milling of slag, wherein more than 100 kWh of milling energy are introduced per metric ton of slag and the weight ratio of slag to water is 0.05-4:1 and from 0.005 to 2% by weight, based on the slag, of a milling auxiliary which comprises at least one compound selected from the group consisting of polycarboxylate ether, phosphated polycondensation product, lignosulfonate, melamine-formaldehyde sulfonate, naphthalene-formaldehyde sulfonate, monoglycols, diglycols, triglycols and polyglycols, polyalcohols, alkanolamine, amino acids, sugar, molasses and curing accelerators based on calcium silicate hydrate is added to the material being milled before or during the milling.

The invention relates to a process for the wet milling of slag, wherein more than 100 kWh of milling energy are introduced per metric ton of slag and the weight ratio of slag to water is 0.05-4:1 and from 0.005 to 2% by weight, based on the slag, of a milling auxiliary which comprises at least one compound selected from the group consisting of polycarboxylate ether, phosphated polycondensation product, lignosulfonate, melamine-formaldehyde sulfonate, naphthalene-formaldehyde sulfonate, monoglycols, diglycols, triglycols and polyglycols, polyalcohols, alkanolamine, amino acids, sugar, molasses and curing accelerators based on calcium silicate hydrate is added to the material being milled before or during the milling.

The invention discloses a calcium-alumino-silicate-hydrate nano-seeds suspension and preparation method thereof. The preparation method of calcium-alumino-silicate-hydrate nano-seeds suspension includes the following steps: dropwise adding the aqueous solution of calcium source, the aqueous solution of silicon source and the aqueous solution of aluminum source to the solution of polycarboxylate superplasticizer, and adjusting the pH value to 10.0˜13.5, and continuously stirring to obtain the calcium-alumino-silicate-hydrate nano-seeds suspension. The beneficial effect in the present invention is: the calcium-alumino-silicate-hydrate nano-seeds has small particle size, good dispersion stability, and it can effectively improve the early hydration and mechanical performance of cement-based materials, and has good application prospects; the preparation process is simple, without washing, drying, ultrasonic dispersion and other subsequent processes, suitable for large-scale production.

The invention discloses a calcium-alumino-silicate-hydrate nano-seeds suspension and preparation method thereof. The preparation method of calcium-alumino-silicate-hydrate nano-seeds suspension includes the following steps: dropwise adding the aqueous solution of calcium source, the aqueous solution of silicon source and the aqueous solution of aluminum source to the solution of polycarboxylate superplasticizer, and adjusting the pH value to 10.0˜13.5, and continuously stirring to obtain the calcium-alumino-silicate-hydrate nano-seeds suspension. The beneficial effect in the present invention is: the calcium-alumino-silicate-hydrate nano-seeds has small particle size, good dispersion stability, and it can effectively improve the early hydration and mechanical performance of cement-based materials, and has good application prospects; the preparation process is simple, without washing, drying, ultrasonic dispersion and other subsequent processes, suitable for large-scale production.

A process for the manufacturing of a slurry containing nucleating agents which comprises reacting at least one source of a Ca containing compound with at least one source of a Si containing compound, in an aqueous media and in the presence of a doping agent selected from the group consisting of P, B, S, and mixtures thereof; wherein: (i) the reaction is carried out at a temperature comprised from 100 to 350° C.; (ii) the total molar ratio Ca/Si is 1.5-2.5, and (iii) the total molar ratio doping agent/Si is 0.01-2; provided that: (a) when the sole doping agent is P, the total molar ratio P/Si is 0.1-2; (b) when the sole doping agent is B, the total molar ratio B/Si is 0.01-2, and (c) when the sole doping agent is S, the total molar ratio S/Si is 0.1-2.

A process for the manufacturing of a slurry containing nucleating agents which comprises reacting at least one source of a Ca containing compound with at least one source of a Si containing compound, in an aqueous media and in the presence of a doping agent selected from the group consisting of P, B, S, and mixtures thereof; wherein: (i) the reaction is carried out at a temperature comprised from 100 to 350° C.; (ii) the total molar ratio Ca/Si is 1.5-2.5, and (iii) the total molar ratio doping agent/Si is 0.01-2; provided that: (a) when the sole doping agent is P, the total molar ratio P/Si is 0.1-2; (b) when the sole doping agent is B, the total molar ratio B/Si is 0.01-2, and (c) when the sole doping agent is S, the total molar ratio S/Si is 0.1-2.

The object of the present invention is a novel admixture comprising a hardening accelerator for hydraulic compositions based on Portland cement and other supplementary cementitious materials.

An adjuvant combination composed of a milling assistant and a concrete admixture for a composition including cement, for accelerating cement hydration, wherein the milling assistant includes at least one amino alcohol and at least one cement hydration accelerator selected from chlorides, thiocyanates, nitrates, nitrites and hydroxides, and the concrete admixture includes a reaction product of at least one calcium compound with at least one silicon compound selected from a silicon dioxide compound, a silica compound and a silicate compound. Using the adjuvant combination produces a significant acceleration in the hardening of a composition including cement, after the addition of water. This is an advantage especially in the production of prefabricated concrete components, allowing quicker deshuttering.

An adjuvant combination composed of a milling assistant and a concrete admixture for a composition including cement, for accelerating cement hydration, wherein the milling assistant includes at least one amino alcohol and at least one cement hydration accelerator selected from chlorides, thiocyanates, nitrates, nitrites and hydroxides, and the concrete admixture includes a reaction product of at least one calcium compound with at least one silicon compound selected from a silicon dioxide compound, a silica compound and a silicate compound. Using the adjuvant combination produces a significant acceleration in the hardening of a composition including cement, after the addition of water. This is an advantage especially in the production of prefabricated concrete components, allowing quicker deshuttering.

A process for the production of a mineral foam includes separately preparing a slurry of cement and an aqueous foam, wherein the cement slurry includes water and Portland cement as well as calcium silicate hydrate crystallization seeds; contacting the slurry of cement with the aqueous foam to obtain a slurry of foamed cement; and casting the slurry of foamed cement and leave it to set.