Thermoset ceramic compositions and a method of preparation of such compositions. The compositions are advanced organic/inorganic hybrid composite polymer ceramic alloys. The material combines strength, hardness and high temperature performance of technical ceramics with the strength, ductility, thermal shock resistance, density, and easy processing of the polymer. Consisting of a branched backbone of silicon, and alumina, with highly coordinated Si—O—Si or Al—O—Al bonds, the material undergoes sintering at 7 to 300 centigrade for 2 to 94 hours from water at a pH between 0 to 14, humidity of 0 to 100%, with or without vaporous solvents.

Thermoset ceramic compositions and a method of preparation of such compositions. The compositions are advanced organic/inorganic hybrid composite polymer ceramic alloys. The material combines strength, hardness and high temperature performance of technical ceramics with the strength, ductility, thermal shock resistance, density, and easy processing of the polymer. Consisting of a branched backbone of silicon, and alumina, with highly coordinated Si—O—Si or Al—O—Al bonds, the material undergoes sintering at 7 to 300 centigrade for 2 to 94 hours from water at a pH between 0 to 14, humidity of 0 to 100%, with or without vaporous solvents.

Methods and systems of reducing lost circulation in a wellbore are provided. An example method includes providing a pozzolan slurry comprising a pozzolanic material and water; and providing a calcium slurry comprising a calcium source, a high pH activator, and water. The method further comprises allowing the pozzolan slurry and the calcium slurry to remain separate; wherein at least one of the pozzolan slurry and the calcium slurry comprise a thixotropic material; wherein at least one of the pozzolan slurry and the calcium slurry comprise a dispersant; wherein at least one of the pozzolan slurry and the calcium slurry comprise a weighting agent. The method additionally comprises mixing the pozzolan slurry and the calcium slurry to form a two-part thixotropic lost circulation slurry after the allowing the pozzolan slurry and the calcium slurry to remain separate. The method also includes introducing the two-part thixotropic lost circulation slurry to a lost circulation zone within the wellbore; and allowing or causing to allow the two-part thixotropic lost circulation slurry to set into a hardened mass within the lost circulation zone.

Methods and systems of reducing lost circulation in a wellbore are provided. An example method includes providing a pozzolan slurry comprising a pozzolanic material and water; and providing a calcium slurry comprising a calcium source, a high pH activator, and water. The method further comprises allowing the pozzolan slurry and the calcium slurry to remain separate; wherein at least one of the pozzolan slurry and the calcium slurry comprise a thixotropic material; wherein at least one of the pozzolan slurry and the calcium slurry comprise a dispersant; wherein at least one of the pozzolan slurry and the calcium slurry comprise a weighting agent. The method additionally comprises mixing the pozzolan slurry and the calcium slurry to form a two-part thixotropic lost circulation slurry after the allowing the pozzolan slurry and the calcium slurry to remain separate. The method also includes introducing the two-part thixotropic lost circulation slurry to a lost circulation zone within the wellbore; and allowing or causing to allow the two-part thixotropic lost circulation slurry to set into a hardened mass within the lost circulation zone.

Methods for cementing a subterranean well and maintaining zonal isolation involve preparing a cement slurry that contains water, an inorganic cement and an expanding agent. The slurry is placed in the annular region between casing and the formation or between two casing strings. After the cement sets, the expanding agent reacts and causes the set cement to be in a state of compression within the annular region. The casing dimensions may fluctuate in response to a temperature change, a pressure change, a mechanical disturbance resulting from a well intervention, or mud contamination or a combination thereof. The expanding agent may further react and maintain a state of compression within the annular region. The state of compression in the annular region may be monitored by acoustic impedance measurements.

Methods for cementing a subterranean well and maintaining zonal isolation involve preparing a cement slurry that contains water, an inorganic cement and an expanding agent. The slurry is placed in the annular region between casing and the formation or between two casing strings. After the cement sets, the expanding agent reacts and causes the set cement to be in a state of compression within the annular region. The casing dimensions may fluctuate in response to a temperature change, a pressure change, a mechanical disturbance resulting from a well intervention, or mud contamination or a combination thereof. The expanding agent may further react and maintain a state of compression within the annular region. The state of compression in the annular region may be monitored by acoustic impedance measurements.

The present disclosure relates to a method of cementing comprising: providing a cement composition comprising: water, a cement, and a non-aqueous liquid anti-shrinkage cement additive comprising calcined magnesium oxide and a non-aqueous liquid; introducing the cement composition into a subterranean formation; and allowing the cement composition to set in the subterranean formation. Non-aqueous liquid anti-shrinkage cement additives, cement compositions, and systems are also provided.

The present disclosure relates to a method of cementing comprising: providing a cement composition comprising: water, a cement, and a non-aqueous liquid anti-shrinkage cement additive comprising calcined magnesium oxide and a non-aqueous liquid; introducing the cement composition into a subterranean formation; and allowing the cement composition to set in the subterranean formation. Non-aqueous liquid anti-shrinkage cement additives, cement compositions, and systems are also provided.

A composition consisting essentially of (a) 1 to 30% by weight of a 1 to 90% by weight aqueous phosphoric acid and/or a hydrogen phosphate; (b) 1 to 40% by weight of a compound selected from the group of oxides, hydroxides and oxide hydrates of magnesium, calcium, iron, zinc and copper; (c) 40 to 95% by weight of a particulate filler selected from the group of glass; mono-, oligo- and polyphosphates of magnesium, calcium, barium and aluminium; calcium sulphate; barium sulphate; simple and complex silicates; simple and complex aluminates; simple and complex titanates; simple and complex zirconates; zirconium dioxide; titanium dioxide, aluminium oxide; silicon oxide; silicon carbide; aluminium nitride; boron nitride and silicon nitride; (d) 1 to 10% by weight of an urea compound selected from the group consisting of imidazolidine-2-on, allantoin and imidazolidinyl urea; and (e) 0 to 15% by weight of a component differing from (a) to (d).

Described herein is bio-fiber-based building material wherein the thermal performance is improved by two to four-fold over the prior art Hemperete by identifying and incorporating performance-enhancing ingredients into a bio-fiber and binder mix using specifically developed mixing formulas.