Disclosed are surface retarder composition and method for etching cementitious materials which achieve a desirable light acid etch look without using muriatic (hydrochloric) acid or sand blasting, removing the human health and environmental concerns. Formulations in accordance with embodiments disclosed herein are easier to remove from formwork or molds after demolding than conventional retarder paints. Surface retarders prevent the hydration of cement particles, which allows the uncured layer of paste next to the form to be removed such as by washing with water or other fluids, or by brushing, revealing aggregates. Also disclosed are molded cement and concrete materials or articles exhibiting such light etch.

The invention relates to a method for producing water-soluble or water-swellable polymers containing acryloyldimethyltaurate, neutral monomers, and monomers with carboxylate groups. The monomers undergo free radical polymerisation in precipitation in a polar solvent or solvent mixture, providing that an additional polar organic solvent is contained if the polar solvent contains 2-methyl-2-propanol, a ketone or both.

The invention relates to a method for producing water-soluble or water-swellable polymers containing acryloyldimethyltaurate, neutral monomers, and monomers with carboxylate groups. The monomers undergo free radical polymerisation in precipitation in a polar solvent or solvent mixture, providing that an additional polar organic solvent is contained if the polar solvent contains 2-methyl-2-propanol, a ketone or both.

A copolymer includes a main hydrocarbon chain and side groups including carboxylic groups and polyoxyalkylate groups. The copolymer further includes gem-bisphosphonate groups. The copolymer can be included in an admixture for suspensions of mineral particles and in a composition of mineral particles. The copolymer can also be used for fluidifying and maintaining fluid, suspensions of mineral particles and for reducing the sensitivity of hydraulic compositions to clays and alkaline sulfates.

A copolymer includes a main hydrocarbon chain and side groups including carboxylic groups and polyoxyalkylate groups. The copolymer further includes gem-bisphosphonate groups. The copolymer can be included in an admixture for suspensions of mineral particles and in a composition of mineral particles. The copolymer can also be used for fluidifying and maintaining fluid, suspensions of mineral particles and for reducing the sensitivity of hydraulic compositions to clays and alkaline sulfates.

The invention relates to a composition in the form of a solid and suitable as a dispersant for inorganic solids suspensions, comprising A) at least one water-soluble polymer comprising polyether groups, and B) at least one water-soluble condensation product comprising acid groups and/or salts thereof and based on monomers, the monomers comprising at least ) a monomer having a ketone radical and ) formaldehyde. Further disclosed are a method for producing the composition of the invention, and the use thereof in an inorganic binder composition.

The invention relates to a composition in the form of a solid and suitable as a dispersant for inorganic solids suspensions, comprising A) at least one water-soluble polymer comprising polyether groups, and B) at least one water-soluble condensation product comprising acid groups and/or salts thereof and based on monomers, the monomers comprising at least ) a monomer having a ketone radical and ) formaldehyde. Further disclosed are a method for producing the composition of the invention, and the use thereof in an inorganic binder composition.

The invention relates to a process for producing a pulverulent composition comprising at least one polymeric dispersant (PD) which comprises structural units having anionic and/or anionogenic groups and structural units having polyether side chains, and at least one polysaccharide (PS). The process here comprises the process steps: a) production of an aqueous dispersion having a viscosity of the dispersion of less than 10 000 mPa.Math.s, comprising the at least one polymeric dispersant (PD) and the at least one polysaccharide (PS) and b) spray drying of the aqueous dispersion produced in process step a). Furthermore, the use of the pulverulent composition according to the invention in inorganic binder compositions, especially as a rheological additive, is disclosed.

The invention relates to a process for producing a pulverulent composition comprising at least one polymeric dispersant (PD) which comprises structural units having anionic and/or anionogenic groups and structural units having polyether side chains, and at least one polysaccharide (PS). The process here comprises the process steps: a) production of an aqueous dispersion having a viscosity of the dispersion of less than 10 000 mPa.Math.s, comprising the at least one polymeric dispersant (PD) and the at least one polysaccharide (PS) and b) spray drying of the aqueous dispersion produced in process step a). Furthermore, the use of the pulverulent composition according to the invention in inorganic binder compositions, especially as a rheological additive, is disclosed.

The invention relates to aqueous polymer dispersions comprising polymerized units issued from the following monomers with related weight proportions based on 100 parts of weight of a)+b): a) 50 to 90% of a monoethylenically unsaturated non-ionic monomer, b) 10 to 50% of vinyl aromatic monomer or methyl methacrylate, c) 1 to 5% of a hydroxy-containing (meth)acrylate, d) 0.1 to 3% of acid monomer selected from d1) acid monomer selected from monocarboxylic or dicarboxylic acid monomers and d2) acid monomer selected from phosphorous-based or sulfur-based strong acid monomers or/and their salts, or from the mixtures of d1) and d2), e) 0.001 to 0.5% of chain transfer agent, and f) 0 to 1% one of internal crosslinker bearing at least two copolymerisable ethylenic unsaturations, the polymer having a Tg measured by DSC from 30 to 0 C. and a gel content of 0 to 60%, formed during polymerization.