C04B28/16

USE OF MINERAL FINES TO REDUCE CLINKER CONTENT OF CEMENTITIOUS COMPOSITIONS
20220017419 · 2022-01-20 ·

Mineral fines reduce OPC content in concrete, mortar and other cementitious compositions, typically in combination with a pozzolanically active SCM. Mineral fines can replace and/or augment a portion of hydraulic cement and/or fine aggregate. Mineral fines can replace a portion of cement binder and fine aggregate as an intermediate that fills a size void between largest cement particles and smallest fine aggregate particles. Supplemental lime can enhance balance of calcium ions in the mix water and/or pore solution. Supplemental sulfate can address sulfate deficiencies caused by high clinker reduction, use of water reducers and/or superplasticizers, and SCMs containing aluminates. Concentrated or pure carbon dioxide (CO.sub.2) can be used to passivate alkaline values in highly alkaline materials, such as concrete washout fines, CKD, class C flyash, incinerator ash, bottom ash, or biomass ash. CO.sub.2 passivation or sequestration can be carried out before, during or after forming an initial concrete mix.

LIMESTONE CALCINED CLAY CEMENT (LC3) CONSTRUCTION COMPOSITION

A limestone calcined clay cement construction composition comprises a) a cementitious binder comprising one or more calcium silicate mineral phases and one or more calcium aluminate mineral phases, and having a Blaine surface area of at least 3800 cm.sup.2/g, in an amount of 180 to 400 kg per m.sup.3 of the freshly mixed construction composition; b) a supplementary cementitious material having a Dv90 of less than 200 μm, in a total amount of 50 to 100 parts by weight, relative to 100 parts by weight of cementitious binder a), the supplementary cementitious material comprising (b-1) a calcined clay material and (b-2) a carbonate rock powder in a weight ratio of (b-1) to (b-2) in the range of 0.5 to 2; c) optionally, an extraneous aluminate source; d) a sulfate source; and e) a polyol in an amount of 0.3 to 2.5 wt.-%, relative to the amount of cementitious binder a). The composition contains available aluminate, calculated as Al(OH).sub.4.sup.−, from the calcium aluminate mineral phases plus the optional extraneous aluminate source, per 100 g of cementitious binder a), in a total amount of at least 0.08 mol, if the amount of cementitious binder a) is in the range of 180 to less than 220 kg per m.sup.3 of the freshly mixed composition, at least 0.06 mol, if the amount of cementitious binder a) is in the range of 220 to less than 280 kg per m.sup.3 of the freshly mixed composition, and at least 0.05 mol, if the amount of cementitious binder a) is 280 kg or more per m.sup.3 of the freshly mixed composition; and the molar ratio of total available aluminate to sulfate is 0.4 to 2.0. The construction composition further comprises f) an ettringite formation controller comprising (i) glyoxylic acid, a glyoxylic acid salt and/or a glyoxylic acid derivative; and (ii) at least one of (ii-a) a borate source and (ii-b) a carbonate source, wherein the carbonate source is selected from inorganic carbonates having an aqueous solubility of 0.1 g.Math.L.sup.−1 or more, organic carbonates, and mixtures thereof; and g) a co-retarder selected from (g-1) α-hydroxy monocarboxylic acids and salts thereof, (g-2) phosphonic acids and salts thereof, (g-3) polycarboxylic acids and salts thereof, and mixtures thereof. The limestone calcined clay cement construction composition is a reduced carbon footprint composition and exhibits high early strength, high final strength, sufficient open time and high durability. Ingredients of the construction composition are abundantly available.

LIMESTONE CALCINED CLAY CEMENT (LC3) CONSTRUCTION COMPOSITION

A limestone calcined clay cement construction composition comprises a) a cementitious binder comprising one or more calcium silicate mineral phases and one or more calcium aluminate mineral phases, and having a Blaine surface area of at least 3800 cm.sup.2/g, in an amount of 180 to 400 kg per m.sup.3 of the freshly mixed construction composition; b) a supplementary cementitious material having a Dv90 of less than 200 μm, in a total amount of 50 to 100 parts by weight, relative to 100 parts by weight of cementitious binder a), the supplementary cementitious material comprising (b-1) a calcined clay material and (b-2) a carbonate rock powder in a weight ratio of (b-1) to (b-2) in the range of 0.5 to 2; c) optionally, an extraneous aluminate source; d) a sulfate source; and e) a polyol in an amount of 0.3 to 2.5 wt.-%, relative to the amount of cementitious binder a). The composition contains available aluminate, calculated as Al(OH).sub.4.sup.−, from the calcium aluminate mineral phases plus the optional extraneous aluminate source, per 100 g of cementitious binder a), in a total amount of at least 0.08 mol, if the amount of cementitious binder a) is in the range of 180 to less than 220 kg per m.sup.3 of the freshly mixed composition, at least 0.06 mol, if the amount of cementitious binder a) is in the range of 220 to less than 280 kg per m.sup.3 of the freshly mixed composition, and at least 0.05 mol, if the amount of cementitious binder a) is 280 kg or more per m.sup.3 of the freshly mixed composition; and the molar ratio of total available aluminate to sulfate is 0.4 to 2.0. The construction composition further comprises f) an ettringite formation controller comprising (i) glyoxylic acid, a glyoxylic acid salt and/or a glyoxylic acid derivative; and (ii) at least one of (ii-a) a borate source and (ii-b) a carbonate source, wherein the carbonate source is selected from inorganic carbonates having an aqueous solubility of 0.1 g.Math.L.sup.−1 or more, organic carbonates, and mixtures thereof; and g) a co-retarder selected from (g-1) α-hydroxy monocarboxylic acids and salts thereof, (g-2) phosphonic acids and salts thereof, (g-3) polycarboxylic acids and salts thereof, and mixtures thereof. The limestone calcined clay cement construction composition is a reduced carbon footprint composition and exhibits high early strength, high final strength, sufficient open time and high durability. Ingredients of the construction composition are abundantly available.

USE OF POLYOL FOR REDUCING SHRINKAGE OF CONSTRUCTION CHEMICAL COMPOSITIONS
20230295043 · 2023-09-21 · ·

The use of polyol having a functionality of 4 or less and an OH group density of at least 0.033 mol OH per g polyol as a composition for reducing shrinking of construction chemicals on the basis of a hydraulic binder comprising a) alumina cement and/or calcium sulfoaluminate cement, b) calcium sulfate, and c) optionally Portland cement.

USE OF POLYOL FOR REDUCING SHRINKAGE OF CONSTRUCTION CHEMICAL COMPOSITIONS
20230295043 · 2023-09-21 · ·

The use of polyol having a functionality of 4 or less and an OH group density of at least 0.033 mol OH per g polyol as a composition for reducing shrinking of construction chemicals on the basis of a hydraulic binder comprising a) alumina cement and/or calcium sulfoaluminate cement, b) calcium sulfate, and c) optionally Portland cement.

Construction Material Based on a Mineral Binder Comprising Synergistically Effective Hydrophobisation Agent Combinations

The invention concerns construction materials based on a mineral binder, which includes a synergistically effective hydrophobisation mixture. The invention also relates to methods for processing of such construction materials and the use of a synergistically effective mixture for the hydrophobisation of a mineral binder based construction material.

Construction Material Based on a Mineral Binder Comprising Synergistically Effective Hydrophobisation Agent Combinations

The invention concerns construction materials based on a mineral binder, which includes a synergistically effective hydrophobisation mixture. The invention also relates to methods for processing of such construction materials and the use of a synergistically effective mixture for the hydrophobisation of a mineral binder based construction material.

Process for Producing a Binder

The invention relates to a method of producing a binder comprising the steps of preparing (20) a residual material comprising amorphous alumina-rich and/or aluminium hydroxide-rich constituents, heating (30) the residual material to produce a fired material, the heating (30) of the residual material being at a temperature of >800° C.

Process for Producing a Binder

The invention relates to a method of producing a binder comprising the steps of preparing (20) a residual material comprising amorphous alumina-rich and/or aluminium hydroxide-rich constituents, heating (30) the residual material to produce a fired material, the heating (30) of the residual material being at a temperature of >800° C.

STABILIZED GYPSUM PARTICLES

The present invention is directed to a construction chemical composition for the preparation of gypsum articles, said construction chemical composition comprising fine calcium sulfate and a dispersant being a polyarylether. Further the present invention is directed to a process for preparing said construction chemical composition as well as an article comprising said construction chemical composition.