Disclosed are a low-shrinkage, high-strength, and large ceramic plate and a manufacturing method thereof. The method comprises the following steps: (1) preparing a ceramic raw material powder; (2) subjecting an acicular wollastonite to surface coating with a silane coupling agent and to pre-dispersion with a fumed silica to obtain a pre-treated acicular wollastonite; and (3) thoroughly mixing the ceramic raw material powder and the pre-treated acicular wollastonite and granulating the resulting mixture, the amount of the pre-treated acicular wollastonite added being 10 wt % to 30 wt % of the ceramic raw material powder, and subjecting the resulting granules to dry pressing and sintering to obtain the large ceramic plate. The acicular wollastonite is incorporated into the manufacturing of the large ceramic plate to take full advantage of the reinforcing effect and low sintering shrinkage characteristics of the acicular wollastonite. The invention reduces sintering shrinkage and increases product strength.

The present invention is a composition and shaping of a ceramic material comprising at least one frit and at least one inorganic raw material. Some of the advantages are that said material requires a heat treatment no higher than 1180° C., that the duration of said heat treatment does not exceed 60 minutes, that the thermal expansion coefficient after the heat treatment is less than 25×10.sup.−7° C..sup.−1 in the temperature range 25° C. to 500° C. and that the material exhibits a high resistance to thermal shock, withstanding at least 10 consecutive thermal shock cycles between 600° C. and 25° C. without forming cracks or structural changes. The ceramic material composition is shaped by uniaxial pressing, band pressing, pour moulding, extrusion, injection moulding or lamination.

A recycled aluminium silicate material, suitable for use in ceramic article production, wherein the recycled aluminium silicate material has a particle size distribution such that: (i) the d.sub.50 particle size is from 10 μm to 30 μm; (ii) the d.sub.70 particle size is less than 40 μm; and (iii) the d.sub.98 particle size is less than 60 μm. A particulate mixture, suitable for use in ceramic article production, includes the above defined recycled aluminium silicate material.

A particulate mixture, suitable for use in ceramic article production, wherein the mixture includes from 30 wt % to 80 wt % recycled aluminium silicate material. The particulate mixture has a particle size distribution such that: (i) the d.sub.50 particle size is from 10 μm to 30 μm; (ii) the d.sub.70 particle size is less than 40 μm; and (iii) the d.sub.98 particle size is less than 60 μm.

Disclosed are a semi-transparent ceramic sheet decorated through ink light-absorbance and a preparation method thereof. The semi-transparent ceramic sheet comprises a semi-transparent green body, an inner inkjet pattern layer infiltrating into the semi-transparent green body from an upper surface of the semi-transparent green body, a decoloration glaze layer located on the upper surface, and a surface pattern layer located on the decoloration glaze layer. The decoloration glaze layer is capable of decoloring the ink of the inner inkjet pattern layer. The semi-transparent ceramic sheet is provided with the decoloration glaze layer so that the inkjet decoration of the inner inkjet pattern layer cannot be displayed on the surface, and the decorative pattern on the surface of the green body is the surface pattern layer and the inner inkjet pattern layer is completely in the inner layer of the green body.

A process for the production of a ceramic article includes the steps of: (a) preparing a particulate mixture; (b) contacting the particulate mixture to water to form a humidified mixture; (c) pressing the humidified mixture to form a green article; (d) optionally, subjecting the green article to an initial drying step; (e) optionally, glazing the green article to form a glazed green article; (f) subjecting the green article to a heat treatment step to form a hot fused article; and (g) cooling the hot fused article to form a glazed ceramic article. The particulate mixture includes from 30 wt % to 80 wt % recycled aluminium silicate material. The particulate mixture has: (i) a d.sub.50 particle size from 10 μm to 30 μm; (ii) a d.sub.70 particle size of less than 40 μm; and (iii) a d.sub.98 particle size of less than 60 μm. Steps (c) and (f), and optionally steps (d) and (e) are continuous process steps.

A process for the production of a ceramic article includes the steps of: (a) preparing a particulate mixture; (b) contacting the particulate mixture to water to form a humidified mixture; (c) pressing the humidified mixture to form a green article; (d) optionally, subjecting the green article to an initial drying step; (e) optionally, glazing the green article to form a glazed green article; (f) subjecting the green article to a heat treatment step to form a hot fused article; and (g) cooling the hot fused article to form a glazed ceramic article. The particulate mixture includes from 30 wt % to 80 wt % recycled aluminium silicate material. The particulate mixture has: (i) a d.sub.50 particle size from 10 μm to 30 μm; (ii) a d.sub.70 particle size of less than 40 μm; and (iii) a d.sub.98 particle size of less than 60 μm. Steps (c) and (f), and optionally steps (d) and (e) are continuous process steps.

A ceramic membrane is provided, which may include glass, incinerator fly ash, kaolin and palygorskite. The weight percent of the glass may be 3060 wt %. The weight percent of the incinerator fly ash may be 530 wt %. The weight percent of the kaolin may be 050 wt %. The weight percent of the palygorskite is 030 wt %.

A ceramic membrane is provided, which may include glass, incinerator fly ash, kaolin and palygorskite. The weight percent of the glass may be 3060 wt %. The weight percent of the incinerator fly ash may be 530 wt %. The weight percent of the kaolin may be 050 wt %. The weight percent of the palygorskite is 030 wt %.

Ceramic tiles may be prepared employing a process characterized by the addition to the ceramic raw materials of an aqueous slurry comprising a swellable clay of the smectite family, a binder and a water-soluble salt of a monovalent cation. The ceramic raw materials mixed and then subjected to wet grinding to produce a slip. The thus obtained slip is then subjected to spray drying.