A refractory object may include a Cr.sub.2O.sub.3 content of at least about 80 wt. % of a total weight of the refractory object, an Al.sub.2O.sub.3 content of at least about 0.7 wt. % and not greater than about 10.0 wt. % of the total weight of the refractory object, a SiO.sub.2 content of at least about 0.3 wt. % and not greater than about 5.0 wt. % of the total weight of the refractory object and a TiO.sub.2 content of at least about 1.0 wt. % and not greater than about 5.6 wt. % TiO.sub.2 of the total weight of the refractory object. The refractory object may further include an MOR of at least about 37 MPa as measured at 1200° C.

A refractory, coarse ceramic product including at least one granular refractory material, has an open porosity of between 22 and 45 vol.-%, in particular of between 23 and 29 vol.-%, and a grain structure of the refractory material, wherein the medium grain size fraction with grain sizes of between 0.1 and 0.5 mm is 10 to 55 wt.-%, in particular 35 to 50 wt.-%, and wherein the remainder of the grain structure is a finest grain fraction with grain sizes of up to 0.1 mm and/or coarse-grain fraction with grain sizes of more than 0.5 mm.

A refractory, coarse ceramic product including at least one granular refractory material, has an open porosity of between 22 and 45 vol.-%, in particular of between 23 and 29 vol.-%, and a grain structure of the refractory material, wherein the medium grain size fraction with grain sizes of between 0.1 and 0.5 mm is 10 to 55 wt.-%, in particular 35 to 50 wt.-%, and wherein the remainder of the grain structure is a finest grain fraction with grain sizes of up to 0.1 mm and/or coarse-grain fraction with grain sizes of more than 0.5 mm.

Use of porous metal oxide microspheres as light stabilizers for shaped artificial polymer articles, wherein the porous metal oxide microspheres are prepared via a process comprising forming a liquid dispersion of polymer nanoparticles and a metal oxide; forming liquid droplets of the dispersion; drying the droplets to provide polymer template microspheres comprising polymer nanospheres; and removing the polymer nanospheres from the template microspheres to provide the porous metal oxide microspheres.

The disclosure relates to solid oxide fuel cell (SOFC) anode materials that comprise various compositions of chromate based oxide materials. These materials offer high conductivity achievable at intermediate and low temperatures and can be used to prepare the anode layer of a SOFC. A method of making a low- or intermediate-temperature SOFC having an anode layer comprising a chromate based oxide material is also provided.

The disclosure relates to solid oxide fuel cell (SOFC) anode materials that comprise various compositions of chromate based oxide materials. These materials offer high conductivity achievable at intermediate and low temperatures and can be used to prepare the anode layer of a SOFC. A method of making a low- or intermediate-temperature SOFC having an anode layer comprising a chromate based oxide material is also provided.

A method for forming a sintered composition includes providing a slurry precursor including a chalcogenide compound; tape casting the slurry precursor to form a green tape; and sintering the green tape at a temperature in a range of 500° C. to 1350° C. for a time in a range of less than 60 min. An energy device includes a first sintered, non-polished electrode having a first surface and a second surface; a first current collector disposed on the first surface of the first electrode; an electrolyte layer disposed on the second surface of the first electrode; and a second electrode disposed on the electrolyte layer.

Exemplary methods of coating a metal-containing component are described. The methods are developed to increase corrosion resistance and improve coating adhesion to a metal substrate. The methods include forming a bonding layer on a metal substrate, where the bonding layer includes an oxide of a metal in the metal substrate. The coating methods further include depositing a stress buffer layer on the bonding layer, where the stress buffer layer is characterized by a stress buffer layer coefficient of thermal expansion (CTE) that is less than a metal substrate CTE and a bonding layer CTE. The coating methods also include depositing an environmental barrier layer on the stress buffer layer, where a ratio of the metal substrate CTE to an environmental barrier layer CTE is greater than or about 20:1, and where the environmental barrier layer includes silicon oxide. The metal-containing components may be used in fabrication equipment for electronic devices.

Exemplary methods of coating a metal-containing component are described. The methods are developed to increase corrosion resistance and improve coating adhesion to a metal substrate. The methods include forming a bonding layer on a metal substrate, where the bonding layer includes an oxide of a metal in the metal substrate. The coating methods further include depositing a stress buffer layer on the bonding layer, where the stress buffer layer is characterized by a stress buffer layer coefficient of thermal expansion (CTE) that is less than a metal substrate CTE and a bonding layer CTE. The coating methods also include depositing an environmental barrier layer on the stress buffer layer, where a ratio of the metal substrate CTE to an environmental barrier layer CTE is greater than or about 20:1, and where the environmental barrier layer includes silicon oxide. The metal-containing components may be used in fabrication equipment for electronic devices.

In additive manufacturing operations, powders used in stereolithographic processes need to be precisely spread out in a uniform fashion at every pass of the stereolithographic process to ensure predictability in powder surface morphology. Typically, this is difficult to achieve with conventional powders because often these powders suffer from poor flowability, which may further deteriorate over time, and impairs the efficiency of the stereolithographic processes. The present disclosure describes additive manufacturing powders having improved physical characteristics such as flowability and tap density, which are less sensitive or insensitive to ambient humidity. For example, there is described a powder that includes spherical particles having a particle size distribution of less than 1000 micrometers and having a measurable flowability as determined in accordance with ASTM B213 at 75% relative humidity.