Disclosed is a solid state electrolyte comprising a compound of Formula 1

Li.sub.7-.sub.a.sub.*α-(b−4)*β−xM.sup.a.sub.αLa.sub.3Hf.sub.2−βM.sup.b.sub.βO.sub.12−x−δX.sub.x   (1)

wherein

M.sup.a is a cationic element having a valence of a+;

M.sup.b is a cationic element having a valence of b+; and

X is an anion having a valence of −1,

wherein, when M.sup.a includes H, 0≤α≤5, otherwise 0≤α≤0.75, and wherein 0≤β≤1.5, 0≤x≤1.5, and (a*α+(b−4)β+x)>0, 0≤δ≤1.

Proposed are a slurry composition for suspension plasma thermal spray, a preparation method therefor, and a suspension plasma thermal spray coating film. When the slurry composition is used to form a thermal spray coating film, the thermal spray coating film can be stably applied to applications used in a corrosive environment because no changes occur in content of oxygen and fluorine in the thermal spray coating film. In addition, when forming the coating film, since various crystal structures can be formed under control, the coating film can be used in various environments requiring corrosion resistance. In addition, the slurry composition can inhibit formation of cracks and pores that frequently occur in existing thermal spray coating films, thereby allowing for formation of a denser thermal spray coating film than the existing thermal spray coating film.

A sintered material is provided having a phase of a compound at least containing a rare earth element and fluorine, the sintered material having an L* value of 70 or more in the L*a*b* color space. The crystal grains of the sintered material preferably has an average grain size of 10 μm or less. The sintered material preferably has a relative density of 95% or more. The sintered material preferably has a three-point flexural strength of 100 MPa or more. The sintered material preferably contains no oxygen, or preferably has an oxygen content of 13% by mass or less when containing oxygen. The compound is preferably rare earth element fluoride or oxyfluoride.

A sintered body of the present invention contains yttrium oxyfluoride. The yttrium oxyfluoride is preferably YOF and/or Y.sub.5O.sub.4F.sub.7. The sintered body of the present invention preferably contains 50% by mass or more of yttrium oxyfluoride. The sintered body of the present invention has a relative density of preferably 70% or more and an open porosity of preferably 10% or less. Furthermore, the sintered body of the present invention has a three-point bending strength of preferably 10 MPa or more and 300 MPa or less.

A scintillation crystal can include Ln.sub.(1-y)RE.sub.yX.sub.3, wherein Ln represents a rare earth element, RE represents a different rare earth element, y has a value in a range of 0 to 1, and X represents a halogen. In an embodiment, RE is Ce, and the scintillation crystal is doped with Sr, Ba, or a mixture thereof at a concentration of at least approximately 0.0002 wt. %. In another embodiment, the scintillation crystal can have unexpectedly improved linearity and unexpectedly improved energy resolution properties. In a further embodiment, a radiation detection system can include the scintillation crystal, a photosensor, and an electronics device. Such a radiation detection system can be useful in a variety of radiation imaging applications.

A scintillation crystal can include Ln.sub.(1-y)RE.sub.yX.sub.3, wherein Ln represents a rare earth element, RE represents a different rare earth element, y has a value in a range of 0 to 1, and X represents a halogen. In an embodiment, RE is Ce, and the scintillation crystal is doped with Sr, Ba, or a mixture thereof at a concentration of at least approximately 0.0002 wt. %. In another embodiment, the scintillation crystal can have unexpectedly improved linearity and unexpectedly improved energy resolution properties. In a further embodiment, a radiation detection system can include the scintillation crystal, a photosensor, and an electronics device. Such a radiation detection system can be useful in a variety of radiation imaging applications.

Provided are a sintered material having high corrosion resistance, a method of manufacturing the sintered material, a member for a semiconductor manufacturing apparatus, a method of manufacturing a member for a semiconductor manufacturing apparatus, a semiconductor manufacturing apparatus, and a method of manufacturing a semiconductor manufacturing apparatus. The sintered material according to an embodiment includes 50 mass% or more of yttrium oxyfluoride, has a relative density of 97.0% or more, and has a Vickers hardness of 5.0 GPa or more. The method of manufacturing a sintered material according to an embodiment includes forming a molded body including yttrium oxyfluoride powder having a particle size of 0.3 .Math.m or less, and sintering the molded body under an atmospheric pressure at a temperature of 800° C. or less.

Provided are a sintered material having high corrosion resistance, a method of manufacturing the sintered material, a member for a semiconductor manufacturing apparatus, a method of manufacturing a member for a semiconductor manufacturing apparatus, a semiconductor manufacturing apparatus, and a method of manufacturing a semiconductor manufacturing apparatus. The sintered material according to an embodiment includes 50 mass% or more of yttrium oxyfluoride, has a relative density of 97.0% or more, and has a Vickers hardness of 5.0 GPa or more. The method of manufacturing a sintered material according to an embodiment includes forming a molded body including yttrium oxyfluoride powder having a particle size of 0.3 .Math.m or less, and sintering the molded body under an atmospheric pressure at a temperature of 800° C. or less.

A MgF.sub.2—CaF.sub.2 binary system sintered body for a radiation moderator having a compact polycrystalline structure excellent in radiation moderation performance, especially neutron moderation performance, comprises MgF.sub.2 containing CaF.sub.2 from 0.2% by weight to 90% by weight inclusive, having a bulk density of 2.96 g/cm.sup.3 or more, and a bending strength of 15 MPa or more and a Vickers hardness of 90 or more as regards mechanical strengths.

A MgF.sub.2—CaF.sub.2 binary system sintered body for a radiation moderator having a compact polycrystalline structure excellent in radiation moderation performance, especially neutron moderation performance, comprises MgF.sub.2 containing CaF.sub.2 from 0.2% by weight to 90% by weight inclusive, having a bulk density of 2.96 g/cm.sup.3 or more, and a bending strength of 15 MPa or more and a Vickers hardness of 90 or more as regards mechanical strengths.