Ceramic matrix composite (CMC) materials are a desired solution for lightweight and high temperature applications. CMC materials can be reinforced with polymer-derived ceramic (PDC) fibers, which advantageously possess intrinsic thermal stability and high mechanical strength. Carbon-rich SiOC and SiOCN fibers were synthesized via hand-drawing and electrospinning polymer pyrolysis of a hybrid precursor materials with the aid of a spinning reagent. The prepared fibers are crosslinked and pyrolyzed for polymer-to-ceramic conversion.

This invention provides resin formulations which may be used for 3D printing and pyrolyzing to produce a ceramic matrix composite. The resin formulations contain a solid-phase filler, to provide high thermal stability and mechanical strength (e.g., fracture toughness) in the final ceramic material. The invention provides direct, free-form 3D printing of a preceramic polymer loaded with a solid-phase filler, followed by converting the preceramic polymer to a 3D-printed ceramic matrix composite with potentially complex 3D shapes or in the form of large parts. Other variations provide active solid-phase functional additives as solid-phase fillers, to perform or enhance at least one chemical, physical, mechanical, or electrical function within the ceramic structure as it is being formed as well as in the final structure. Solid-phase functional additives actively improve the final ceramic structure through one or more changes actively induced by the additives during pyrolysis or other thermal treatment.

A system and method to dry plug cement in a ceramic honeycomb body during the manufacture of plugged ceramic honeycomb bodies. The system includes a heating element (520) configured to immediately heat without contact a face (502) of a ceramic honeycomb body (500) plugged with a wet plug cement (510) to rapidly dry and stiffen the plug cement (510) on the face (502) of the ceramic honeycomb body (500). The method includes immediately applying heat without contact to a face (502) of a ceramic honeycomb body (500) having wet plug cement (510) disposed in channels (508) of the ceramic honeycomb body at the face, and rapidly drying and stiffening the plug cement on the face of the ceramic honeycomb body.

A system and method to dry plug cement in a ceramic honeycomb body during the manufacture of plugged ceramic honeycomb bodies. The system includes a heating element (520) configured to immediately heat without contact a face (502) of a ceramic honeycomb body (500) plugged with a wet plug cement (510) to rapidly dry and stiffen the plug cement (510) on the face (502) of the ceramic honeycomb body (500). The method includes immediately applying heat without contact to a face (502) of a ceramic honeycomb body (500) having wet plug cement (510) disposed in channels (508) of the ceramic honeycomb body at the face, and rapidly drying and stiffening the plug cement on the face of the ceramic honeycomb body.

The present invention relates to a suspension comprising 50-95% by weight of the total suspension (w/w) of at least one metallic material and/or ceramic material and/or polymeric material and/or solid carbon containing material; and at least 5% by weight of the total suspension of one or more fatty acids or derivatives thereof. In addition, the invention relates to uses of such suspension in 3D printing processes.

Ultra-high temperature carbide (UHTC) foams and methods of fabricating and using the same are provided. The UHTC foams are produced in a three-step process, including UHTC slurry preparation, freeze-drying, and spark plasma sintering (SPS). The fabrication methods allow for the production of any kind of single- or multi-component UHTC foam, while also providing flexibility in the shape and size of the UHTC foams to produce near-net-shape components.

A composite precursor powder, including one or more metals or metalloids, and one or more oxides, wherein a molar ratio of the one or more metals or metalloids to the one or more oxides is from about 1:0.01 to about 1:4, and wherein the molar ratio of the one or more metals or metalloids to the one or more oxides is configured according to a desired volumetric change of the composite precursor powder when converted to a non-oxide ceramic.

Methods, apparatus and systems using heat exchanger reactors to form polymer derived ceramic materials, including methods for making polysilocarb (SiOC) precursors.

A system for forming a product with different size particles is disclosed. The system comprises at least one print head region configured to retain a first group of print heads configurable to additively print at least a first portion of the product with a first material and a second group of print heads configurable to additively print at least a second portion of the product with a second material. The described system may also comprise a processor configured to regulate the first group of print heads and the second group of print heads to distribute the first material and the second material. A method of making an object by ink jet printing using the disclosed system is also disclosed.

Disclosed is a coating material for coating a surface of a kiln for preparing an active material, the coating material being represented by the following Formula 1:

Ni.sub.aX.sub.z  (1) wherein an equation of a+z=1 is satisfied, with the proviso that 0.2≤a<1.0 and 0<z≤0.8 are satisfied, and X is at least one element selected from the group consisting of W, Cr, Co, Fe, Cu, Na, Al, Mg, Si, Zn, K, Ti, Mo, N, B, P, C, Ta, Nb, O, Mn, Sn, Ag and Zr, or an alloy or compound of two or more elements selected therefrom.