A pre-ceramic support structure for additive manufacturing, that upon thermal processing, is soluble in various solvents.

A catalyst-free synthesis method for the formation of a metalorganic compound comprising a desired (first) metal may include, for example, selecting another (second) metal and an organic solvent, with the second metal being selected to (i) be more reactive with respect to the organic solvent than the first metal and (ii) form, upon exposure of the second metal to the organic solvent, a reaction by-product that is more soluble in the organic solvent than the metalorganic compound. An alloy comprising the first metal and the second metal may be first produced (e.g., formed or otherwise obtained) and then treated with the organic solvent in a liquid phase or a vapor phase to form a mixture comprising (i) the reaction by-product comprising the second metal and (ii) the metalorganic compound comprising the first metal. The metalorganic compound may then be separated from the mixture in the form of a solid.

A ceramic matrix composite (CMC) is formed using a three-dimensional (3-D) woven preform by removing the set of sacrificial fibers from the 3-D woven preform and allowing a metal or metal alloy infiltrate the 3-D woven preform. The 3-D woven preform is formed by a method that includes providing a woven layer comprising a first set of ceramic fibers oriented in a first (x) direction woven with a second set of ceramic fibers oriented in a second (y) direction; stacking a plurality of woven layers on top of each other, said woven layers providing a two-dimensional (2-D) preform; weaving a set of sacrificial fibers in a third (z) direction with the 2-D preform, said weaving providing the 3-D woven preform; and shaping the 3-D woven preform into a predetermined shape.

A method of manufacturing a green body, the method comprising: providing: a third composition comprising a second substrate material, a third polymer, a fusing agent, and a third solvent; forming the third composition into a structure wherein the third composition forms a third layer; and contacting the third layer with a fourth solvent in which the third polymer is insoluble to precipitate said polymer, thereby forming a green body.

A substrate is further manufactured by: arranging a plurality of green bodies to form an assembly of green bodies;
fusing the green bodies in the assembly together, thereby forming a precursor substrate; and sintering the precursor substrate, thereby forming a substrate.

Ceramic matrix composite components and methods for fabricating ceramic matrix composite components are provided. In one example, a ceramic matrix composite component includes a ceramic matrix composite body. The ceramic matrix composite body includes a layer-to-layer weave of ceramic fibers and a layer of 1-directional and/or 2-directional (1D/2D) fabric of ceramic fibers disposed adjacent to the layer-to-layer weave. When stressed, the ceramic matrix composite body forms a relatively high through-thickness stress region and a relatively high in-plane bending stress region. The layer-to-layer weave is disposed through the relatively high through-thickness stress region and the layer of 1D/2D fabric is disposed through the relatively high in-plane bending stress region.

A pre-ceramic support structure for additive manufacturing, that upon thermal processing, is soluble in various solvents.

A pre-ceramic support structure for additive manufacturing, that upon thermal processing, is soluble in various solvents.

A feedstock material for use as a support material in an additive manufacturing system includes a pre-ceramic material in powder form. The preceramic material comprises calcium carbonate, sodium carbonate, sodium aluminate or combinations thereof. The feedstock material includes a thermoplastic binder having the pre-ceramic material dispersed therein, wherein the pre-ceramic material and the thermoplastic binder are in a filament form. The filament is configured to be melted and extruded to form a support structure for a ceramifable article in a layer by layer manner, wherein the pre-ceramic material is at least about 50% of the feedstock material.

A method of forming a protective shield to protect an aircraft component from EMI or energy bursts includes the steps of combining a carbon-based or silicon-based preceramic polymer precursor and a metallic precursor to form a dope, processing the dope to provide a deposit that includes nano-structures, post-processing the deposit to provide a nano-structure material with a uniformly distributed base metal or metal compound, and forming a protective shield using the nano-structure material.

A catalyst-free synthesis method for the formation of a metalorganic compound comprising a desired (first) metal may include, for example, selecting another (second) metal and an organic solvent, with the second metal being selected to (i) be more reactive with respect to the organic solvent than the first metal and (ii) form, upon exposure of the second metal to the organic solvent, a reaction by-product that is more soluble in the organic solvent than the metalorganic compound. An alloy comprising the first metal and the second metal may be first produced (e.g., formed or otherwise obtained) and then treated with the organic solvent in a liquid phase or a vapor phase to form a mixture comprising (i) the reaction by-product comprising the second metal and (ii) the metalorganic compound comprising the first metal. The metalorganic compound may then be separated from the mixture in the form of a solid.