A preparation method and a product of a metal-matrix composite reinforced by nanoscale carbon materials are provided, including: plating metal layers on surfaces of the nanoscale carbon materials, and then adding mental particles to perform ball milling for dispersion and sintering. Volumes of the nanoscale carbon materials account for 0.01% to 30% of the metal-matrix composite. Size requirements of the nanoscale carbon materials and the metal particles are that: K×a sum of maximum cross-sectional areas of the nanoscale carbon materials in a unit volume≤a sum of surface areas of the mental particles in the unit volume; and the K represent a space compensation coefficient. The method is practical and effective, and the nanoscale carbon materials are efficiently and uniformly dispersed in metallic matrix. The obtained composite further has excellent mechanical, electrical and thermal properties, and is applied in metal-matrix composites, nano-electronic components, and biosensors.

A preparation method and a product of a metal-matrix composite reinforced by nanoscale carbon materials are provided, including: plating metal layers on surfaces of the nanoscale carbon materials, and then adding mental particles to perform ball milling for dispersion and sintering. Volumes of the nanoscale carbon materials account for 0.01% to 30% of the metal-matrix composite. Size requirements of the nanoscale carbon materials and the metal particles are that: K×a sum of maximum cross-sectional areas of the nanoscale carbon materials in a unit volume≤a sum of surface areas of the mental particles in the unit volume; and the K represent a space compensation coefficient. The method is practical and effective, and the nanoscale carbon materials are efficiently and uniformly dispersed in metallic matrix. The obtained composite further has excellent mechanical, electrical and thermal properties, and is applied in metal-matrix composites, nano-electronic components, and biosensors.

The present disclosure provides a heat shield. The heat shield may comprise a first layer comprising a first material, a second layer radially outward of the first layer comprising a second material, and a third layer radially outward of the second layer comprising a third material, wherein the first layer is coupled to the second layer by at least one post and at least one support extending from a radially outer surface of the first layer.

The present disclosure provides a heat shield. The heat shield may comprise a first layer comprising a first material, a second layer radially outward of the first layer comprising a second material, and a third layer radially outward of the second layer comprising a third material, wherein the first layer is coupled to the second layer by at least one post and at least one support extending from a radially outer surface of the first layer.

Methods, processes, systems, devices and apparatus are provided for additive manufacture resulting in the 3D printing of ceramic materials and components with a thickness greater than three millimeters (3 mm). A sulfur-free 3D printable formulation comprises a liquid inorganic polymer resin using Stereolithograpy (SLA) printers and Digital Light Processing (DLP) curing of the polymer resin via the chemical bonding of the materials rather than sintering. Thus, the process has shorter manufacturing intervals, significantly lower energy use and produces larger scale ceramic components having less linear shrinkage, less mass loss and high ceramic yield with no corrosive sulfur compounds present in the ceramic component.

Methods, processes, systems, devices and apparatus are provided for additive manufacture resulting in the 3D printing of ceramic materials and components with a thickness greater than three millimeters (3 mm). A sulfur-free 3D printable formulation comprises a liquid inorganic polymer resin using Stereolithograpy (SLA) printers and Digital Light Processing (DLP) curing of the polymer resin via the chemical bonding of the materials rather than sintering. Thus, the process has shorter manufacturing intervals, significantly lower energy use and produces larger scale ceramic components having less linear shrinkage, less mass loss and high ceramic yield with no corrosive sulfur compounds present in the ceramic component.

Hexavalent chromium-free slurries are provided that are capable of achieving a full cure at temperatures as low as 330-450 degrees F., thus making the coatings especially suitable for application on temperature sensitive base materials. The slurries are suitable in the production of protective coating systems formed by novel silicate-based basecoats that are sealed with novel phosphate-based topcoats. The coating systems exhibit acceptable corrosion and heat resistance and are capable of replacing traditional chromate-containing coating systems.

Hexavalent chromium-free slurries are provided that are capable of achieving a full cure at temperatures as low as 330-450 degrees F., thus making the coatings especially suitable for application on temperature sensitive base materials. The slurries are suitable in the production of protective coating systems formed by novel silicate-based basecoats that are sealed with novel phosphate-based topcoats. The coating systems exhibit acceptable corrosion and heat resistance and are capable of replacing traditional chromate-containing coating systems.

A black ceramic composite coating is presented. The ceramic composite coating comprises a ceramic matrix having embedded therein carbide nanoparticles (in particular metal carbide nanoparticles) and/or metal-carbon composite nanoparticles (with separate metal and carbon phases) embedded therein. The carbide nanoparticles are metastable and the metal-carbon composite nanoparticles are decay products of the metastable carbide nanoparticles. A further aspect of the invention relates to producing such a ceramic composite coating.

A black ceramic composite coating is presented. The ceramic composite coating comprises a ceramic matrix having embedded therein carbide nanoparticles (in particular metal carbide nanoparticles) and/or metal-carbon composite nanoparticles (with separate metal and carbon phases) embedded therein. The carbide nanoparticles are metastable and the metal-carbon composite nanoparticles are decay products of the metastable carbide nanoparticles. A further aspect of the invention relates to producing such a ceramic composite coating.