A composition comprising thermoset polymer, shape memory polymer to facilitate macro scale damage closure, and a means for molecular scale healing is disclosed; the composition has the ability to resolve structural defects by a bio-mimetic close-then heal process. In use, the shape memory polymer serves to bring surfaces of a structural defect into approximation, whereafter use of the means for molecular scale healing allowed for movement of the healing means into the defect and thus obtain molecular scale healing. The means for molecular scale healing can be a thermoplastic such as fibers, particles or spheres which are used by heating to a level at or above the thermoplastic's melting point, then cooling of the composition below the melting temperature of the thermoplastic. Compositions of the invention have the ability to not only close macroscopic defects, but also to do so repeatedly even if another wound/damage occurs in a previously healed/repaired area.

A method of enhancing carbonate precipitation in a downhole environment comprises introducing into the downhole environment a treatment composition comprising: a carbonate producing agent comprising a microbe, an enzyme, or a combination comprising at least one of the foregoing, and a substrate comprising N-oxyurea, semicarbazide, N,N-dioxyurea, or a combination comprising at least one of the foregoing. An organic feedstock and a geobacter can also be used to treating a wellbore or a subterranean formation. Encapsulated carbonate producing agent such as encapsulated bacterial spores are used to form self-healing cemented structure in a downhole environment.

A method of enhancing carbonate precipitation in a downhole environment comprises introducing into the downhole environment a treatment composition comprising: a carbonate producing agent comprising a microbe, an enzyme, or a combination comprising at least one of the foregoing, and a substrate comprising N-oxyurea, semicarbazide, N,N-dioxyurea, or a combination comprising at least one of the foregoing. An organic feedstock and a geobacter can also be used to treating a wellbore or a subterranean formation. Encapsulated carbonate producing agent such as encapsulated bacterial spores are used to form self-healing cemented structure in a downhole environment.

A composition comprising thermoset polymer, shape memory polymer to facilitate macro scale damage closure, and methods for molecular scale healing are provided. The composition can resolve structural defects by a bio-mimetic close-then heal process. In use, the shape memory polymer can provide molecular scale healing in a structural defect. The methods for molecular scale healing can include heating a composition including a thermoplastic such as fibers, particles or spheres to a level at or above the thermoplastic's melting point, then cooling of the composition below the melting temperature of the thermoplastic. The compositions have the ability to close macroscopic defects repeatedly even if another wound/damage occurs in a previously healed/repaired area.

A composition comprising thermoset polymer, shape memory polymer to facilitate macro scale damage closure, and methods for molecular scale healing are provided. The composition can resolve structural defects by a bio-mimetic close-then heal process. In use, the shape memory polymer can provide molecular scale healing in a structural defect. The methods for molecular scale healing can include heating a composition including a thermoplastic such as fibers, particles or spheres to a level at or above the thermoplastic's melting point, then cooling of the composition below the melting temperature of the thermoplastic. The compositions have the ability to close macroscopic defects repeatedly even if another wound/damage occurs in a previously healed/repaired area.

A method of diffusing CO.sub.2 within a concrete mixture that includes mixing a non-recycled aggregate material with a CO.sub.2 gas in a pretreatment chamber of a concrete preparation system to form a CO.sub.2 adsorbed aggregate material, transferring the CO.sub.2 adsorbed aggregate material from the pretreatment chamber into a cement mixing chamber of the concrete preparation system, and mixing the CO.sub.2 adsorbed aggregate material with cement and water to form the concrete mixture, where mixing the CO.sub.2 adsorbed aggregate material with cement and water releases CO.sub.2 from the CO.sub.2 adsorbed aggregate material and diffuses CO.sub.2 into the concrete mixture to form a carbonated concrete mixture.

A method of diffusing CO.sub.2 within a concrete mixture that includes mixing a non-recycled aggregate material with a CO.sub.2 gas in a pretreatment chamber of a concrete preparation system to form a CO.sub.2 adsorbed aggregate material, transferring the CO.sub.2 adsorbed aggregate material from the pretreatment chamber into a cement mixing chamber of the concrete preparation system, and mixing the CO.sub.2 adsorbed aggregate material with cement and water to form the concrete mixture, where mixing the CO.sub.2 adsorbed aggregate material with cement and water releases CO.sub.2 from the CO.sub.2 adsorbed aggregate material and diffuses CO.sub.2 into the concrete mixture to form a carbonated concrete mixture.

A method of sealing propagating cracks in a sensor-laden cement sheath comprising the steps of monitoring an electrical resistivity of the sensor-laden cement sheath to produce a measured value, wherein the sensor-laden cement sheath comprises a conductive sensor, an on-demand expanding agent, and a cement, activating a heat source when the measured value of the electrical resistivity is greater than an activation threshold, increasing a temperature of the sensor-laden cement sheath with the heat source to an activation temperature, wherein the activation temperature is operable to initiate a reaction between the on-demand expanding agent and water, wherein the activation temperature is greater than a formation temperature, reacting the on-demand expanding agent with water to produce a swelled agent, wherein the swelled agent occupies a greater volume than the on-demand expanding agent, and sealing the propagating cracks in the sensor-laden cement sheath with the swelled agent.

A method of sealing propagating cracks in a sensor-laden cement sheath comprising the steps of monitoring an electrical resistivity of the sensor-laden cement sheath to produce a measured value, wherein the sensor-laden cement sheath comprises a conductive sensor, an on-demand expanding agent, and a cement, activating a heat source when the measured value of the electrical resistivity is greater than an activation threshold, increasing a temperature of the sensor-laden cement sheath with the heat source to an activation temperature, wherein the activation temperature is operable to initiate a reaction between the on-demand expanding agent and water, wherein the activation temperature is greater than a formation temperature, reacting the on-demand expanding agent with water to produce a swelled agent, wherein the swelled agent occupies a greater volume than the on-demand expanding agent, and sealing the propagating cracks in the sensor-laden cement sheath with the swelled agent.

Disclosed are biopolymeric and biologically active mortars suitable for use in providing building materials having enhanced physical properties. Further disclosed are methods for making and using the disclosed materials.