A method of diffusing CO.sub.2 within a concrete mixture that includes mixing a non-recycled aggregate material with a CO.sub.2 gas in a pretreatment chamber of a concrete preparation system to form a CO.sub.2 adsorbed aggregate material, transferring the CO.sub.2 adsorbed aggregate material from the pretreatment chamber into a cement mixing chamber of the concrete preparation system, and mixing the CO.sub.2 adsorbed aggregate material with cement and water to form the concrete mixture, where mixing the CO.sub.2 adsorbed aggregate material with cement and water releases CO.sub.2 from the CO.sub.2 adsorbed aggregate material and diffuses CO.sub.2 into the concrete mixture to form a carbonated concrete mixture.

A method of diffusing CO.sub.2 within a concrete mixture that includes mixing a non-recycled aggregate material with a CO.sub.2 gas in a pretreatment chamber of a concrete preparation system to form a CO.sub.2 adsorbed aggregate material, transferring the CO.sub.2 adsorbed aggregate material from the pretreatment chamber into a cement mixing chamber of the concrete preparation system, and mixing the CO.sub.2 adsorbed aggregate material with cement and water to form the concrete mixture, where mixing the CO.sub.2 adsorbed aggregate material with cement and water releases CO.sub.2 from the CO.sub.2 adsorbed aggregate material and diffuses CO.sub.2 into the concrete mixture to form a carbonated concrete mixture.

A composition of a cement additive material to improve durability of cementitious structures, was disclosed. The cement additive composition includes an admixture of one or more of divalent magnesium metal silicates with capacity to act as a latent hydraulic binder in said composition activated by a hydration process under aqueous conditions, and in particular the divalent metal silicate is magnesium-dominated silicate, preferably comprising mineral groups of olivines, orthopyroxenes, amphiboles, and serpentines or mixtures thereof. The composition also includes chloride ions or brine.

Admixture for cementitious building materials can provide a self-healing mechanism to improve material longevity. In certain embodiments, the admixture can include the combination of both a quicklime-based replacement for fine and coarse aggregates and an SCM replacement for OPC in standard mortar and concrete.

Admixture for cementitious building materials can provide a self-healing mechanism to improve material longevity. In certain embodiments, the admixture can include the combination of both a quicklime-based replacement for fine and coarse aggregates and an SCM replacement for OPC in standard mortar and concrete.

A method of sealing propagating cracks in a sensor-laden cement sheath comprising the steps of monitoring an electrical resistivity of the sensor-laden cement sheath to produce a measured value, wherein the sensor-laden cement sheath comprises a conductive sensor, an on-demand expanding agent, and a cement, activating a heat source when the measured value of the electrical resistivity is greater than an activation threshold, increasing a temperature of the sensor-laden cement sheath with the heat source to an activation temperature, wherein the activation temperature is operable to initiate a reaction between the on-demand expanding agent and water, wherein the activation temperature is greater than a formation temperature, reacting the on-demand expanding agent with water to produce a swelled agent, wherein the swelled agent occupies a greater volume than the on-demand expanding agent, and sealing the propagating cracks in the sensor-laden cement sheath with the swelled agent.

A method of sealing propagating cracks in a sensor-laden cement sheath comprising the steps of monitoring an electrical resistivity of the sensor-laden cement sheath to produce a measured value, wherein the sensor-laden cement sheath comprises a conductive sensor, an on-demand expanding agent, and a cement, activating a heat source when the measured value of the electrical resistivity is greater than an activation threshold, increasing a temperature of the sensor-laden cement sheath with the heat source to an activation temperature, wherein the activation temperature is operable to initiate a reaction between the on-demand expanding agent and water, wherein the activation temperature is greater than a formation temperature, reacting the on-demand expanding agent with water to produce a swelled agent, wherein the swelled agent occupies a greater volume than the on-demand expanding agent, and sealing the propagating cracks in the sensor-laden cement sheath with the swelled agent.

Methods and systems that utilize reactive metals that hydrate in the presence of a wellbore fluid. The reactive metals can be utilized in cement compositions, on the outer surface of the oilfield tubular in the form of a layer of the reactive metal(s), or on the outer surface of the oilfield tubular in the form of a layer of a composition that includes the reactive metal(s).

Methods and systems that utilize reactive metals that hydrate in the presence of a wellbore fluid. The reactive metals can be utilized in cement compositions, on the outer surface of the oilfield tubular in the form of a layer of the reactive metal(s), or on the outer surface of the oilfield tubular in the form of a layer of a composition that includes the reactive metal(s).

Cement slurries, cured cements, and methods of making cured cement and methods of using cement slurries are provided. The cement slurries have, among other attributes, improved elasticity and self-healing properties and may be used, for instance, in the oil and gas drilling industry. The cement slurry comprises water, a cement precursor material, and a block copolymer composition. The block copolymer composition has at least one copolymer backbone, with each copolymer backbone comprising at least two hard segments. Furthermore, a soft segment is disposed between the at least two hard segments. The copolymer backbone has at least one anhydride group grafted onto the soft segment, and the anhydride group is crosslinked by an aminosilane crosslinker.