According to at least one embodiment of the present description, a cement slurry includes 1% to 90% BWOC of a cement precursor material based on the total weight of the cement slurry; and from 1% to 40% BWOC of a swelling additive based on the total weight of the cement slurry. The swelling additive comprises at least one micronized rubber, at least one distillate, and at least one solvent-refined heavy paraffinic.

According to at least one embodiment of the present description, a cement slurry includes 1% to 90% BWOC of a cement precursor material based on the total weight of the cement slurry; and from 1% to 40% BWOC of a swelling additive based on the total weight of the cement slurry. The swelling additive comprises at least one micronized rubber, at least one distillate, and at least one solvent-refined heavy paraffinic.

A method of enhancing carbonate precipitation in a downhole environment comprises introducing into the downhole environment a treatment composition comprising: a carbonate producing agent comprising a microbe, an enzyme, or a combination comprising at least one of the foregoing, and a substrate comprising N-oxyurea, semicarbazide, N,N-dioxyurea, or a combination comprising at least one of the foregoing. An organic feedstock and a geobacter can also be used to treating a wellbore or a subterranean formation. Encapsulated carbonate producing agent such as encapsulated bacterial spores are used to form self-healing cemented structure in a downhole environment.

A method of enhancing carbonate precipitation in a downhole environment comprises introducing into the downhole environment a treatment composition comprising: a carbonate producing agent comprising a microbe, an enzyme, or a combination comprising at least one of the foregoing, and a substrate comprising N-oxyurea, semicarbazide, N,N-dioxyurea, or a combination comprising at least one of the foregoing. An organic feedstock and a geobacter can also be used to treating a wellbore or a subterranean formation. Encapsulated carbonate producing agent such as encapsulated bacterial spores are used to form self-healing cemented structure in a downhole environment.

A composition comprising thermoset polymer, shape memory polymer to facilitate macro scale damage closure, and a means for molecular scale healing is disclosed; the composition has the ability to resolve structural defects by a bio-mimetic close-then heal process. In use, the shape memory polymer serves to bring surfaces of a structural defect into approximation, whereafter use of the means for molecular scale healing allowed for movement of the healing means into the defect and thus obtain molecular scale healing. The means for molecular scale healing can be a thermoplastic such as fibers, particles or spheres which are used by heating to a level at or above the thermoplastic's melting point, then cooling of the composition below the melting temperature of the thermoplastic. Compositions of the invention have the ability to not only close macroscopic defects, but also to do so repeatedly even if another wound/damage occurs in a previously healed/repaired area.

A composition comprising thermoset polymer, shape memory polymer to facilitate macro scale damage closure, and a means for molecular scale healing is disclosed; the composition has the ability to resolve structural defects by a bio-mimetic close-then heal process. In use, the shape memory polymer serves to bring surfaces of a structural defect into approximation, whereafter use of the means for molecular scale healing allowed for movement of the healing means into the defect and thus obtain molecular scale healing. The means for molecular scale healing can be a thermoplastic such as fibers, particles or spheres which are used by heating to a level at or above the thermoplastic's melting point, then cooling of the composition below the melting temperature of the thermoplastic. Compositions of the invention have the ability to not only close macroscopic defects, but also to do so repeatedly even if another wound/damage occurs in a previously healed/repaired area.

Various embodiments disclosed relate to compositions including a plurality of capsules each independently comprising an outer wall and an inner compartment, the inner compartment independently comprising at least one of a first hardenable resin, a first hardener or activator, and a solvent, self-healing hardened resins formed from the same, and methods of using the same. In various embodiments, the present invention provides a method of treating a subterranean formation including placing the composition in a subterranean formation, and forming a selfhealing hardened resin in the subterranean formation from the composition.

Various embodiments disclosed relate to compositions including a plurality of capsules each independently comprising an outer wall and an inner compartment, the inner compartment independently comprising at least one of a first hardenable resin, a first hardener or activator, and a solvent, self-healing hardened resins formed from the same, and methods of using the same. In various embodiments, the present invention provides a method of treating a subterranean formation including placing the composition in a subterranean formation, and forming a selfhealing hardened resin in the subterranean formation from the composition.

Provided are a marine concrete composition using dechlorination microorganisms capable of easily removing chlorine generated by seawater through an electrical method by allowing electrons emitted from electricity-generating microorganisms to flow through steel fibers incorporated into ultra-high-performance concrete (UHPC) or high-performance fiber reinforced concrete (HPFRCC) through a dechlorination microbial capsule carrier and capable of self-healing concrete crack sites through a self-healing microbial capsule carrier and is also capable of fundamentally solving the problem of reduced durability against salt damage of ultra-high-performance concrete or high-performance fiber reinforced concrete for application in marine construction environments through a dechlorination microbial capsule carrier, and a method for constructing a marine concrete structure using the same.

Cement compositions containing a cement component and an oil-immiscible solvent and methods for using same are provided. In another aspect, methods for sealing subterranean zones are provided that include emplacing a cement composition into a wellbore containing a cement component and an oil-immiscible solvent, contacting the cement composition with a water source, and reacting the cement composition with the water source to form a hardened cement.