This disclosure relates to an inorganic-organic metal phosphate ceramic coating from the reaction of an inorganic phosphate of the formulas (i) A.sub.m(H.sub.2PO.sub.4).sub.m.nH.sub.2O or (ii) AH.sub.3(PO.sub.4).sub.2.nH.sub.2O; where A is ammonium or an m-valent metal element; m=1, 2, or 3; and n is 0 to 25; and at least one metal oxide or hydroxide represented by the formula B.sub.2mO.sub.m or B(OH).sub.2m, where B is a 2m-valent metal; and m=1 or 1.5; thereof; and at least one polymer capable of reacting with at least the one metal oxide or hydroxide; or a first organic precursor combined with the inorganic phosphate and a second organic precursor combined with the at least one metal oxide or hydroxide, the second organic precursor configured to chemically react with the one or more first organic precursor.

A multi-functional open graded friction course and a method of treating highway water runoff using the multi-functional open graded friction course are described herein. Open graded friction course is treated with an additive or additives, such as, but not limited to, an adsorbent. After treatment with the additive, the additive remains in the void spaces in the open graded friction course, thus creating a multi-functional open graded friction course. When highway or roadway water runoff flows into the void spaces, pollutants, such as heavy metals, are adsorbed by the additives and the water then flows laterally out of the multi-functional open graded friction course.

A cement-based tile formed from a mixture comprising: a cement in the range of about 0.1 to 88% by wet weight percent; a secondary material in the range of about 0.1 to 50% by wet weight percent, the secondary material comprising limestone, sand, silica sand, gypsum, silica fume, fumed silica, Plaster of Paris, calcium carbonate, fly ash, slag, rock, or a combination thereof; a reinforcement fiber in the range of about 0.5 to 20% by wet weight percent, the reinforcement fiber comprising cellulose fiber, glass fiber, plastic fiber, polypropylene fiber, polyvinyl alcohol (PVA) fiber, homopolymer acrylic fiber, alkali-resistant fiber, or a combination thereof; a rheology modifying agent in the range of about 0.5 to 10% by wet weight percent; a water in the range of 10 to 60% of a total wet material weight; and wherein the mixture is extruded or molded to form the cement-based tile.

A cement-based tile formed from a mixture comprising: a cement in the range of about 0.1 to 88% by wet weight percent; a secondary material in the range of about 0.1 to 50% by wet weight percent, the secondary material comprising limestone, sand, silica sand, gypsum, silica fume, fumed silica, Plaster of Paris, calcium carbonate, fly ash, slag, rock, or a combination thereof; a reinforcement fiber in the range of about 0.5 to 20% by wet weight percent, the reinforcement fiber comprising cellulose fiber, glass fiber, plastic fiber, polypropylene fiber, polyvinyl alcohol (PVA) fiber, homopolymer acrylic fiber, alkali-resistant fiber, or a combination thereof; a rheology modifying agent in the range of about 0.5 to 10% by wet weight percent; a water in the range of 10 to 60% of a total wet material weight; and wherein the mixture is extruded or molded to form the cement-based tile.

This disclosure relates to an inorganic-organic metal phosphate ceramic coating from the reaction of an inorganic phosphate of the formulas (i) A.sub.m(H.sub.2PO.sub.4).sub.m.Math.nH.sub.2O or (ii) AH.sub.3(PO.sub.4).sub.2.Math.nH.sub.2O; where A is ammonium or an m-valent metal element; m=1, 2, or 3; and n is 0 to 25; and at least one metal oxide or hydroxide represented by the formula B.sub.2mO.sub.m or B(OH).sub.2m, where B is a 2m-valent metal; and m=1 or 1.5; thereof; and at least one polymer capable of reacting with at least the one metal oxide or hydroxide; or a first organic precursor combined with the inorganic phosphate and a second organic precursor combined with the at least one metal oxide or hydroxide, the second organic precursor configured to chemically react with the one or more first organic precursor.

This disclosure relates to an inorganic-organic metal phosphate ceramic coating from the reaction of an inorganic phosphate of the formulas (i) A.sub.m(H.sub.2PO.sub.4).sub.m.Math.nH.sub.2O or (ii) AH.sub.3(PO.sub.4).sub.2.Math.nH.sub.2O; where A is ammonium or an m-valent metal element; m=1, 2, or 3; and n is 0 to 25; and at least one metal oxide or hydroxide represented by the formula B.sub.2mO.sub.m or B(OH).sub.2m, where B is a 2m-valent metal; and m=1 or 1.5; thereof; and at least one polymer capable of reacting with at least the one metal oxide or hydroxide; or a first organic precursor combined with the inorganic phosphate and a second organic precursor combined with the at least one metal oxide or hydroxide, the second organic precursor configured to chemically react with the one or more first organic precursor.

The embodiments herein are directed to dry wall waste mixtures, formed under pressure into example embodiments referred to herein as dry wall waste blocks (DWBs) and/or gypsum wallboard waste blocks (GWWBs) and tile structures. DWBs/GWWBs mixtures in particular, often incorporate a higher percentage in the composite mixtures from about 60% up to 85% of dry wall waste than other mixtures and beneficially often incorporates substantially all of the wallboard facing paper as part of the composite mixture. That is, waste processing is simplified by comingling core and paper layers in the final product. DWBs/GWWBs mixtures utilize demolition and construction waste, replacing a high percentage of Portland cement with waste-derived binder.

The embodiments herein are directed to dry wall waste mixtures, formed under pressure into example embodiments referred to herein as dry wall waste blocks (DWBs) and/or gypsum wallboard waste blocks (GWWBs) and tile structures. DWBs/GWWBs mixtures in particular, often incorporate a higher percentage in the composite mixtures from about 60% up to 85% of dry wall waste than other mixtures and beneficially often incorporates substantially all of the wallboard facing paper as part of the composite mixture. That is, waste processing is simplified by comingling core and paper layers in the final product. DWBs/GWWBs mixtures utilize demolition and construction waste, replacing a high percentage of Portland cement with waste-derived binder.