The present invention relates to a paste comprising amorphous calcium carbonate (ACC) doped with divalent alkaline-earth metal ions, e.g., magnesium ions, or transition metal ions: a dry three-dimensional model made of such a paste, e.g., by 3D-printing process such as robocasting 3D-printing process; and a process for the preparation of said paste.

Process for the production composite articles, comprising the steps of: a) providing a curable mixture comprising: 30-95 wt % of filler material, —5-70 wt % of resin, selected from unsaturated polyester resins, vinyl ester resins, (meth)acrylate resins, and combinations thereof, 0.5-10 phr of at least one peroxyester, 0.1-2.0 phr of at least one organic hydroperoxide, the weight ratio peroxyester/organic hydroperoxide being below 14.0, the curable mixture being essentially free of ketone peroxide, b) shaping the mixture, and c) heating the shaped mixture at a temperature in the range 60-100° C. to affect hardening of the resin and the formation of an article.

Process for the production composite articles, comprising the steps of: a) providing a curable mixture comprising: 30-95 wt % of filler material, —5-70 wt % of resin, selected from unsaturated polyester resins, vinyl ester resins, (meth)acrylate resins, and combinations thereof, 0.5-10 phr of at least one peroxyester, 0.1-2.0 phr of at least one organic hydroperoxide, the weight ratio peroxyester/organic hydroperoxide being below 14.0, the curable mixture being essentially free of ketone peroxide, b) shaping the mixture, and c) heating the shaped mixture at a temperature in the range 60-100° C. to affect hardening of the resin and the formation of an article.

Methods and compositions for reducing gas seepage into a cement slurry. One method includes adding a formulation to the cement slurry, the formulation comprising at least one component responsive to a predetermined concentration of hydrocarbon gas in the cement slurry, where upon the cement slurry reaching the predetermined concentration of hydrocarbon gas, the hydrocarbon gas undergoes at least a partial oxidation caused by the formulation to quicken the setting time of the cement slurry via release of heat by an exothermic reaction.

Methods and compositions for reducing gas seepage into a cement slurry. One method includes adding a formulation to the cement slurry, the formulation comprising at least one component responsive to a predetermined concentration of hydrocarbon gas in the cement slurry, where upon the cement slurry reaching the predetermined concentration of hydrocarbon gas, the hydrocarbon gas undergoes at least a partial oxidation caused by the formulation to quicken the setting time of the cement slurry via release of heat by an exothermic reaction.

A method for reducing gas seepage into a cement slurry. The method includes adding a formulation to the cement slurry, the formulation comprising at least one component responsive to a predetermined concentration of hydrocarbon gas in the cement slurry, where upon the cement slurry reaching the predetermined concentration of hydrocarbon gas, the hydrocarbon gas undergoes at least a partial oxidation caused by the formulation to quicken the setting time of the cement slurry via release of heat by an exothermic reaction.

A method for reducing gas seepage into a cement slurry. The method includes adding a formulation to the cement slurry, the formulation comprising at least one component responsive to a predetermined concentration of hydrocarbon gas in the cement slurry, where upon the cement slurry reaching the predetermined concentration of hydrocarbon gas, the hydrocarbon gas undergoes at least a partial oxidation caused by the formulation to quicken the setting time of the cement slurry via release of heat by an exothermic reaction.

A method of fabricating a coating includes providing a ceramic matrix composite that includes SiC fibers disposed in a SiC matrix, depositing a base slurry on the ceramic matrix composite, wherein the base slurry contains powders of a metal oxide, at least one of silicon carbide, silicon nitride, or free silicon, and barium-magnesium-aluminosilicate in a first carrier fluid, drying the deposited base slurry to produce a base green layer, depositing a transition slurry on the base green layer, wherein the transition slurry contains powders of a metal oxide, at least one of silicon carbide, silicon nitride, or free silicon, at least one of zirconium carbide, zirconium nitride, or zirconium oxide, and barium-magnesium-aluminosilicate in a second carrier fluid, drying the deposited transition slurry to produce a transition green layer, and forming a consolidated coating on the ceramic matrix composite by heating the base green layer and the at least one transition green layer to cause chemical reactions that convert the powders to metal-silicon-oxygen rich phase and metal-zirconium-oxygen rich phase.

A method of fabricating a coating includes providing a ceramic matrix composite that includes SiC fibers disposed in a SiC matrix, depositing a base slurry on the ceramic matrix composite, wherein the base slurry contains powders of a metal oxide, at least one of silicon carbide, silicon nitride, or free silicon, and barium-magnesium-aluminosilicate in a first carrier fluid, drying the deposited base slurry to produce a base green layer, depositing a transition slurry on the base green layer, wherein the transition slurry contains powders of a metal oxide, at least one of silicon carbide, silicon nitride, or free silicon, at least one of zirconium carbide, zirconium nitride, or zirconium oxide, and barium-magnesium-aluminosilicate in a second carrier fluid, drying the deposited transition slurry to produce a transition green layer, and forming a consolidated coating on the ceramic matrix composite by heating the base green layer and the at least one transition green layer to cause chemical reactions that convert the powders to metal-silicon-oxygen rich phase and metal-zirconium-oxygen rich phase.

An antimicrobial ceramic glazing composition contains one or more antimicrobial agents disposed therein. Methods for making and using the glazing composition are disclosed, as well as substrates having a fired antimicrobial glaze thereon. The antimicrobial agents comprise metallic oxides, with a subset of the disclosed combinations exhibiting synergistic effect in fired glazes.