A method of sealing propagating cracks in a sensor-laden cement sheath comprising the steps of monitoring an electrical resistivity of the sensor-laden cement sheath to produce a measured value, wherein the sensor-laden cement sheath comprises a conductive sensor, an on-demand expanding agent, and a cement, activating a heat source when the measured value of the electrical resistivity is greater than an activation threshold, increasing a temperature of the sensor-laden cement sheath with the heat source to an activation temperature, wherein the activation temperature is operable to initiate a reaction between the on-demand expanding agent and water, wherein the activation temperature is greater than a formation temperature, reacting the on-demand expanding agent with water to produce a swelled agent, wherein the swelled agent occupies a greater volume than the on-demand expanding agent, and sealing the propagating cracks in the sensor-laden cement sheath with the swelled agent.

A method of sealing propagating cracks in a sensor-laden cement sheath comprising the steps of monitoring an electrical resistivity of the sensor-laden cement sheath to produce a measured value, wherein the sensor-laden cement sheath comprises a conductive sensor, an on-demand expanding agent, and a cement, activating a heat source when the measured value of the electrical resistivity is greater than an activation threshold, increasing a temperature of the sensor-laden cement sheath with the heat source to an activation temperature, wherein the activation temperature is operable to initiate a reaction between the on-demand expanding agent and water, wherein the activation temperature is greater than a formation temperature, reacting the on-demand expanding agent with water to produce a swelled agent, wherein the swelled agent occupies a greater volume than the on-demand expanding agent, and sealing the propagating cracks in the sensor-laden cement sheath with the swelled agent.

Described herein are compositions useful for controlling fluid flow, for example in a target zone of a subterranean environment, and methods of forming and using the same. The composition generally comprises a quantity of fibers and a quantity of swellable particles, which may be dispersed in a carrier fluid. The composition may be synthesized in the form of a bulk gel or may be gelatinated during use. The fibers in the compositions provide improved performance as compared to prior PPG and RPPG particle-containing compositions. Specifically, the compositions reinforce the re-cross-linked/re-associated hydrogel plug in underground features and support proper rehydration of RPPG particles with water or brine to better to provide structural support for the particles within the gel and to more completely fill underground void space conduits.

Compositions, methods, and systems for mitigating annular pressure buildup in a wellbore. A method comprises introducing a spacer fluid into an annulus of the wellbore, wherein the spacer fluid comprises an aqueous base fluid, an acid swellable polymer, and a hydrolysable ester. The method further comprises allowing or causing to allow at least a portion of the spacer fluid to remain in the annulus; and allowing or causing to allow a temperature to increase in the annulus to the temperature sufficient to hydrolyze the hydrolysable ester; wherein hydrolysis of the hydrolysable ester produces an acid; wherein the acid reacts with the acid swellable polymer to produce a salt; and wherein the produced salt has a thermal expansion coefficient less than that of the aqueous base fluid.

Some embodiments of the present invention comprise a method of cementing comprising: placing a settable composition into a well bore, the settable composition comprising RFA, hydraulic cement, and water; and allowing the settable composition to set. Other embodiments comprise a method of cementing comprising: placing a settable composition into a well bore, the settable composition comprising RFA, calcium hydroxide (lime), and water; and allowing the settable composition to set. Other embodiments comprise a settable composition comprising: RFA, hydraulic cement, calcium hydroxide, natural pozzolan and water; and allowing the composition to set. Other embodiments comprise a settable composition comprising RFA and any combination of hydraulic cement, calcium hydroxide, slag, fly ash, and natural or other pozzolan.

Some embodiments of the present invention comprise a method of cementing comprising: placing a settable composition into a well bore, the settable composition comprising RFA, hydraulic cement, and water; and allowing the settable composition to set. Other embodiments comprise a method of cementing comprising: placing a settable composition into a well bore, the settable composition comprising RFA, calcium hydroxide (lime), and water; and allowing the settable composition to set. Other embodiments comprise a settable composition comprising: RFA, hydraulic cement, calcium hydroxide, natural pozzolan and water; and allowing the composition to set. Other embodiments comprise a settable composition comprising RFA and any combination of hydraulic cement, calcium hydroxide, slag, fly ash, and natural or other pozzolan.

A method of treating a pond, lake or other body of water to improve the retention of water includes treating the ground at the bed of the pond with bentonite clay, a super absorbent polymer, a polysaccharide, and a polymer flocculant. The bentonite clay can be granulated #16 Wyoming bentonite clay, the super absorbent polymer can be granulated polyacrylamide, the polysaccharide can be granulated carboxy methyl cellulose, and the polymer flocculant can be a high-performance polymer flocculant, such as 2-Propenoic Acid, polymer with 2-Promenamide, sodium salt 90-100%.

A method of treating a pond, lake or other body of water to improve the retention of water includes treating the ground at the bed of the pond with bentonite clay, a super absorbent polymer, a polysaccharide, and a polymer flocculant. The bentonite clay can be granulated #16 Wyoming bentonite clay, the super absorbent polymer can be granulated polyacrylamide, the polysaccharide can be granulated carboxy methyl cellulose, and the polymer flocculant can be a high-performance polymer flocculant, such as 2-Propenoic Acid, polymer with 2-Promenamide, sodium salt 90-100%.

Cementitious mixtures, compositions for use in cementitious mixtures, and methods of producing cementitious mixtures wherein the compositions are suitable for modifying or improving certain properties of the cementitious mixtures. The compositions include a superabsorbent polymer (SAP) hydrogel having a macromolecular network structure, and at least one pozzolanic material that is chemically incorporated into the macromolecular network structure of the SAP hydrogel.

Disclosed herein are compositions and methods for increasing the viscosity of a calcium-containing fluid by addition of a modifying agent. The resulting enhanced viscosity fluid may be used in a variety of applications including drilling, to create an enhanced-viscosity fluid, and demolition/mining to create an expansive putty for use in underwater and overhead applications.