Cement slurries, cured cements, and methods of making cured cement and methods of using cement slurries are provided. The cement slurries have, among other attributes, improved elasticity and self-healing properties and may be used, for instance, in the oil and gas drilling industry. The cement slurry comprises water, a cement precursor material, and a block copolymer composition. The block copolymer composition has at least one copolymer backbone, with each copolymer backbone comprising at least two hard segments. Furthermore, a soft segment is disposed between the at least two hard segments. The copolymer backbone has at least one anhydride group grafted onto the soft segment, and the anhydride group is crosslinked by an aminosilane crosslinker.

Cement slurries are prepared that comprise water, a hydraulic cement, particles of an oil-absorbent particles and non-swellable hydrophobic particles. The particles are present in an amount sufficient to alter a property of a non-aqueous drilling fluid. The cement slurry is placed in a subterranean well, whereupon the slurry contacts residual drilling fluid on casing and formation surfaces. The oil-absorbent particles and hydrophobic particles in the cement slurry may reduce the mobility of the drilling fluid, thereby improving zonal isolation.

Cement slurries are prepared that comprise water, a hydraulic cement, particles of an oil-absorbent particles and non-swellable hydrophobic particles. The particles are present in an amount sufficient to alter a property of a non-aqueous drilling fluid. The cement slurry is placed in a subterranean well, whereupon the slurry contacts residual drilling fluid on casing and formation surfaces. The oil-absorbent particles and hydrophobic particles in the cement slurry may reduce the mobility of the drilling fluid, thereby improving zonal isolation.

Embodiments of the invention relate to concrete admixtures, provide a phosphonato block polymer, a preparation method and an application. The method includes: the phosphonato block polymer prepared by copolycondensating an ether-type segment A, a phosphonato segment B, and a third part of aldehyde C. The ether-type segment A is obtained by polycondensating a polyether monomer and a first part of aldehyde C. The phosphonato segment B is obtained by polycondensating a monomer b containing phosphonato, a monomer c, and a second part of aldehyde C in an aprotic weak polar solvent E. By preparing a block polymer using arylalkane as a main chain and using a phosphonic acid or phosphinic acid functional group as an adsorption group, the invention improves the resistance of the block polymer to sulfate and clay interference, and can achieve initial high dispersion of concrete with a low water-cement ratio and decreasing of the system viscosity.

The present invention relates to the use of a copolymer as a dispersant for binder compositions based on calcium sulfate, the copolymer having a polymer backbone and sidechains bound thereto, and at least one ionizable monomeric unit M1 and at least one sidechain-carrying monomeric unit M2, characterized in that the copolymer has, in a direction along the polymer backbone, a non-random distribution of the monomeric units M1 and/or of the monomeric units M2.

The present invention relates to admixtures, especially a dispersant for solid particles, in particular a dispersant for mineral binder compositions, comprising: a) a superplasticizer and b) a copolymer having a polymer backbone and side chains bonded thereto, comprising at least one ionizable monomer unit M1 and at least one side chain-bearing monomer unit M2, wherein the copolymer has a nonrandom distribution of the monomer units M1 and/or the monomer units M2 in a direction along the polymer backbone,
and wherein the superplasticizer and the copolymer differ from a chemical and/or structural point of view.

The asphalt composition of the present invention is an asphalt composition comprising 1% to 15% by mass of a block copolymer (a) and an asphalt (c), wherein the block copolymer (a) comprises a specific block copolymer (a-1) and a specific block copolymer (a-2) in specific amounts, wherein the content of a vinyl aromatic monomer unit in the block copolymer (a) is 34% by mass or more and 55% by mass or less, the number average molecular weight of the block copolymer (a-1) is in the range of 20,000 to 73,000, and the number average molecular weight of the block copolymer (a-2) is 1.5 to 5.0 times higher than the number average molecular weight of the block copolymer (a-1).

Aqueous admixtures for inorganic binder compositions, useful in the field of additive manufacturing including a) 12-55, preferably 15-50 weight-%, especially 20-45 weight-% of at least one anionic polymer selected from the group consisiting of plasticizers, water reducers, superplasticizers and workability retainers for inorganic binders, b) 15-35 weight-%, preferably 20-30 weight-% of at least one water insoluble liquid defoamer, and c) optionally 1-10 weight-%, preferably 2-5 weight-% of at least one retarder, based on 100 weight-% of the aqueous composition.

Cement slurries, cured cements, and methods of making cured cement and methods of using cement slurries are provided. The cement slurries have, among other attributes, improved expanding capabilities and may be used, for instance, in the oil and gas drilling industry. The cement slurry comprises water, a cement precursor material, and an expanding agent. The expanding agent comprising at least a poly(acrylic acid)-metal oxide nanocomposite, where the metal oxide comprises MgO, CaO, or both, and the poly(acrylic acid) comprises a t-butyl terminal group, an isobornyl terminal group, or both.

A blister resistant asphalt impregnating composition comprises asphalt, a linear styrene butadiene block copolymer, a radial styrene butadiene block copolymer, a reactive elastomeric polymer and a fire retardant.