Provided herein are compositions, methods, and systems related to 3D printing a reactive vaterite cement composition, comprising feeding a composition comprising reactive vaterite cement through a 3D printing machine; printing a 3D printed reactive vaterite cement product; and curing the 3D printed reactive vaterite cement product by transforming reactive vaterite cement in the 3D printed reactive vaterite cement product to aragonite and/or calcite during and/or after the curing.

Provided herein are compositions, methods, and systems related to 3D printing a reactive vaterite cement composition, comprising feeding a composition comprising reactive vaterite cement through a 3D printing machine; printing a 3D printed reactive vaterite cement product; and curing the 3D printed reactive vaterite cement product by transforming reactive vaterite cement in the 3D printed reactive vaterite cement product to aragonite and/or calcite during and/or after the curing.

Provided herein are processes for preparing a glass powder pozzolan product, the process including steps of: providing a crushed and clean waste glass; sorting the waste glass post pulverization through a process to take a coarse stream; adding a fine stream collected in the process and milling the coarse and fine streams to provide the glass powder pozzolan product. Glass powder pozzolan products, as well as systems for producing such glass powder pozzolan products, are also provided.

Provided herein are processes for preparing a glass powder pozzolan product, the process including steps of: providing a crushed and clean waste glass; sorting the waste glass post pulverization through a process to take a coarse stream; adding a fine stream collected in the process and milling the coarse and fine streams to provide the glass powder pozzolan product. Glass powder pozzolan products, as well as systems for producing such glass powder pozzolan products, are also provided.

Provided herein are compositions, methods, and systems comprising vaterite and magnesium oxide.

Provided herein are compositions, methods, and systems comprising vaterite and magnesium oxide.

Process for preparing a composition comprising a sulfonated lignin, including: preparing a lignin-containing aqueous suspension having a solids content up to about 45 wt % and a pH greater than about 6, by mixing a lignin with water; heating the aqueous suspension between about 65° C. and 160° C.; sulfonating the lignin using a sulfonating agent generating a sulfite ion and/or bisulfite ion, at a temperature of from about 90° C. to 160° C., at a sulfonation pH of from about 6 to 11 and at a molar ratio of sulfonating agent to lignin between about 0.1:1 and 1.5:1 on a sulfite to monomeric lignin sub-unit basis; and cooling the sulfonated lignin-containing resulting mixture. The sulfonated lignin, in aqueous mixture or as a powder, can be used as a dispersant in several products including for instance concrete, grout, mortar, oil-well cement, cement board, gypsum wallboard, agricultural products, drilling fluids, coal slurries.

Process for preparing a composition comprising a sulfonated lignin, including: preparing a lignin-containing aqueous suspension having a solids content up to about 45 wt % and a pH greater than about 6, by mixing a lignin with water; heating the aqueous suspension between about 65° C. and 160° C.; sulfonating the lignin using a sulfonating agent generating a sulfite ion and/or bisulfite ion, at a temperature of from about 90° C. to 160° C., at a sulfonation pH of from about 6 to 11 and at a molar ratio of sulfonating agent to lignin between about 0.1:1 and 1.5:1 on a sulfite to monomeric lignin sub-unit basis; and cooling the sulfonated lignin-containing resulting mixture. The sulfonated lignin, in aqueous mixture or as a powder, can be used as a dispersant in several products including for instance concrete, grout, mortar, oil-well cement, cement board, gypsum wallboard, agricultural products, drilling fluids, coal slurries.

The present invention relates to an additive for hydraulically setting compositions comprising a colloidally disperse preparation comprising at least one salt of a polyvalent metal cation with at least one organic phosphonate and/or phosphate compound as anion and at least one polymeric dispersant comprising anionic and/or anionogenic groups and polyether side chains. The additive is especially suitable as slump retainer and for improving early strength.

The present invention relates to an additive for hydraulically setting compositions comprising a colloidally disperse preparation comprising at least one salt of a polyvalent metal cation with at least one organic phosphonate and/or phosphate compound as anion and at least one polymeric dispersant comprising anionic and/or anionogenic groups and polyether side chains. The additive is especially suitable as slump retainer and for improving early strength.