A cementitious mixture for a 3D printer and its relative use are described, more specifically for the production of finished products having a complex geometry using a 3D printing apparatus.

Methods and systems of reducing lost circulation in a wellbore are provided. An example method includes providing a pozzolan slurry comprising a pozzolanic material and water; and providing a calcium slurry comprising a calcium source, a high pH activator, and water. The method further comprises allowing the pozzolan slurry and the calcium slurry to remain separate; wherein at least one of the pozzolan slurry and the calcium slurry comprise a thixotropic material; wherein at least one of the pozzolan slurry and the calcium slurry comprise a dispersant; wherein at least one of the pozzolan slurry and the calcium slurry comprise a weighting agent. The method additionally comprises mixing the pozzolan slurry and the calcium slurry to form a two-part thixotropic lost circulation slurry after the allowing the pozzolan slurry and the calcium slurry to remain separate. The method also includes introducing the two-part thixotropic lost circulation slurry to a lost circulation zone within the wellbore; and allowing or causing to allow the two-part thixotropic lost circulation slurry to set into a hardened mass within the lost circulation zone.

Methods and systems of reducing lost circulation in a wellbore are provided. An example method includes providing a pozzolan slurry comprising a pozzolanic material and water; and providing a calcium slurry comprising a calcium source, a high pH activator, and water. The method further comprises allowing the pozzolan slurry and the calcium slurry to remain separate; wherein at least one of the pozzolan slurry and the calcium slurry comprise a thixotropic material; wherein at least one of the pozzolan slurry and the calcium slurry comprise a dispersant; wherein at least one of the pozzolan slurry and the calcium slurry comprise a weighting agent. The method additionally comprises mixing the pozzolan slurry and the calcium slurry to form a two-part thixotropic lost circulation slurry after the allowing the pozzolan slurry and the calcium slurry to remain separate. The method also includes introducing the two-part thixotropic lost circulation slurry to a lost circulation zone within the wellbore; and allowing or causing to allow the two-part thixotropic lost circulation slurry to set into a hardened mass within the lost circulation zone.

Method of efficiently manufacturing cement-SCM compositions having improved strength compared to cement-SCM compositions made using conventional methods. The cement-SCM compositions may contain: (A) a fine interground particulate component with (1) a hydraulic cement fraction and (2) a supplementary cementitious material (SCM) fraction; (B) a coarse particulate component comprised of coarse SCM particles not interground with the fine interground particulate component; and optionally (C) an auxiliary particulate component not interground with the fine interground particulate component or the coarse particulate component. A method of manufacturing a cement-SCM composition may be performed by: (A) intergrinding hydraulic cement (e.g., cement clinker) with one or more SCMs to form a fine interground particulate component; (B) blending, without intergrinding, the fine interground particulate component with a coarse particulate component comprised of coarse SCM particles; and optionally (C) further combining, without intergrinding, an auxiliary particulate component with the fine interground particulate component and the coarse particulate component.

Method of efficiently manufacturing cement-SCM compositions having improved strength compared to cement-SCM compositions made using conventional methods. The cement-SCM compositions may contain: (A) a fine interground particulate component with (1) a hydraulic cement fraction and (2) a supplementary cementitious material (SCM) fraction; (B) a coarse particulate component comprised of coarse SCM particles not interground with the fine interground particulate component; and optionally (C) an auxiliary particulate component not interground with the fine interground particulate component or the coarse particulate component. A method of manufacturing a cement-SCM composition may be performed by: (A) intergrinding hydraulic cement (e.g., cement clinker) with one or more SCMs to form a fine interground particulate component; (B) blending, without intergrinding, the fine interground particulate component with a coarse particulate component comprised of coarse SCM particles; and optionally (C) further combining, without intergrinding, an auxiliary particulate component with the fine interground particulate component and the coarse particulate component.

Embodiments of the disclosure provide a printable cementitious composition comprising a cement binder, an aggregate, at least one pozzolanic additive, an accelerator, water, and nanoclay.

Embodiments of the disclosure provide a printable cementitious composition comprising a cement binder, an aggregate, at least one pozzolanic additive, an accelerator, water, and nanoclay.

A method for the use of a clay including: less than 30% of kaolinite; and at least 20% of muscovite and/or illite; from 1% to 20% of smectite; the muscovite and/or illite/kaolinite weight ratio being greater than 1; for the preparation of a geopolymer precursor.

Sorbent components containing halogen, calcium, alumina, and silica are used in combination during coal combustion to produce environmental benefits. Sorbents such as calcium bromide are added to the coal ahead of combustion and other components are added into the flame or downstream of the flame, preferably at minimum temperatures to assure complete formation of the refractory structures that result in various advantages of the methods. When used together, the components reduce emissions of elemental and oxidized mercury; increase the level of Hg, As, Pb, and/or Cl in the coal ash; decrease the levels of leachable heavy metals (such as Hg) in the ash, preferably to levels below the detectable limits; and make a highly cementitious ash product.

Sorbent components containing halogen, calcium, alumina, and silica are used in combination during coal combustion to produce environmental benefits. Sorbents such as calcium bromide are added to the coal ahead of combustion and other components are added into the flame or downstream of the flame, preferably at minimum temperatures to assure complete formation of the refractory structures that result in various advantages of the methods. When used together, the components reduce emissions of elemental and oxidized mercury; increase the level of Hg, As, Pb, and/or Cl in the coal ash; decrease the levels of leachable heavy metals (such as Hg) in the ash, preferably to levels below the detectable limits; and make a highly cementitious ash product.