A variety of systems, methods and compositions are disclosed for cementing in subterranean formations. Embodiments may include the use of slag co-grind in well cementing operations.

A variety of systems, methods and compositions are disclosed for cementing in subterranean formations. Embodiments may include the use of slag co-grind in well cementing operations.

The present invention refers to a mechanically activated cementitious composite for stopping the impact of firearms, which involved the designing of mixes of Portland Composite Cement PCC mechanically activated through high energy mechanical milling (HEM) with other ingredients, such as: Ordinary PCC Cement, fine sand, fibers, and polymeric additives, among other compounds, to prepare high-performance composite walls capable of stopping several calibers up to type 50 (typically loaded in Barret rifles). In accordance with Mexican and US Standards for ballistic tests, which entail the approval of the concrete ballistic-resistant wall as long as it resists one impact with a 50 caliber Barret, the present invention allows the construction of composite walls' (with dimensions of 404015 cm) with mechanically activated cement and performance complying with the standards.

The present invention refers to a mechanically activated cementitious composite for stopping the impact of firearms, which involved the designing of mixes of Portland Composite Cement PCC mechanically activated through high energy mechanical milling (HEM) with other ingredients, such as: Ordinary PCC Cement, fine sand, fibers, and polymeric additives, among other compounds, to prepare high-performance composite walls capable of stopping several calibers up to type 50 (typically loaded in Barret rifles). In accordance with Mexican and US Standards for ballistic tests, which entail the approval of the concrete ballistic-resistant wall as long as it resists one impact with a 50 caliber Barret, the present invention allows the construction of composite walls' (with dimensions of 404015 cm) with mechanically activated cement and performance complying with the standards.

A retrofitting appliqu for stepped application to a building wall construction. For external retrofitting, the system has an air barrier layer impermeable or semi-permeable for moisture, a ventilated air cavity used to modify temperature and/or remove water that may be coming from both sides or to modify the relative humidity of the ventilation air, a layer of thermal insulation, a composite material called Eco-Wrap with capillary active capability, in which a hydronic heating or cooling system may be located, and a surface finishing layer. For internal retrofitting, the system has an air barrier system arranged onto the wall of the building and separated from a layer of permeable or semi-permeable thermal insulation by a ventilated air gap. The layer of insulation, in turn, is in contact with a layer of Eco-Wrap. A permeable interior finishing layer that may also have capillary active performance is in contact with the Eco-Wrap. Methods for installing the retrofitting appliqu are also disclosed.

A retrofitting appliqu for stepped application to a building wall construction. For external retrofitting, the system has an air barrier layer impermeable or semi-permeable for moisture, a ventilated air cavity used to modify temperature and/or remove water that may be coming from both sides or to modify the relative humidity of the ventilation air, a layer of thermal insulation, a composite material called Eco-Wrap with capillary active capability, in which a hydronic heating or cooling system may be located, and a surface finishing layer. For internal retrofitting, the system has an air barrier system arranged onto the wall of the building and separated from a layer of permeable or semi-permeable thermal insulation by a ventilated air gap. The layer of insulation, in turn, is in contact with a layer of Eco-Wrap. A permeable interior finishing layer that may also have capillary active performance is in contact with the Eco-Wrap. Methods for installing the retrofitting appliqu are also disclosed.

Provided is an amphoteric composite hydrogel, including: a polymer having a structure of formula I,

##STR00001##

wherein m, n, p and q are each an integer of 0 to 1000, m+n>100, p+q>100, R is

##STR00002##

R.sub.1 is H or an alkali metal element, and R.sub.2 is H or CH.sub.3; and a pozzolanic material incorporated into the structure of formula 1. Also provided are a cement mortar composition and a concrete composition each comprising the amphoteric composite hydrogel and a method of preparing the amphoteric composite hydrogel.

It has been unexpectedly discovered that the addition of a natural or other pozzolan to non-spec fly ash significantly improves the properties of the non-spec fly ash to the extent it can be certified under ASTM C618 and AASHTO 295, as either a Class F or Class C fly ash. The natural pozzolan may be a volcanic ejecta, such as pumice or perlite. Other pozzolans may also be used for this beneficiation process. Many pozzolans are experimentally tested and may be used to beneficiate non-spec fly ash into certifiable Class F fly ash. Additionally, this disclosure provides a method of converting a Class C fly ash to a more valuable Class F fly ash. This discovery will extend diminishing Class F fly ash supplies and turn non-spec fly ash waste streams into valuable, certified fly ash pozzolan which will protect and enhance concrete, mortars and grouts.

It has been unexpectedly discovered that the addition of a natural or other pozzolan to non-spec fly ash significantly improves the properties of the non-spec fly ash to the extent it can be certified under ASTM C618 and AASHTO 295, as either a Class F or Class C fly ash. The natural pozzolan may be a volcanic ejecta, such as pumice or perlite. Other pozzolans may also be used for this beneficiation process. Many pozzolans are experimentally tested and may be used to beneficiate non-spec fly ash into certifiable Class F fly ash. Additionally, this disclosure provides a method of converting a Class C fly ash to a more valuable Class F fly ash. This discovery will extend diminishing Class F fly ash supplies and turn non-spec fly ash waste streams into valuable, certified fly ash pozzolan which will protect and enhance concrete, mortars and grouts.

Sorbent components containing halogen, calcium, alumina, and silica are used in combination during coal combustion to produce environmental benefits. Sorbents such as calcium bromide are added to the coal ahead of combustion and other components are added into the flame or downstream of the flame, preferably at minimum temperatures to assure complete formation of the refractory structures that result in various advantages of the methods. When used together, the components reduce emissions of elemental and oxidized mercury; increase the level of Hg, As, Pb, and/or Cl in the coal ash; decrease the levels of leachable heavy metals (such as Hg) in the ash, preferably to levels below the detectable limits; and make a highly cementitious ash product.