The present invention relates to the technical field of hydraulic compositions, for example concrete and mortar compositions. More specifically, the present patent application relates to additives used in hydraulic compositions, to the compositions containing same, and also to the method for preparing these additives and to the various uses thereof.

Methods for plasticizing cementitious mixtures having relatively high water/cement ratio (at least 0.40 or higher) are surprisingly improved in terms of dosage efficiency, compared to conventional superplasticizer polycarboxylate polymers, when the comb-type carboxylate copolymer is formed from two different polyether side chains having specifically selected monomer constituents.

The present application concerns the use of a molecule producing an aqueous solution exhibiting a dispersive portion of more than 25%, for improving workability retention in a hydraulic composition based on a hydraulic binder composition including aluminosilicates and a maximum of 10% by weight of clinker preferably from 0 to 10% by weight of clinker.

The invention relates to dispersants for inorganic particles, preferably for hydraulic binders, which comprises the following structural units: i) at least one triazine structural unit, ii) at least one polyalkylene glycol structural unit, and iii) at least two phosphoric ester structural units on at least one carbon atom of one or more aromatic triazine rings of the formulae (IIa) and/or (IIb):
N(CH.sub.2CH.sub.2OPO.sub.3H.sub.2).sub.2,(IIa)
and
NHCH.sub.2CH.sub.2OPO.sub.3H.sub.2.(IIb) The invention also relates to a process for preparing the dispersants, to building material mixtures comprising one or more dispersants and one or more inorganic binders. The invention relates to the use of the dispersants as a water reducing agent, as a means for reducing the viscosity and for enhancing the early strengths of aqueous inorganic binders, and also to the use as a grinding aid in the production of cement.

Construction castable material with controllable flow or slump comprising (a) a binder comprising fly ashes comprising from 1.5% to 35% by weight of CaO and a Lost on Ignition (LOI) value from 0.5% to 5.5% by weight, representing from 10% to 60% of the binder weight and ground granulated blast furnace slag comprising from 40% to 70% by weight of CaO and from 30 to 60% by weight of SiO2, representing from 40% to 90% of the binder weight, (b) an activator comprising alkaline reagents selected from the group composed by water glass, preferably in solution with 30 to 50% by weight solid content, sodium metasilicates and sodium hydroxide, (c) sand, fine and coarse aggregates and (d) organic acids or conjugated salts of organic acids in a dosage from 0.001% to 3% by weight with respect to the binder.

According to one or more embodiments of the present invention, modification of concrete within a pumping line is achieved with new designs of inline static mixers allowing passage of concrete material that is primarily of solids in the form of suspended minerals, cement and aggregates, and without benefit of the flow of additional fluid, such as the airflow driving a shotcrete process. According to one or more embodiments of the present invention, modification within a concrete pumping line is essential where unmodified concrete is necessary for purposes of batching or pumping, such as where the modification creates a very rapid set or an extreme thickening. According to one or more embodiments of the present invention, modification, unmodified concrete can be delivered to the point of inline modification at the end of a pumping line, where highly reactive components can then be intermixed. According to one or more embodiments of the present invention, this allows volume production of Roman Concrete or a hot mortar activated with quicklime, facilitates the inclusion of highly reactive shrinkage compensating agents, makes the use of alkali-activated or geopolymer concrete more practical for large-scale production, and makes possible very rapid additive-manufacturing methods with low-cost conventional delivered concrete.

According to one or more embodiments of the present invention, modification of concrete within a pumping line is achieved with new designs of inline static mixers allowing passage of concrete material that is primarily of solids in the form of suspended minerals, cement and aggregates, and without benefit of the flow of additional fluid, such as the airflow driving a shotcrete process. According to one or more embodiments of the present invention, modification within a concrete pumping line is essential where unmodified concrete is necessary for purposes of batching or pumping, such as where the modification creates a very rapid set or an extreme thickening. According to one or more embodiments of the present invention, modification, unmodified concrete can be delivered to the point of inline modification at the end of a pumping line, where highly reactive components can then be intermixed. According to one or more embodiments of the present invention, this allows volume production of Roman Concrete or a hot mortar activated with quicklime, facilitates the inclusion of highly reactive shrinkage compensating agents, makes the use of alkali-activated or geopolymer concrete more practical for large-scale production, and makes possible very rapid additive-manufacturing methods with low-cost conventional delivered concrete.

Disclosed are an additive of a cement composition including a cross-linked polycarboxylic copolymer and a cement composition including the same. More particularly, an additive of a cement composition including a polycarboxylic copolymer and/or a salt thereof, wherein the polycarboxylic copolymer is a copolymer of a monomer mixture including an alkoxy polyalkylene glycol mono(meth)acrylic acid ester-based monomer, a (meth)acrylic acid-based monomer, and a cross-linking agent containing 5 to 20 alkylene oxide groups and having two or more acrylate groups or vinyl groups, and a cement composition including the same are disclosed. The additive of the cement composition including the polycarboxylic copolymer according to the present invention controls a cross-linked structure and thereby initial sensitivity and retentivity are improved, and, accordingly, a cement composition having superior long-term workability may be formed.

The present invention relates to a polycarbonic acid-based cement dispersant, a method for preparing the same, and a mortar-concrete admixture using the polycarbonic acid-based cement dispersant.

The cement dispersant of the present invention and the mortar-concrete admixture using the cement dispersant are applied to a cement composition such as a cement paste, mortar, concrete, etc., enhance a dispersion and retention force between cement molecules, have excellent fluidity due to the suppression of slump loss, and have an effect of improving workability, such as shortening a concrete mixing time by 20% or more. Further, the mortar-concrete admixture using the cement dispersant of the present invention has an effect of providing a very good concrete condition and an appropriate compressive strength over time.

A ready-mix concrete or mortar, or precast concrete composition has at least one aggregate (A), a binder composition (B), at least one alkali sulfate activator (C), water (D) and at least one water reducing polymer (E). The binder composition includes ground blast furnace slag and one or more optional components being at least one hydraulic binder other than slag, one or more supplementary cementitious materials, and one or more filler materials. The water reducing polymer (E) is a copolymer comprising the following monomeric units, a monomeric unit A between 0 and 40, a monomeric unit B between 25 and 95, a monomeric unit C between 5 and 50, and a monomeric unit D between 0 and 25, the values being in mol %. The ready-mix concrete or mortar, or precast concrete composition is classified in one of the classes S3, S4 and S5 according to standard NF EN 206.