Provided herein are compositions, methods, and systems comprising vaterite and magnesium oxide.

The present disclosure relates to a liquid agent that mitigates shrinkage of cement, particularly cement used in a hydrocarbon-producing well. The anti-shrinkage agent includes a slow-setting calcium aluminate cement as well as gypsum and may exhibit shelf-life stability, physical stability, or both. The present disclosure further relates to methods of cementing a hydrocarbon-producing well using the anti-shrinkage agent and to cements containing the anti-shrinkage agent.

The present disclosure relates to a liquid agent that mitigates shrinkage of cement, particularly cement used in a hydrocarbon-producing well. The anti-shrinkage agent includes a slow-setting calcium aluminate cement as well as gypsum and may exhibit shelf-life stability, physical stability, or both. The present disclosure further relates to methods of cementing a hydrocarbon-producing well using the anti-shrinkage agent and to cements containing the anti-shrinkage agent.

A low-density, high-strength concrete composition that is both self-compacting and lightweight, with a low weight-fraction of aggregate to total dry raw materials, and a highly-homogenous distribution of a non-absorptive and closed-cell lightweight aggregate such as glass microspheres or copolymer polymer beads or a combination thereof, and the steps of providing the composition or components. Lightweight concretes formed therefrom have low density, high strength-to-weight ratios, and high R-value. The concrete has strength similar to that ordinarily found in structural lightweight concrete but at an oven-dried density as low as 40 lbs./cu.ft. The concrete, at the density ordinarily found in structural lightweight concrete, has a higher strength and, at the strength ordinarily found in structural lightweight concrete, a lower density. Such strength-to-density ratios range approximately from above 30 cu.ft/sq.in. to above 110 cu.ft/sq.in., with a 28-day compressive strength ranging from about 3400 to 8000 psi.

A low-density, high-strength concrete composition that is both self-compacting and lightweight, with a low weight-fraction of aggregate to total dry raw materials, and a highly-homogenous distribution of a non-absorptive and closed-cell lightweight aggregate such as glass microspheres or copolymer polymer beads or a combination thereof, and the steps of providing the composition or components. Lightweight concretes formed therefrom have low density, high strength-to-weight ratios, and high R-value. The concrete has strength similar to that ordinarily found in structural lightweight concrete but at an oven-dried density as low as 40 lbs./cu.ft. The concrete, at the density ordinarily found in structural lightweight concrete, has a higher strength and, at the strength ordinarily found in structural lightweight concrete, a lower density. Such strength-to-density ratios range approximately from above 30 cu.ft/sq.in. to above 110 cu.ft/sq.in., with a 28-day compressive strength ranging from about 3400 to 8000 psi.

At least one glycol compound is used as a grinding aid when grinding at least one solid substance, in particular an inorganic and/or mineral solid substance, in a rolling mill, wherein the at least one glycol compound has a structure according to formula I: (formula 1) and wherein a) R1, R2, R3 each independently of one another stand for H or an alkyl, alkoxy or alkanol group with 1-8 carbon atoms, in particular with 2-4 carbon atoms; and b) X stands for a substituted or unsubstituted alkylene group with 1-8 carbon atoms, in particular 1-4 carbon atoms.

At least one glycol compound is used as a grinding aid when grinding at least one solid substance, in particular an inorganic and/or mineral solid substance, in a rolling mill, wherein the at least one glycol compound has a structure according to formula I: (formula 1) and wherein a) R1, R2, R3 each independently of one another stand for H or an alkyl, alkoxy or alkanol group with 1-8 carbon atoms, in particular with 2-4 carbon atoms; and b) X stands for a substituted or unsubstituted alkylene group with 1-8 carbon atoms, in particular 1-4 carbon atoms.

The present invention aims to provide a shrinkage reducing agent that exhibits high performance to reduce the shrinkage of hydraulic materials. The present invention relates to a shrinkage reducing agent for a hydraulic material including a compound that satisfies the following conditions (1) to (4): (1) a ratio represented by {(15-drop flow value of a mortar composition containing the compound)/(15-drop flow value of a mortar free from the compound)}×100 is 120 or less, wherein the (15-drop flow value of a mortar composition containing the compound) means a 15-drop flow value of a mortar composition containing the compound at a solid concentration of 0.1% after 10 minutes mixing and the (15-drop flow value of a mortar free from the compound) means a 15-drop flow value of a mortar free from the compound after 10 minutes mixing; (2) a ratio represented by {(ratio between 15-drop flow values after two hours mixing)/(ratio between 15-drop flow values after 10 minutes mixing)}×100 is 110 or less, wherein the (ratio between 15-drop flow values after two hours mixing) means a ratio of a 15-drop flow value of a mortar composition containing the compound at a solid concentration of 0.1% after two hours mixing to a 15-drop flow value of a mortar free from the compound after two hours mixing, and the (ratio between 15-drop flow values after 10 minutes mixing) means a ratio of a 15-drop flow value of a mortar composition containing the compound at a solid concentration of 0.1% after 10 minutes mixing to a 15-drop flow value of a mortar free from the compound after 10 minutes mixing; (3) the compound has an average particle diameter of 2.2 to 8.5 nm in an alkaline solution; and (4) a product of {(ratio between 15-drop flow values relating to a mortar composition containing the compound at a solid concentration of 1.0%)×(ratio between 15-drop flow values relating to a mortar composition containing the compound at a solid concentration of 0.1%)} is 10,100 or more, wherein the (ratio between 15-drop flow values relating to a mortar composition containing the compound at a solid concentration of 1.0%) means a ratio of a 15-drop flow value of a mortar composition containing the compound at a solid concentration of 1.0% after 10 minutes mixing to a 15-drop flow value of a mortar free from the compound after 10 minutes mixing, and the (ratio between 15-drop flow values relating to a mortar composition containing the compound at a solid concentration of 0.1%) means a ratio of a 15-drop flow value of a mortar composition containing the compound at a solid concentration of 0.1% after 10 minutes mixing to a 15-drop flow value of a mortar free from the compound after 10 minute

The present invention aims to provide a shrinkage reducing agent that exhibits high performance to reduce the shrinkage of hydraulic materials. The present invention relates to a shrinkage reducing agent for a hydraulic material including a compound that satisfies the following conditions (1) to (4): (1) a ratio represented by {(15-drop flow value of a mortar composition containing the compound)/(15-drop flow value of a mortar free from the compound)}×100 is 120 or less, wherein the (15-drop flow value of a mortar composition containing the compound) means a 15-drop flow value of a mortar composition containing the compound at a solid concentration of 0.1% after 10 minutes mixing and the (15-drop flow value of a mortar free from the compound) means a 15-drop flow value of a mortar free from the compound after 10 minutes mixing; (2) a ratio represented by {(ratio between 15-drop flow values after two hours mixing)/(ratio between 15-drop flow values after 10 minutes mixing)}×100 is 110 or less, wherein the (ratio between 15-drop flow values after two hours mixing) means a ratio of a 15-drop flow value of a mortar composition containing the compound at a solid concentration of 0.1% after two hours mixing to a 15-drop flow value of a mortar free from the compound after two hours mixing, and the (ratio between 15-drop flow values after 10 minutes mixing) means a ratio of a 15-drop flow value of a mortar composition containing the compound at a solid concentration of 0.1% after 10 minutes mixing to a 15-drop flow value of a mortar free from the compound after 10 minutes mixing; (3) the compound has an average particle diameter of 2.2 to 8.5 nm in an alkaline solution; and (4) a product of {(ratio between 15-drop flow values relating to a mortar composition containing the compound at a solid concentration of 1.0%)×(ratio between 15-drop flow values relating to a mortar composition containing the compound at a solid concentration of 0.1%)} is 10,100 or more, wherein the (ratio between 15-drop flow values relating to a mortar composition containing the compound at a solid concentration of 1.0%) means a ratio of a 15-drop flow value of a mortar composition containing the compound at a solid concentration of 1.0% after 10 minutes mixing to a 15-drop flow value of a mortar free from the compound after 10 minutes mixing, and the (ratio between 15-drop flow values relating to a mortar composition containing the compound at a solid concentration of 0.1%) means a ratio of a 15-drop flow value of a mortar composition containing the compound at a solid concentration of 0.1% after 10 minutes mixing to a 15-drop flow value of a mortar free from the compound after 10 minute

A calcium sulphate-based product including gypsum and a shrinkage resistance additive. The shrinkage resistance additive is a metal nitrate, hydroxide, acetate or sulphate and is preferably provided in an amount greater than 4 wt % (based on the amount of additive and gypsum). The additive may be a nitrate of an alkali metal (e.g. potassium), an alkaline earth metal (e.g. magnesium or calcium), a transition metal (e.g. iron or zinc) or aluminium.