Geopolymeric compositions are presented that are useful for cementing subterranean wells. The compositions may contain an aluminosilicate source, a metal silicate, an alkali activator and a slurry density modifier that may contain uintaite, vitrified shale, petroleum coke or coal or combinations thereof. Methods for placing the geopolymeric compositions in subterranean wells are also presented.

A method for controlling the volume expansion of a hydraulically setting composition including steel making slag, the method including a step of adding a silica source to the composition. Furthermore, hydraulically setting compositions obtained by such methods and their uses.

Geopolymeric compositions are presented that are useful as geopolymer slurries for cementing subterranean wells. The slurries may contain an aluminosilicate source, an alkaline source, and a carrier fluid. The slurries generate an alkali metal or alkaline earth hydroxide activator in situ, thereby avoiding or reducing handling of alkali materials at a wellsite.

Pumpable slurry compositions including at least one aluminosilicate additive and optional pozzolanic cement additives and methods including the pumpable slurry compositions improve development of compressive strengths in the pumpable cement slurry compositions. The methods utilize one or more pumpable cement slurry compositions including at least one cement component, water, at least one first aluminosilicate additive, at least one optional second aluminosilicate additive, and one or more optional pozzolanic additives, where the at least one first aluminosilicate additive has an amorphous phase of greater than about 50% and a weight ratio of silica oxide to aluminum oxide of about 1.0 to about 2.5, and the at least one optional second aluminosilicate additive has a weight ratio of silica oxide to aluminum oxide of about 1.7 to about 3.3.

A method for sealing of surfaces comprising the steps of: (a) supplying a first grouting composition; (b) introducing a second component to said first grouting composition to form a third grouting composition; and (c) forming a sealing barrier on a surface from said third grouting composition.

A concrete emulsion comprising a cement, aggregate, water, and carbon dioxide is provided. The carbon dioxide may be liquid or supercritical and is dispersed in the concrete emulsion composition. A method of producing a concrete emulsion composition is also provided. The method includes mixing a cement, aggregate, and water to form a hydrated concrete composition, and emulsifying the hydrated concrete composition with liquid or supercritical CO.sub.2. An article comprising the concrete emulsion composition is provided. Further, a method of treating a wellbore comprising producing a concrete emulsion composition and pumping the concrete emulsion composition into a wellbore, and a method of manufacturing an article comprising producing a concrete emulsion composition and 3D printing the concrete emulsion composition are also provided.

Cementing compositions contain water, a cement and an additive for adjusting thermal conductivity. The additive for adjusting thermal conductivity may be graphite, graphene, aluminum oxide, hematite, copper metal, copper oxide, aluminum, amorphous carbon, gallium metal, iron metal, magnesium oxide, nickel metal, nickel oxide, tin metal, tin oxide, zinc metal or zinc oxide, or combinations thereof. Such compositions may have thermal conductivities exceeding 2 W/mK. Such compositions may be useful in closed loop geothermal completions or for encasing electrical cables.

Geopolymer precursors are presented that are useful for subterranean wells. The precursors contain an aluminosilicate source, an alkali activator, and a carrier fluid. Additives are incorporated into the precursors to induce expansion, self-healing, flexibility, and to improve tensile and shear-bond strength.

Trafficked pavement substrates utilize markings to segregate traffic (e.g., divide lanes traveling in the same direction, divide sides of the road traveling in opposite directions). A dry polymer modified cement mixture may be used to provide the markings. The dry polymer modified cement mixture is prepared by mixing a dry polymer modified cement blend (ordinary Portland cement, aggregate and polymer powders) with water. The location of the lines is identified, and the dry polymer modified cement mixture is applied onto the identified areas as a thin layer. The dry polymer modified cement blend may include polymers to provide colored markings. Glass beads may be embedded into the dry polymer modified mixture before it cures to retroreflect light shined thereon. The trafficked pavement substrate may have troughs formed therein and the dry polymer modified cement markings may be formed therewithin so that the markings are flush.

Methods and systems for cementing a wellbore are described. The methods include forming a slurry including a cement-based matrix, water, a polymer-based additive, and a rheology modifying agent; mixing the slurry to form a printing ink; introducing the slurry and a printer into a wellbore; and forming a cement-based composite structure in the wellbore by printing a plurality of layers using the printing ink.