A moldable composite material for use in the production of models and objects across numerous industries, the cured state of the composite material having various other applications, and a method of manufacture thereof. The composite material is self-adhering, substantially self-curing, and easily recyclable for reclamation of reuse. Certain embodiments may also be applied for use in 3D printing.

Provided is a three-dimensional object formation method for forming a three-dimensional object by at least repeating: forming a powder material layer using a powder material for three-dimensional object formation containing a base material coated with an organic material; and hardening a predetermined region of the powder material layer by delivering a hardening liquid to the powder material layer formed in the formation of a powder material layer, where the hardening liquid contains a cross-linking agent cross-linkable with the organic material.

This invention relates to three-dimensional printing. This invention in particular relates to a method of generating mold and printing a three-dimensional object. The mold thickness is controlled and holes are generated in the mold surface for releasing moisture easily. The mold surface having holes is designed initially digitally and then combined with the three-dimensional model before printing the three-dimensional object. In case the thickness of the mold surface is more then it reduces the overall quality of the three-dimensional object. When the model is enclosed inside the mold, there will be some residue moisture in the model even if the drying apparatus can improve this by drying layer by layer. This affects the final quality of the part. A solution of these problems is provided in the present invention. The thickness of the mold layer is between 0.5 to 1 mm and holes having 0.1 to 0.4 mm diameter. The holes are evenly distributed on the mold. The mold having the holes is prepared from which moisture can easily escape. A method of digitally generated a mold having thin layer and holes is used for fabricating three dimensional objects with high precision and quality.

This invention relates to three-dimensional printing. This invention particularly relates to a system with a dynamic variable size nozzle orifice for three-dimensional printing of objects based on crafting and molding techniques, and a method thereof. The present invention provides a dynamic variable nozzle orifice, where one embodiment uses a nozzle made of a soft flexible material. The soft flexible material, such as rubber, latex or silicone, is such that when the extrusion pressure is high the orifice will enlarge and allow wider extrusion volume for filling large or wide voids. In another scenario, when the extrusion pressure is lower the orifice will be narrower and give precise narrow extrusion to fill smaller voids. Another embodiment uses a method of controlling the orifice size which is by a mechanical means independent of the pressure in the nozzle. Such a method can utilize an iris device for controlling the size of the orifice. By utilizing the function of a dynamic orifice size of the nozzle when depositing a crafting material inside a mold structure as described herein, the printing time can be reduced without a reduction in detailing abilities. Subsequently, the systems and methods of the present invention are useful for fabricating high-quality three-dimensional objects using a crafting paste and molding techniques.

An ink formulation for additive manufacturing of low density syntactic foams is described. The ink formulation can include a thermoset resin, a curing agent suitable for use with the thermoset resin, a plurality of hollow spheres, such as glass microballoons, one or more solvents, and one or more non-hollow, viscosity modifying filler. Also described are a method of preparing the ink formulation, a method of preparing three-dimensional objects comprising low density syntactic foams, and the three-dimensional objects prepared thereby.

Provide is a cement ink for a cement ink for 3D printing (which also includes additive manufacturing) of 3D cement structures and materials. The cement ink includes an American Petroleum Institute (API) Class G cement, a nano-clay, a superplasticizer, a hydroxyethyl cellulose, and a defoamer. The nano-clay may be hydrophilic bentonite. The superplasticizer may be a polycarboxylate ether. The defoamer may be 2-ethyl-1-hexanol. Processes for forming the cement ink and printing 3D cement structures using the cement ink are also provided.

A cementitious composition suitable for formation by three-dimensional printing according to the present invention is aimed at developing a cementitious composition suitable for formation by three-dimensional printing which gives good stability to the extruded material coming out of a nozzle. The workpiece obtained from the three-dimensional printing formation therefore has fewer errors and greater fineness and is easier to use. The cementitious composition comprises cement, fine aggregate, powdered limestone, expanding admixture, retarding admixture, thickener and rheology modifier.

A method for producing a three-dimensional porous transition alumina catalyst monolith of stacked catalyst fibers, comprising the following steps: a) Preparing a suspension paste in a liquid diluent of hydroxide precursor particles or oxyhydroxide precursor particles of transition alumina particles or mixtures thereof and which suspension can furthermore comprise a binder material in a maximum amount of 20 wt %, based on the amount of hydroxide precursor particles or oxyhydroxide precursor particles of transition alumina particles or mixtures thereof and/or a plasticizer and/or a dopant in a maximum amount of 10 wt %, based on the amount of hydroxide precursor particles or oxyhydroxide precursor particles of transition alumina particles or mixtures thereof, all particles in the suspension having a number average particle size in the range of from 0.05 to 700 m, b) extruding the paste of step a) through one or more nozzles to form fibers, and depositing the extruded fibers to form a three-dimensional porous catalyst monolith precursor, c) drying the porous catalyst monolith precursor to remove the liquid diluent, d) performing a temperature treatment of the dried porous catalyst monolith precursor of step c) at a temperature in the range of from 500 to 1000 C., to form the transition alumina catalyst monolith, wherein no temperature treatment of the porous catalyst monolith precursor or porous catalyst monolith at temperatures above 1000 C. is performed and wherein no further catalytically active metals, metal oxides or metal compounds are applied to the surface of the transition alumina precursor particles, the catalyst monolith precursor or transition alumina catalyst monolith. no further catalytically active metals, metal oxides or metal compounds are present in the suspension paste.

In an embodiment, a system includes a three-dimensional (3D) printer, a neutral feedstock, a p-doped feedstock, an n-doped feedstock, and a laser. The 3D printer includes a platen and an enclosure. The platen includes an inert metal. The enclosure includes an inert atmosphere. The neutral feedstock is configured to be deposited onto the platen. The neutral feedstock includes a halogenated solution and a nanoparticle having a negative electron affinity. The p-doped feedstock is configured to be deposited onto the platen. The p-doped feedstock includes a boronated compound introduced to the neutral feedstock. The n-doped feedstock is configured to be deposited onto the platen. The n-doped feedstock includes a phosphorous compound introduced to the neutral feedstock. The laser is configured to induce the nanoparticle to emit solvated electrons into the halogenated solution to form, by reduction, layers of a ceramic comprising a neutral layer, a p-doped layer, and an n-doped layer.

The present invention discloses a concrete construction method for controlling setting time and special equipment thereof. The technical solution comprises processes of mixing, pumping, extruding, forming, setting and hardening. An electric treatment of applying an external electric field to a concrete mixture is provided between the pumping and the extruding process. The mixture treated by the external electric field is immediately extruded through an extrusion outlet. The special equipment comprises a transporting pump, a transporting pipeline and an extrusion device. The extrusion device comprises an equipment for electrical process and the extrusion outlet. By adopting the construction solution and equipment in the present technical solution, an effect on rapid controlling or adjusting the concrete setting time is achieved and an early strength of concrete is rapidly and rationally enhanced. A requirement of adjusting concrete setting time at will before the forming process is met.