A 3D printer material that includes one or more additives or additive materials mixed with a base material (e.g., a powder for use in binder jetting or a paste for use in extrusion). The additives may be fine powders (or spherical additives), fibers, aggregates, or a combination thereof with the particular additive material(s) and the ratio of additive to base being carefully chosen to achieve desired physical and/or chemical characteristics in the 3D object printed using the new 3D printer material. The addition of powders and/or fibers serves to strengthen the 3D printed material produced through binder jetting or extrusion. In particular, the new 3D printer materials address the issue of weak interfaces between printed horizontal layers since the additives either improve packing or bridge the layers of the 3D printed object.

An exemplary process for forming a cured hybrid magnesium cement composition may include first combining a mixture of magnesium-containing material, a metal silicate inorganic polymer having a repeat unit of SiP.sub.2O.sub.7, and a salt having a non-metallic oxide anion, and then mixing the mixture with water.

Material system suitable for a 3D printing method or 3D printing method material system comprising or consisting of a particulate material, a printing liquid, and an ester activator as well as 3D printing processes that use such a material system and molding parts produced by means of such material systems and 3D printing processes.

A method of placing a flowable construction material including a hydraulic binder for building structural components layer-by-layer, such as for 3D concrete printing, the method including preparing a fresh flowable construction material made of Portland cement, fine limestone filler materials, fine sands, water, and water reducing admixture and possibly a set or hardening accelerating admixture, conveying the flowable construction material to a deposition head, placing the construction material through an outlet of the deposition head in order to form a layer of construction material, before placing the construction material, adding a rheology-modifying agent to the construction material so that the placed material has an increased yield stress when compared to the material during the conveying step.

A 3D-printable, self-reinforced ultra-ductile cementitious material comprising; a mix of 50 percent cement and 50 percent mineral admixture.

Methods and materials are disclosed for making three dimensional articles via 3d printing. The methods can include printing both electrically insulating and electrically conducting portions, transparent, reflective or opaque portions, transparent portions having different refractive indices, portions of different colors, and where the various deposited portions are UV or heat curable, and optionally comprise particles, such as metallic particles in electrically conductive portions and ceramic particles in electrically insulating portions. A variety of 3D articles can be made, such as transparent articles such as eyeglasses, or electronics articles such as portions of smartphones, tablets or the like.

The present disclosure is drawn to material sets for 3-dimensional printing, 3-dimensional printing systems, and 3-dimensional printed parts. A material set can include a polyamide polymer powder having an average particle size from 20 m to 120 m and a fusing agent. The polyamide-12 powder can include greater than 80 meq/g carboxylic end groups and less than 40 meq/g amino end groups. The fusing agent can include an energy absorber capable of absorbing electromagnetic radiation to produce heat.

Provided is a method for easily reinforcing a three-dimensional shaped object. The method for reinforcing a three-dimensional shaped object comprises reinforcing the three-dimensional shaped object using an impregnating composition containing a 2-cyanoacrylic acid ester having a specific structure, said impregnating composition having a viscosity at 25 C. in a range of from 1 to 1000 mPa.Math.s, and said impregnating composition having a Shore hardness D in a range of from 20 to 75 when being hardened. Preferably, the three-dimensional shaped object is formed of an inorganic powder.

A system and method of constructing a 4D-printed ceramic object includes extruding inks including particles and polymeric ceramic precursors through a nozzle to deposit the inks on a heating plate, whereby a 3D-printed elastomeric object is formed on the heating plate, folding the 3D-printed elastomeric object into a complex structure to form a 4D-printed pre-strained elastomeric object, and converting the 4D-printed elastomeric object into the 4D-printed ceramic object.

Provided herein are compositions including oxotremorine (e.g., oxotremorine methiodide or Oxo-M) and 4-PPBP (e.g., 4-PPBP maleate). Also provided are methods of treating a connective tissue defect in a subject with oxotremorine and 4-PPBP. In addition, provided are scaffolds and methods of making same that include multiple fibers that include Oxo-M, 4-PPBP, and optionally icariin or kartogenin.