Patent classifications
C04B2111/0081
ANISOTROPIC LAMELLAR INORGANIC FIBER AEROGEL MATERIALS AND PREPARATION METHOD THEREOF
The present disclosure provides an anisotropic lamellar inorganic fiber aerogel material and a preparation method thereof. The method includes: mixing a polymer solution, an inorganic precursor and a chloride to obtain a spinning precursor solution; blow spinning the spinning precursor solution to obtain a composite fiber aerogel; calcinating the composite fiber aerogel to obtain the anisotropic lamellar inorganic fiber aerogel material. Therefore, the method has advantages of simplicity, easy operation, low cost, high efficiency and easy industrialized production. The inorganic fiber aerogel materials prepared by the above method are composed of multi-layer stacked fibers and have an anisotropic lamellar structure, which can be cut into any desired shape, and stacked to any desired thickness. In addition, the inorganic fiber aerogel materials have good flexibility and compressibility, excellent fire resistance, good high and low temperature resistance and superior thermal insulation, which greatly expands their application field.
METHOD FOR PRODUCING TRANSITION ALUMINA CATALYST MONOLITHS
A method for producing a three-dimensional porous transition alumina catalyst monolith of stacked catalyst fibers, comprising the following steps: a) Preparing a suspension paste in a liquid diluent of hydroxide precursor particles or oxyhydroxide precursor particles of transition alumina particles or mixtures thereof and which suspension can furthermore comprise a binder material in a maximum amount of 20 wt %, based on the amount of hydroxide precursor particles or oxyhydroxide precursor particles of transition alumina particles or mixtures thereof and/or a plasticizer and/or a dopant in a maximum amount of 10 wt %, based on the amount of hydroxide precursor particles or oxyhydroxide precursor particles of transition alumina particles or mixtures thereof, all particles in the suspension having a number average particle size in the range of from 0.05 to 700 m, b) extruding the paste of step a) through one or more nozzles to form fibers, and depositing the extruded fibers to form a three-dimensional porous catalyst monolith precursor, c) drying the porous catalyst monolith precursor to remove the liquid diluent, d) performing a temperature treatment of the dried porous catalyst monolith precursor of step c) at a temperature in the range of from 500 to 1000 C., to form the transition alumina catalyst monolith, wherein no temperature treatment of the porous catalyst monolith precursor or porous catalyst monolith at temperatures above 1000 C. is performed and wherein no further catalytically active metals, metal oxides or metal compounds are applied to the surface of the transition alumina precursor particles, the catalyst monolith precursor or transition alumina catalyst monolith. no further catalytically active metals, metal oxides or metal compounds are present in the suspension paste.
Honeycomb structure
A honeycomb structure includes plugged honeycomb segments, bonding layers and a circumferential wall. The bonding layers includes bottomed-hollow unbonded portions, which extend toward an internal side in an axial direction from an end face of the honeycomb structure, in portions of circumferential bonding layers bonding the honeycomb segments on an outermost circumference. The unbonded portions exist on respective extended lines extending from an intersection of the bonding layers which is closest to a centroid of the end face. An opening length of the unbonded portion is 1 to 10 mm, a ratio of an opening depth of the unbonded portion to a length of the honeycomb segment is 10 to 45%, and a ratio of a distance from the circumferential wall to a point at which an open end of the unbonded portion ends to a length of the circumferential bonding layer is 5 to 100%.
HONEYCOMB BODY WITH POROUS MATERIAL
A honeycomb body (100) having a porous ceramic honeycomb structure with a first end (105), a second end (135), and a plurality of walls (115) having wall surfaces defining a plurality of inner channels (110). A porous material is disposed on one or more of the wall surfaces of the honeycomb body (100). A method for forming a honeycomb body (100) includes depositing a porous inorganic material on a ceramic honeycomb body (100) and binding the porous inorganic material to the ceramic honeycomb body (100) to form the porous layer.
HONEYCOMB BODIES WITH HONEYCOMB STRUCTURE STRENGTHENING FEATURES AND EXTRUSION DIES THEREFOR
A honeycomb body having a honeycomb structure and a peripheral skin, the honeycomb structure having walls defining a plurality of cells including peripheral cells disposed directly adjacent to the peripheral skin. One or more of the peripheral cells is at least partially defined by a first wall surface, a second wall surface, and a skin surface portion extending between the first wall surface and the second wall surface. A continuously-varying radius extends from a first tangent to the first wall surface along the skin surface portion and to a second tangent to the second wall surface. Other honeycomb bodies, structures, and extrusion dies for forming honeycomb structures are disclosed.
Catalyst-containing oxygen transport membrane
A method is described of producing a catalyst-containing composite oxygen ion membrane and a catalyst-containing composite oxygen ion membrane in which a porous fuel oxidation layer and a dense separation layer and optionally, a porous surface exchange layer are formed on a porous support from mixtures of (Ln.sub.1xA.sub.x).sub.wCr.sub.1yB.sub.yO.sub.3 and a doped zirconia. Adding certain catalyst metals into the fuel oxidation layer not only enhances the initial oxygen flux, but also reduces the degradation rate of the oxygen flux over long-term operation. One of the possible reasons for the improved flux and stability is that the addition of the catalyst metal reduces the chemical reaction between the (Ln.sub.1xA.sub.x).sub.wCr.sub.1yB.sub.yO.sub.3 and the zirconia phases during membrane fabrication and operation, as indicated by the X-ray diffraction results.
SKINNING OF CERAMIC HONEYCOMB BODIES
A ceramic honeycomb body having a skin that does not block partial cells extending from an inlet face to an outlet face at an outer periphery portion of the body. A method of making the ceramic honeycomb body having the skin includes disposing a sheet on an outer peripheral wall of a honeycomb core having an outer surface spaced apart from interiors of the partial cells and skinning the body having the sheet disposed thereon. Subsequent curing in the method bonds the skin to cell walls of the body spaced apart from interiors of the partial cells.
Exhaust filter with active plugs
A ceramic honeycomb body having intersecting walls that form channels extending axially from a first end face to a second end face and plugs to seal the channels at least at one of the first end face and the second end face. The plugs include a first active component, such as a catalytically active component or a chemically active component, of the plug structure, wherein the intersecting walls comprise no first active component and optionally have a second active component of the wall structure or disposed on the walls. Included are methods of making the ceramic honeycomb body having plugs of the first active component and walls with no first active component.
Ordered cellular structures and methods of manufacturing the same
A method of manufacturing an ordered cellular structure including a series of interconnected unit cells. Each unit cell includes at least one straight wall segment. The method includes irradiating a volume of photo-monomer in a reservoir with at least one light beam from at least one light source to form the ordered cellular structure. Irradiating the volume of photo-monomer includes directing the at least one light beam though a series of interconnected apertures defined in a photo-mask covering the reservoir.
Substrate and a method of manufacturing a substrate
A substrate and a method of manufacturing a catalytic substrate body arranged within the catalytic convertor such that a principal flow of fluid through the catalytic convertor flows along a surface of the substrate body, wherein said surface has a plurality of openings to micro-channels that extend away from said surface; and at least a portion of the surface of the substrate body comprises a catalytically active material, wherein the substrate body is in the form of a pellet; a sheet; solid elongated bodies; solid rods; a solid body having a plurality of bores; a non-tubular elongated body; a non-hollow body; a sheet curved in the form or a spiral; or a combination thereof.